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MSDS  : SPADNS REAGENT FOR FLUORIDE,444-11
CAS  : 7647-01-0
7784-46-5
7732-18-5
NAME  : hydrogen chloride (hydrochloric acid) (sara 302/313)
sodium arsenite (sara 302/313) (cercla)
other components
water
===================== Product Identification =====================

MSDS NAME:SPADNS REAGENT FOR FLUORIDE,444-11
NIIN:01-010-3168
MSDS Number: BXYDQ
=== Responsible Party ===
Company:HACH CO.
Address:100 DAYTON RD.
Box:907
City:AMES
State:IA
ZIP:50010
Country:US
Info Phone Num:800-227-4224
Emergency Phone Num:800-227-4224/303-623-5716POISON CTR
CAGE:4T252
=== Contractor Identification ===
Company:HACH CO
Address:5600 LINDBERGH DR
Box:389
City:LOVELAND
State:CO
ZIP:80539
Country:US
Phone:970-669-3050/ 303-623-5716
CAGE:91224
Company:HACH COMPANY
Address:100 DAYTON RD.
Box:907
City:AMES
State:IA
ZIP:50010
Country:US
Phone:800-227-4224
CAGE:4T252

============= Composition/Information on Ingredients =============

Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313)
(CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: <40%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:SODIUM ARSENITE (SARA 302/313) (CERCLA)
CAS:7784-46-5
RTECS #:CG3675000
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1018
ACGIH TLV:0.01 MG(AS)/M3,A1;95
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Name:OTHER COMPONENTS
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED

Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT

===================== Hazards Identification =====================

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 540 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, TEETH,
RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE. INHALE:MAY CAUSE
INFLAMMATION, CHOCKING, COUGHING, LUNG DAMAGE. EYE/SKIN:SEVERE
BURNS. MAY CAUSE PERMANENT EYE DAMAGE. ORAL: IMMEDIATE PAIN & BURNS
OF MOUTH, THROAT, ESOPHAGUS & GI TRACT. MAY BE FATAL. CHRONIC-
EROSION OF TEETH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BURNS, COUGHING, DIFFICULT
BREATHING, CHEST PAIN, ABDOMINAL PAIN, NAUSEA, VOMITING, DENTAL
EROSION, CHOCKING, SKIN REDNESS OR DISCOLORATION, DEEP ULCERATION,
EYE DAMAGE, DEATH, SEDATION
Medical Cond Aggravated by Exposure:DAMAGED SKIN, EYE DISORDERS,
LUNG/RESPIRATORY SYSTEM DISEASES

======================= First Aid Measures =======================

First Aid:GET MEDICAL CARE IMMEDIATELY IN ALL CASES.
EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
KEEP EYELIDS OPEN. TREAT FOR CHEMICAL BURNS IF NECESSARY.
INHALATION:REMOVE TO FRESH AIR. PRO VIDE CPR/OXYGEN IF NEEDED.
INGESTION:IFCONSCIOUS, DRINK LARGE AMOUNT OF MILK/WATER. DO NOT
INDUCE VOMITING.

===================== Fire Fighting Measures =====================

Flash Point:NONE
Extinguishing Media:USE DRY CHEMICAL. USE WATER SPRAY TO COOL
FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE. REACTS WITH MOST
METALS FORMING HYDROGEN WHICH CAN EXPLODE. MAY FORM TOXIC FUMES OF
ARSENIC AND CHLORIDES

================== Accidental Release Measures ==================

Spill Release Procedures:WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE
AREA. REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). DO NOT RELEASE
INTO SOIL, SEWER. NEUTRALIZE WITH SODA ASH/SODIUM BICARBONATE. USE
AN ABSORBENT SUCH AS SA ND/VERMICULITE ON SLURRY. TRANSFER TO
CONTAINER.
Neutralizing Agent:SODA ASH, LIME, SODIUM BICARBONATE

====================== Handling and Storage ======================

Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED,
CORROSION-PROOF AREA, AWAY FROM FLAME AND EXCESSIVE HEAT. KEEP OUT
OF REACH OF CHILDREN.
Other Precautions:DANGER! STRONG ACID. MODERATELY TOXIC. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPORS/MIST. USE UNDER
THE HOOD WITH ADEQUATE VENTILATION. PROTECT CONTAINERS AGAINST
PHYSICAL DAMAGE.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:USE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY
AND HEALTH (NIOSH) APPROVED SELF-CONTAINED BREATHING APPARATUS
OPERATED IN POSITIVE PRESSURE MODE WHEN PERMISSIBLE EXPOSURE LIMITS
ARE EXCEEDED.
Ventilation:PROVIDE GENERAL VENTILATION OR LOCAL EXHAUST TO MEET OSHA
PERMISSIBLE EXPOSURE LIMITS (OSHA PEL).
Protective Gloves:PVC, NEOPRENE
Eye Protection:CHEMICAL SAFETY GOGGLES AND FACE SHIELD
Other Protective Equipment:USE RUBBER SPLASH APRON AND RUBBER BOOTS.
EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NOTE TO PHYSICIAN:WASH AFFECTED SKIN AREAS WITH A 5% SOLUTION OF SODIUM
BICARBONATE. IF INGESTED, THE RISK VERSUS THE BENEFIT OF THE
PASSAGE OF A NASO-GASTRIC TUBE IS DEBATABLE. DO NOT GIVE THE EXPOSE
D PERSON BICARBONATE TO NEUTRALIZE THE MATERIAL.

================== Physical/Chemical Properties ==================

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:221F,105C
Spec Gravity:1.015
pH:<0.5
Evaporation Rate & Reference:0.64 (REF UNKNOWN)
Solubility in Water:MISCIBLE
Appearance and Odor:DARK RED SOLUTION - SHARP, IRRITATING ODOR
Corrosion Rate:0.207

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, ALKALIES, ACTIVE METALS SUCH AS IRON,
ALUMINUM OR ZINC, CYANIDES, SULFIDES
Stability Condition to Avoid:EXCESSIVE HEAT, FLAMES
Hazardous Decomposition Products:MAY EMIT HYDROGEN CHLORIDE VAPORS OR
GAS, ARSENIC AND CHLORIDES.

==================== Disposal Considerations ====================

Waste Disposal Methods:OBSERVE FEDERAL, STATE AND LOCAL ENVIRONMENTAL
REGULATORS FOR PROPER DISPOSAL. CONSIDER RECYCLING.

======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

*** END OF RECORD ***
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