===================== Product Identification =====================
MSDS NAME:ETHYL ALCOHOL, REAGENT, DENATURED, HPLC GRADE, 270741
NIIN:00F035165
MSDS Number: BTKLP
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL; (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 94
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9394
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50, (ORAL), RAT IS 7060 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF INHALED,
SWALLOWED OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO
EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. CAUSES SKIN
IRRITATION. CAN CAUSE CNS DEPRESSION. E XPOSURE CAN CAUSE DAMAGE TO
EYES, NAUSEA, DIZZINESS & HEADACHE. CHRONIC: DAMAGE TO LIVER,
HEART.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:WARNING: CONTAINS METHANOL. MAY BE FATAL OR
CAUSE BLINDESS IF SWALLOWED. CANNOT BE MADE NON- POISONOUS. CAUSES
IRRITATION TO EYES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAMINATED
CLOTHING & SHOES. WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION: REMOVE T O FRESH AIR. IF NOT BREATHING, GIVE ARTIFICAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN. INGESTION: WASH OUT MOUTH WITH WATER IF PERSON IS
CONSCIOUS. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:48.0F,8.9C
Lower Limits:3.3%
Upper Limits:24.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT. USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS. WARNING: FLAMMABLE LIQUID.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF
IGNITION. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS & HEAVY
RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE & PLACE IN CLOSED
CONTAINERS FOR DISPOSAL. USE NON-SPA RKING TOOLS. VENT AREA & WASH
SPILL SITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:HYGROSCOPIC. STORE IN A COOL, DRY
PLACE. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP TIGHTLY
CLOSED. POISON. IRRITANT. DO NOT BREATHE VAPOR.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID
PROLONGED OR REPEATED EXPOSURE. HANDLE AND STORE UNDER NITROGEN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:OTHER PROTECTIVE CLOTHING, SAFETY SHOWER &
EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:172F,78C
Melt/Freeze Pt:M.P/F.P Text:-202F,-130C
Vapor Pres:44.6 @ 20C
Vapor Density:1.59
Spec Gravity:0.785
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALKALI METALS & AMMONIA.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE &
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE & LOCAL
LAWS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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