=====================  Product Identification  =====================

MSDS NAME:PAD ETCH GAL CASE, 7748232
NIIN:00N066401
MSDS Number: CBDNZ
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:800-274-5263
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897

=============  Composition/Information on Ingredients  =============

Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 33%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM; 15 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:AMMONIUM FLUORIDE (CERCLA)
CAS:12125-01-8
RTECS #:BQ6300000
Fraction by Wt: 14%
OSHA PEL:2.5 MG/M3 (F)
ACGIH TLV:2.5 MG/M3 (F)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Name:SUPDAT: EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP IS
    COMPLETED. STOP SPILL AT SOURCE. DIKE TO PREVENT SPREADING. (ING 4)
RTECS #:9999999ZZ

Name:ING 3: PUMP TO SALVAGE TANK.
RTECS #:9999999ZZ

Name:RESP PROT: CNDTNS (SEE INDUSTRIAL HYGIENIST).
    ENGINEERING/ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE
    EXPOS.
RTECS #:9999999ZZ

Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: EXPOSURE TO LIQUID OR
    VAPOR CAUSES IRREVERSIBLE EYE DAMAGE. SYMPTOMS MAY INCLUDE
    STINGING, TEARING, REDNESS, SWELLING, CORNEAL DAMAGE AND BLINDNESS.
    SKIN: CAUSES BURNS, POSSIBLE DEEP ULCE RATION. INHALATION: MIST CAN
    CAUSE DAMAGE TO NASAL AND RESPIRATORY PASSAGES. INGESTION: RESULTS
    IN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SEVERE DAMAGE TO MUCOUS MEMBRANES AND
    DEEP TISSUES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:SKIN: IMMED FLUSH EXPOSED AREA W/WATER FOR AT LEAST 15 MIN.
    GET MED ATTN. REMOVE CONTAMD CLTHG. LAUNDER CONTAMD CLTHG BEFORE
    REUSE. REMOVE CONTAMD SHOES PROMPTLY. DISCARD SHOES SATURATED
    W/PROD. EYES:  IMMED FLUSH W/LG AMTS OF WATER FOR AT LEAST 15 MIN,
    LIFTING UPPER & LOWER LIDS OCCAS. GET IMMED MED ATTN. IF MD IS NOT
    IMMED AVAIL, CONTINUE FLUSHING W/WATER. DO NOT USE CHEM ANTIDOTE.
    (SUPDAT)

=====================  Fire Fighting Measures  =====================

Lower Limits:4.0%
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT . WATER MAY BE USED TO EXTINGUISH FIRE BY
    COOLING AND DILUTING LIQUID WITH WATER.
Unusual Fire/Explosion Hazard:ACID REACTS WITH MOST METALS TO RELEASE
    HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SM SPILL:COVER CONTAMD SURF W/SODIUM
    BICARBONATE OR SODA ASH/FLAKED LIME MIX (50-50). MIX & ADD WATER IF
    NEC TO FORM SLURRY. SCOOP UP SLURRY & WASH SITE W/SODA ASH SOLN.
    PROPER MIXING PROCS ARE ESSNTL . TRAINED PERS SHOULD CONDUCT THIS
    PROC. (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN
    EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR
    SOLID), ALL HAZ PRECS GIVEN MUST BE OBSERVED.
Other Precautions:ADDITION TO WATER RELEASES HEAT WHICH CAN RESULT IN
    VIOLENT BOILING & SPATTERING. ALWAYS ADD SLOWLY AND IN SMALL
    AMOUNTS. NEVER USE HOT WATER. NEVER ADD WATER TO ACIDS. ALWAYS ADD
    ACIDS TO WATER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD OR ANY
    COMPONENT IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
    ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS PERMIT OTHER
    NIOSH/MSHA APPRVD RESPS (NEG PRE SS TYPE) UNDER SPECIFIED (ING 5)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
    EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESISTANT GLOVES SUCH AS NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 6)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . TO
    PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: INGEST: DO NOT INDUCE VOMIT. VOMIT WILL CAUSE FURTHER
    DMG TO THROAT. DILUTE BY GIVING WATER. GIVE MILK OF MAGNESIA. KEEP
    WARM, QUIET. GET MED ATTN IMMED. INHAL: REMOVE TO FRESH AIR. SP ILL
    PROC: UNTRAINED PERS SHOULD BE REMOVED FROM SPILL AREA. LG
    SPILL:PERS NOT WEAR PROT EQUIP SHOULD BE (ING 3)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:212F,100C
Vapor Pres:17.50 @68F
Vapor Density:2.10
Spec Gravity:> WATER
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>60

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, EXCESSIVE HEAT, ORGANIC MATERIALS,
    REDUCING AGENTS, METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOX MATLS: ACID VAPORS,
    AMMONIA, CARBON DIOXIDE & CARBON MONOXIDE, HYDROGEN FLUORIDE,
    NITROGEN CMPDS, ETC.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
    LOCAL, STATE AND FEDERAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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