===================== Product Identification =====================
MSDS NAME:METHANOL
NIIN:00-224-8353
MSDS Number: CCBYR
=== Responsible Party ===
Company:DUPONT-NEN RESEARCH PRODUCTS
Address:549 ALBANY STREET
City:BOSTON
State:MA
ZIP:02118
Country:US
Info Phone Num:617-482-9595
Emergency Phone Num:800-424-9300(CHEMTREC)/800-441-3637
Chemtrec Ind/Phone:(800)424-9300
CAGE:0VGR3
=== Contractor Identification ===
Company:DUPONT-NEN RESEARCH PRODUCTS
Address:549 ALBANY STREET
Box:City:BOSTON
State:MA
ZIP:02118
Country:US
Phone:617-482-9595
CAGE:0VGR3
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 96
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN IRRIT,SLIGHTLY TOXIC BY
INHAL,DERMAL ABSORPTION,INGEST.25000PPM IMMED DANGEROUS TO
LIFE/HEALTH.INEBRIATION,APATHY/DELIRIUM,COMA,VISUAL
EFFECTS,BLINDNESS,ACIDOSIS,CARDIAC DEPRESS,DEATH.ABSORBS THRU
SKIN.CONVULSIONS,PAIN,DYSPNEA,NARCOSIS,BRONCHITIS,CYANOSIS,LIVER/KI
DNEY DMG,CEREBRAL/PULM EDEMA,FTG,WEAK,CONJ.
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN STATUS:NONE.
Effects of Overexposure:VISUAL IMPAIRMENT,BLINDNESS,CNS
DEPRESSION,ATROPHY,PHOTOPHOBIA,COUGH,HEAD,DULLNESS,VERTIGO,RESTLESS
NESS,INSOMNIA,LEG CRAMPS,NAU,VOMIT,DIARR,VIOLENT PAIN IN
BACK/ABD/EXTREMITIES,MUSC INCOORD,SWEAT,TACH YCARDIA,RESP
FAILURE/CIRCULATORY COLLAPSE(DEATH),LIVER/KIDNEY/BRAIN
DMG,BLINDNESS,CYANOSIS,OPTIC NERVE ATROPHY.
Medical Cond Aggravated by Exposure:PERSONS W/CHRONIC
RESPIRATORY,LIVER,KIDNEY,EYE,SKIN DISEASES. TARGET
EFFECTS:NEUROTOXIN,CNS DEPRESSANT,NARCOTIC.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED.STOP BREATH PERFORM ART
RESP.KEEP WARM/REST.TREAT SYMPT/SUPP.GET MED ATTN IMMED.SKIN:REMOVE
CONTAMCLOTH/SHOES IMMED.WASH W/SOAP/MILD DETERGENT/LG AMTS OF WATER
TIL NOT EVIDENCE OF CHEM REMAINS(15-20MINS).GETMED ATTN
IMMED.EYE:WASH IMMED W/LG AMTS OF WATER/NORMAL SALINE,LIFT EYELIDS
TIL NO EVIDENCE OF CHEM REMIANS(15-20MINS).GET MED ATTN
IMMED.INGEST:WITHING (SUPPL)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=11.1C, 52.F
Lower Limits:6.0
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS TO
PROTECT AGAINST THE HAZ BYPRODUCTS OF COMBUSTION, OXYGEN DEFICIENCY
& TOXIC FUMES.
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPO TO
HEAT/FLAME/OXIDIZERS.VAP HEAVIER THAN AIR;TRAVEL CONSIDERABLE
DISTANCE TO IGN SOURCE-FLASHBACK.VAPO/AIR MIX EXPLOSIVE.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGN SOURCES.ASSURE ADEQUATE
VENTILATION.TAKE UP W/SAND/OTHER APPROPRIATE ABSORBENT MATL & PLACE
INTO SUITABLE CLEAN,DRY CONTAINER FOR LATER DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN
STORING.STORE AWAY FROM INCOMP SUBSTANCES.STORE IAW 29CFR1910.106.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:PROVIDE LOC EXHAU/PROCESS ENCLOSURE VENTI TO MEET PUBLISHED
EXPO LIMITS.VENTILATION EQPMT MUST BE EXPLO-PROOF.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:SPLASH-PROOF SAFETY GOGGLES.
Other Protective Equipment:WEAR IMPERV CLOTH/EQPMT TO PREVENT REP/PROL
SKIN COTNACT W/SUBSTANCE.EYEWASH FOUNTAIN,QUICK DRENCH SHOWER W/IN
WORKAREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
1STAID:2HRS OF INGEST GIVE SYRUP OF IPECAC.LAVAGE WELL W/2-4L OF WATER
W/SODIUM BICARBONATE(20G/L)ADDED(PERFORMED BY QUAL MED PERSON).GET
MED ATTN IMMED.ANTIDOTE:QUAL MED PERSON MAKE DECISION/DOSE.50%
(100PROOF)ETHANOL,1.5ML/KG ORALLY,DIL TO NOT MORE THAN
5%SOLN,FOLLOW 0.5-1.0ML/KG EVERY 2HR 4DAYS.ADMIN 4-METHYLPYRAZOLE
================== Physical/Chemical Properties ==================
HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=65.C, 149.F
Melt/Freeze Pt:=-93.7C, -137.F
Decomp Temp:Decomp Text:NP
Vapor Pres:97.25 @20C
Vapor Density:NP
Spec Gravity:NP
pH:NP
Evaporation Rate & Reference:NP
Solubility in Water:NP
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A CHARACTERISTIC
ALCOHOLIC ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS,LAUMINUM,CHLOROFORM/SODIUM HYDROXIDE,CYANURIC
CHLORIDE,DICHLOROMETHANE,LEAD,STRONG OXIDIZERS,ZINC.
Stability Condition to Avoid:MAY BE IGNITIED BY
HEAT/SPARKS/FLAMES.CONTAINER MAY EXPLODE IN HEAT OF FIRE.VAPOR
EXPLO/POISON HAZARD.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:SUBJ TO SARA SEC 313 ANNUAL TOXIC CHEM RELEASE
REPORTING.OBSERVE ALL FED/STATE/LOC REGS WHEN DISPO.DISPO MUST BE
IAW STDS APPLICABLE TO GENERATORS OF HAZ WASTE 40CFR262.EPA HAZ
WASTE:U154.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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