===================== Product Identification =====================
MSDS NAME:11961,FORMALDEHYDE
NIIN:01-017-3542
MSDS Number: BXYDS
=== Responsible Party ===
Company:HF SCIENTIFIC INC.
Address:3170 METRO PARKWAY S.E.
City:FORT MYERS
State:FL
ZIP:33916-7537
Country:US
Info Phone Num:813-337-2116
Emergency Phone Num:800-424-9300
Preparer's Name:NONE
CAGE:58177
=== Contractor Identification ===
Company:HF SCIENTIFIC INC.
Address:3170 METRO PARKWAY S.E.
City:FORT MYERS
State:FL
ZIP:33916-7539
Country:US
Phone:941-337-2116
CAGE:58177
============= Composition/Information on Ingredients =============
Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 4%
Other REC Limits:MFR, TLV STEL: 2PPM
OSHA PEL:1 PPM,SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 1.0-1.5%
Other REC Limits:250 PPM STEL
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 94
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 800 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: EYES:IRRITATION,DAMAGE.
SKIN:IRRITATION,BURNS,ABSORBTION WITH SAME SYMPTOMS AS INGESTION.
INHALATION:RESPIRATORY TRACT IRRITATION,INJURY,DEATH.
INGESTION:IRRITATION,VOMITING,DIARRHEA,BLINDNESS,
UNCONSCIOUSNESS,DEATH. CHRONIC:DERMATITIS,ALLERGIC REACTION,VISION
IMPAIRMENT,LIVER ENLARGEMENT,SUSPECTED CARCINOGEN.
Explanation of Carcinogenicity:CONTAINS F [50-00-0] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES:IRRITATION,PAIN,BLURRED VISION,DAMAGE.
SKIN:IRRITATION, PAIN,BURNS,ABSORBTION WITH SAME SYMPTOMS AS
INGESTION. INHALATION:SORE THROAT,RESPIRATORY TRACT
IRRITATION,INJURY,PULMONARY EDEMA,PNEUMONIT IS,DEATH.
INGESTION:PAIN,VOMITING,HEADACHE,DIARRHEA,GI TRACT PAIN,WEAK
IRREGULAR PULSE,BLINDNESS,UNCONSCIOUSNESS,DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN AND
EYE PROBLEMS,IMPAIRED LIVER,KIDNEY OR RESPIRATORY FUNCTION MAY BE
AT INCREASED RISK FROM EXPOSURE.PREVIOUSLY EXPOSURE MAY CAUSE
ALLERGIC REACTION TO FUTURE EXP0SURE.
======================= First Aid Measures =======================
Eyes: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO
FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING DIFFICULT,
GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: INDUCE VOMITING BY
GIVING TWO GLASSES OF WATER/MILK AND STICKING FINGER DOWN THROAT.
GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:140F,60C
Lower Limits:7.0%
Upper Limits:73%
Extinguishing Media:USE WATER TO EXTINGUISH FIRES AND COOL FIRE EXPOSED
CONTAINERS. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:USE WATER TO FLUSH SPILLS FROM EXPOSURE AND
DILUTE TO NON-FLAMMABLE MIXTURE. USE SCBA WITH FULL FACEPIECE IN
PRESSURE DEMAND OR POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR FORMS EXPLOSIVE MIXTURE WITH AIR
BETWEEN UPPER AND LOWER EXPLOSIVE LIMITS. FLASH BACK ALONG VAPOR
TRAIL MAY OCCUR. WEAR FULL PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA.REMOVE IGNITION SOURCES.WEAR
RESPIRATORY PROTECTION.DO NOT FLUSH TO SEWER OR SURFACE
WATERS.ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINER
FOR DISPOSAL.REPORTABLE QUANTITY (CERCLA): 1000 LBS FORMALDEHYDE,
5000 LBS METHANE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN CLOSED CONTAINERS.PROTECT FROM
PHYSICAL DAMAGE.OUTSIDE OR DETACHED STORAGE PREFERRED.INSIDE
STORAGE SHOULD BE STANDARD FLAMMABLE ROOM/CABINET.
Other Precautions:STORE FROM OXIDIZERS.DO NOT EAT,DRINK,SMOKE IN
STORAGE OR WORK AREAS.WASH HANDS,FACE,FOREARMS,NECK ON EXITING
RESTRICTED AREAS. SHOWER, DISPOSE OF OUTER CLOTHING,CHANGE TO CLEAN
GARMENTS AT DAYS END.A VOID CROSS-CONTAMINATING STREET CLOTHS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PEL IS EXCEEDED, A FULL-FACE RESPIRATOR WITH
CARTRIDGES OR CANISTERS SPECIFICALLY APPROVED FOR PROTECTION
AGAINST FORMALDEHYDE MAY BE WORN UP TO CONCENTRATIONS OF 10 PPM.
Ventilation:LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED. LOCAL EXHAUST
IS GENERALLY PREFERRED SINCE IT CONTROLS EMISIONS AT SOURCE.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLE AND/OR FACESHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. DO NOT
WEAR CONTACT LENSES. WEAR IMPERVIOUS PROTECTIVE CLOTHING, BOOTS.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
REACTION OF FORMALDEHYDE WITH HYDRCHLORIC ACID MAY FORM
BIS-CHLOROMETHYL ETHER, AN OSHA REGULATED CARCINOGEN.
================== Physical/Chemical Properties ==================
HCC:F6
Boiling Pt:B.P. Text:205F,96C
Melt/Freeze Pt:M.P/F.P Text:5F,-15C
Vapor Density:1.04
Spec Gravity:1.08
Solubility in Water:INFINITE
Appearance and Odor:CLEAR, COLORLESS LIQUID. PUNGENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS EXPLOSIVELY WITH NITROGEN DIOXIDE AT 356F; VIOLENTLY WITH
PERCHLORIC ACID,NITROMETHANE,PERCHACID-ANILINE MIXTURE.
Stability Condition to Avoid:EXTREMES IN TEMPERATURE, SPARKS, AND
FLAME. AVOID OXIDIZING AGENTS AND ALKALIES.
Hazardous Decomposition Products:IF INVOLVED IN FIRE, IRRITATING
GASEOUS FORMALDEHYDE AND CABON MONOXIDE MAY BE RELEASED.
Conditions to Avoid Polymerization:TRIOXYMETHYLENE PRECIPITATE CAN FORM
ON STANDING AT VERY LOW TEMPERATURES. PARAFORMALDEHYDE MAY FORM AT
LOW TEMPERATURE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. IF PERMITTED, MAY BE DISPOSED IN APPROVED
FACILITY OR DISSOLVED IN APPROPRIATE COMBUSTIBLE SOLVENT AND
ATOMIZED IN A RCRA APPROVED CHE MICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER.
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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