===================== Product Identification =====================
MSDS NAME:SIERRA CLEANING COMPOUND
NIIN:00F052776
MSDS Number: CDCCH
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Info Phone Num:614-790-3333/800-274-5263
Emergency Phone Num:800-274-5263/614-790-3333
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897
============= Composition/Information on Ingredients =============
Name:METHYL ETHYL KETONE, 2-BUTANONE *96-4*
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 36%
Other REC Limits:590 MG/CUM
OSHA PEL:200 PPM
ACGIH TLV:590 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, ETHYL ESTER, ETHYL ACETATE *96-4*
CAS:141-78-6
RTECS #:AH5425000
Fraction by Wt: 34-38%
Other REC Limits:400 PPM
OSHA PEL:1400 MG/CUM
ACGIH TLV:1400 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TOLUENE (IARC CARC- GROUP 3) *96-4*
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 19%
Other REC Limits:375 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL (IARC CANCER REVIEW GROUP 3) *96-4*
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 10%
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
Name:VOLATILE ORGANIC CONTENT: 850. 00 G/L; 7.090 LBS/GAL
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MILD IRRITATION. SKIN: MILD
IRRITATION & BURNS. INGESTION: LOW TOXICITY, HARMFUL IN LARGE
AMOUNTS. GI IRRITATION. INHALATION: LOW TOXICITY, HARMFUL IN LARGE
AMOUNTS. IRRITATION TO NOSE, THROAT, RESPIRATORY TRACT, CNS
DEPRESSION & DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, STINGING, TEARING, REDNESS,
DRYNESS, BURNING, CRACKING, BURNS, NAUSEA, VOMITING, DIARRHEA,
DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, HEADACHE,
UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:PRE-EXISTING DISORDERS, LIVER
ABNORMALITIES, ANEMIA, SPLEEN DAMAGE, KIDNEY DAMAGE, LUNG DAMAGE,
BRAIN DAMAGE.
======================= First Aid Measures =======================
Eyes: FLUSH GENTLY W/WATER FOR 15 MINS. SKIN: WASH W/SOAP &
WATER. INGESTION: DON'T INDUCE VOMITING. IF PERSON IS
DROWSY/UNCONSCIOUS, PLACE ON LEFT SIDE W/THE HEAD DOWN. IF
POSSIBLE, DON'T LEAVE INDIV IDUAL UNATTENDED. INHALATION: REMOVE
TOFRESH AIR. KEEP WARM & QUIET. GIVE CPR/OXYGEN IF NEEDED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:20-99F
Lower Limits:1.2
Extinguishing Media:REGULAR FOAM, WATER FOG, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SCBA W/A FULL FACEPIECE OPERATED IN THE
POSITIVE PRESSURE DEMAND MODE W/APPROPRIATE TURN OUT GEAR &
CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE > THAN AIR & MAY TRAVEL ALONG
THE GROUND/MOVE FROM OTHER IGNITION SOURCES AT LOCATIONS DISTANT
FROM MATERIAL HANDLING POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: ABSORB LIQUID ON VERMICULITE, FLOOR
ABSORBENT/OTHER ABSORBENT MATERIAL. LARGE: ELIMINATE IGNITION
SOURCES. PROTECTIVE EQUIPMENT SHOULD BE USED UNTIL CLEAN UP IS
COMPLETE. STOP AT SOURCE. PUMP/V ACUUM AREA, CLEAN CONTAINERS FOR
RECOVERY. (SUPP)
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS MAY BE HAZARDOUS WHEN
EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES, ALL
HAZARD PRECAUTIONS MUST BE OBSERVED.
Other Precautions:ALL FIVE GALLON PAILS & LARGE METAL CONTAINERS, TANK
CARS & TANK TRUCKS SHOULD BE GROUNDED &/BONDED WHEN MATERIAL IS
TRANSFERRED. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM BECAUSE
PRODUCT CAN IGNIT E EXPLOSIVELY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE LIMIT IS EXCEEDED, A NIOSH/MSHA
APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED. OSHA PERMIT OTHER
NIOSH/MSHA RESPIRATORS(NEGATIVE PRESSURE TYPE)UNDER SPECIFIED
CONDITIONS.
Ventilation:SUFFICIENT MECHANICAL(GENERAL/LOCAL EXHAUST) TO MAINTAIN
EXPOSURE BELOW TLVS.
Protective Gloves:NITRILE RUBBER/POLYETHYLENE
Eye Protection:CHEMICAL SPLASH GOGGLES/SAFETY GLASSES
Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
SPILLS: ABSORB UNRECOVERABLE PRODUCT. TRANSFER CONTAMINATED ABSORBENT,
SOIL & OTHER MATERIALS TO CONTAINERS FOR DISPOSAL. PREVENT RUN-OFF
TO SEWERS, STREAMS/OTHER BODIES OF WATER. IF RUN OFF OCCURS, N
OTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:168F
Vapor Pres:65.5
Vapor Density:>1
Spec Gravity:0.851
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:HOMOGENEOUS LIQUID SOLUTION
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:CO2, CO, VARIOUS HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. UN1263.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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