=====================  Product Identification  =====================

MSDS NAME:SULFURIC ACID 66 DEGREE BAUME
NIIN:00N072673
MSDS Number: CBYSF
=== Responsible Party ===
Company:GREAT WESTERN CHEMICAL CO
Address:808 SW 15TH AVENUE
City:PORTLAND
State:OR
ZIP:97205
Country:US
Info Phone Num:503-228-2600
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:DAVID L BISHOP
CAGE:GREA1
=== Contractor Identification ===
Company:GREAT WESTERN CHEMICAL CO
Box:UNKNOW
CAGE:0GV91
Company:GREAT WESTERN CHEMICAL CO
Address:808 S W 15 AVE
City:PORTLAND
State:OR
ZIP:97205
Country:US
Phone:503-228-2600
CAGE:GREA1

=============  Composition/Information on Ingredients  =============

Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: >93%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:SUP DAT: MAY PRODUCE HAZARDOUS FUMES OR HAZARDOUS
    DECOMPOSITION PRODUCTS.
RTECS #:9999999ZZ

Name:EFTS OF OVEREXP: PRLNG SKIN EXPOS MAY CAUSE DESTRUCTION OF
    DERMIS W/IMPAIRMENT OF SKIN AT THE SITE OF CONT TO (ING 4)
RTECS #:9999999ZZ

Name:ING 3: REGENERATE. INGEST: CAN CAUSE SEV IRRIT &/BURNS TO
    ENTIRE GI TRACT, INCL STOM & INTESTINES, CHARACTERIZED (ING 5)
RTECS #:9999999ZZ

Name:ING 4: BY NAUS, VOMIT, DIARR, ABDOM PAIN, BLEEDING &/TISS
    ULCERATION. CHRONIC: RPTD INHAL EXPOS MAY CAUSE BRONCH,(ING 6)
RTECS #:9999999ZZ

Name:ING 5: IMPAIRMENT OF LUNG FUNC, PERM LUNG DMG & EROSION OF
    TOOTH ENAMEL. OTHERWISE, CHRONIC EFTS OF EXPOS WOULD (ING 7)
RTECS #:9999999ZZ

Name:ING 6: BE THE SAME AS FOR ACUTE EXPOSURE.
RTECS #:9999999ZZ

Name:FIRST AID PROC: SKIN: IMMED FLUSH W/PLENTY OF CLEAN RUNNING
    WATER FOR AT LEAST 15 MIN, WHILE REMOVING CONTAM (ING 9)
RTECS #:9999999ZZ

Name:ING 8: CLTHG & SHOES. IF BURN/IRRIT OCCURS, CALL MD.
    INGEST: DO NOT INDUCE VOMIT. GET MED ATTN IMMED. IF VICTIM (ING 10)
RTECS #:9999999ZZ

Name:ING 9: IS FULLY CONSCIOUS, GIVE CUPFUL OF WATER. NEVER GIVE
    ANYTHING BY MOUTH TO AN UNCON PERS. NOTE TO MD: THE (ING 11)
RTECS #:9999999ZZ

Name:ING 10: PRIMARY HAZARD OF THIS MATERIAL IS THE CORROSIVE
    EFFECT ON TISSUE. TREAT EXPOSURE SYMPTOMATICALLY.
RTECS #:9999999ZZ

Name:SPILL PROC: PICK UP BULK OF LIQ USING PUMPS/VACUUM
    TRUCK/ABSORB LIQ IN SAND/COMMERCIAL ABSORB. PLACE IN APPRVD (ING
    13)
RTECS #:9999999ZZ

Name:ING 12: CONTRS FOR DISP. FLUSH SPILL AREA W/WATER, COLLECT
    RINSATES & CONTAINERIZE FOR DISP. PVNT RUN-OFF FROM (ING 14)
RTECS #:9999999ZZ

Name:ING 13: CONTAMINATING SEWERS, STREAMS/OTHER BODIES OF
    WATER. WATER SPILL: THIS MATL IS HVR THAN & COMPLETELY SOL(ING 15)
RTECS #:9999999ZZ

Name:ING 14: IN WATER. STOP OR DIVERT WATER FLOW. DIKE
    CONTAMINATED WATER & REMOVE FOR DISPOSAL AND/OR TREATMENT. (ING 16)
RTECS #:9999999ZZ

Name:ING 15: NOTIFY ALL DOWNSTREAM USERS OF POSSIBLE
    CONTAMINATION.
RTECS #:9999999ZZ

Name:WASTE DISP METH: IS SUBJECT TO THE LAND DISP RESTRICTIONS
    UNDER 40 CFR 268 & MUST BE MANAGED ACCORDINGLY. AS A (ING 18)
RTECS #:9999999ZZ

Name:ING 17: HAZARDOUS LIQUID WASTE, IT MUST BE DISPOSED OF
    I/A/W LOCAL, STATE & FEDERAL REGULATIONS IN A PERMITTED (ING 19)
RTECS #:9999999ZZ

Name:ING 18: HAZARDOUS WASTE TREATMENT, STORAGE AND DISPOSAL
    FACILITY BY TREATMENT.
RTECS #:9999999ZZ

Name:EYE PROTECTION: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL RAT): 2140 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: EXPOS TO MISTS CAN CAUSE
    SEV IRRIT TO NOSE, MOUTH, THROAT & LUNGS. INHAL OF MISTS CAN CAUSE
    BURNS TO RESP TRACT RSLTG IN LUNG EDEMA WHICH CAN RSLT IN SHORTNESS
    OF BRTH, WHEEZING, CHOKING , CHEST PAIN & IMPAIRMENT OF LUNG
    FUNCTION. INHAL OF HIGH CONCS MAY RSLT IN PERM LUNG DMG. EYE: EXPOS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONO ON EVAL OF
    CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992: GROUP 1. ANIMAL:
    PULM IRRIT.
Effects of Overexposure:HLTH HAZ: TO MISTS MAY CAUSE SEV IRRIT &/BURNS,
    W/SYMPS OF TEARING, REDNESS, SWELL & MUC DISCHARGE. DIRECT CONT
    W/LIQ WILL BE CORR TO EYE. CORNEAL DMG W/IMPAIRMENT OF VISION MAY
    RSLT FROM DIRECT CONT  W/LIQ. SKIN: EXPOS TO MISTS MAY RAPIDLYCAUSE
    SEV IRRIT &/BURNS CHARACTERIZED BY REDNESS, SWELL & SCAB FORM. (ING
    3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL: IMMED MOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP.
    DO NOT USE MOUTH-TO-MOUTH METH IF VICTIM INGESTED/INHALED
    SUBSTANCE; USE HOLGER NIELSEN METH (BACK PRESS ARMLIFT)/PROPER RESP
    MED DEVICE.  IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. EYE: IMMED
    FLUSH W/PLENTY OF CLEAN RUNNING WATER FOR AT LEAST 15 MIN, LIFTING
    UPPER & LOWER LIDS OCCAS. REMOVE CONT LENSES IF WORN. GET MED ATTN
    IMMED. (ING 8)

=====================  Fire Fighting Measures  =====================

Flash Point:NONE
Extinguishing Media:FOAM, CARBON DIOXIDE AND DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . USE
    EXTREME CAUTION WHEN APPLYING WATER SPRAY TO COOL CONTRS EXPOSED TO
    FIRE. DO NOT ALLOW WATER SPRAY(SUP DAT)
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMP, MATL EMITS TOX
    OXIDES OF SULFUR. THE UNIFORM FIRE CODE PHYSICAL HAZ RATING FOR
    THIS MATL IS WATER-REACTIVE CLASS 2. DO NOT LET (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:LAND SPILL: WEARING REC PROT CLTHG, DIKE SPILL
    USING SOIL, SAND/COMPATIBLE COMMERCIAL ABSORB. HAZ CONCS OF VAPS
    MAY BE IN LOC SPILL AREA & IMMED DOWNWIND. DO NOT PUT WATER
    DIRECTLY ON THIS PROD AS HEA T EVOLUTION MAY OCCUR CAUSING VIOLENT
    RXN.(ING 12)
Neutralizing Agent:NEUTRALIZE ACID USING LIME OR A LIME BASED AGENT
    COMPATIBLE WITH THIS PRODUCT.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURE. STORE IN
    A COOL, DRY, WELL-VENTILATED PLACE, AWAY FROM ALKALIES AND MOST
    METALS. DO NOT STORE IN DIRECT SUNLIGHT.
Other Precautions:STORE ABOVE FREEZING POINT. DO NOT BREATHE VAPOR OR
    MISTS. USE ONLY WITH ADEQUATE VENTILATION. PROTECT EYES, SKIN, AND
    CLOTHING FROM CONTACT WITH PRODUCT.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:FOR EXPOSURE ABOVE THE OSHA-PEL OR ACGIH-TLV,
    WEAR A NIOSH APPROVED FULL FACEPIECE OR HALF MASK AIR-PURIFYING
    CARTRIDGE RESPIRATOR EQUIPPED WITH AN ACID GAS CARTRIDGE OR
    SUPPLIED AIR.
Ventilation:USE LOCAL EXHAUST VENTILATION CAPABLE OF MAINTAINING
    EMISSIONS IN THE WORK AREA BELOW THE OSHA-PEL OR ACGIH-TLV.
Protective Gloves:NEOPRENE OR PVC GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 20)
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER.
    WEAR NEOPRENE/PVC APRON/FULL PROT CLTHG WHEN HNDLG PROD. NEOPRENE
    BOOTS.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE FIGHT PROC: TO COME IN CONT W/THIS MATL. IT WILL REACT VIOLENTLY
    W/WATER & ORG MATLS RSLTG IN EVOLUTION OF HEAT & SPLATTERING OF
    MATL. EXPLO HAZ: WATER COME IN CONT W/THIS MATL. MATL WILL EVOLVE 
    FLAMM/EXPLO HYDROGEN GAS ON CONT W/REACTIVE METALS (E.G., ALUMINUM,
    MAGNESIUM, ZINC). DILUTE SOLNS MAY BE CORR. (ING 2)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:535F,279C
Melt/Freeze Pt:M.P/F.P Text:-21F,-29C
Vapor Pres:0.0016
Vapor Density:>1
Spec Gravity:1.8354
pH:<1
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH NO ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ALKALIS, AMINES, ANHYDRIDES, COMBUSTIBLES, ORGANICS, OXIDIZERS AND
    POWDERED METALS.
Stability Condition to Avoid:AVOID CONTACT W/WATER AND ORGANIC
    MATERIAL. AVOID EXCESS HEAT. AVOID CONTACT W/ALKALINE MATERIALS AND
    REACTIVE METALS.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT EMITS
    TOXIC OXIDES OF SULFUR.

====================  Disposal Considerations  ====================

Waste Disposal Methods:RCRA 40 CFR 261 CLASSIFICATION: CORR WASTE. U.S.
    EPA WASTE #/DESCRIPTION: D002. IF THIS PROD BECOMES A WASTE, IT
    MEETS CRITERIA OF HAZ WASTE AS DEFINED UNDER 40 CFR 261 DUE TO ITS
    CORR. IF THIS PROD B ECOMES A WASTE. IT WILL BE HAZ WASTE WHICH(ING
    17)

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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