===================== Product Identification =====================
MSDS NAME:01379500 BENZOTRIAZOLE
NIIN:01-448-9170
MSDS Number: CFMXJ
=== Responsible Party ===
Company:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100 OR 201-796-7523
Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:BENZOTRIAZOLE
CAS:95-14-7
RTECS #:DM1225000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:1072MG/KG ORAL-RAL LD50
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRIT-INHAL,EYE.TOXIC BY
INHAL;MODERATE TOXIC BY DERMAL ABSORPTION & INGEST.INHAL:MAY CAUSE
IRRIT.IRRIT/TOXIC.SKIN:MAY CAUSE IRRIT.CHRONIC:MAY CAUSE CONTACT
DERM.POSITIVE ECZEMATOUS RXS OBSERVED IN PA TCH
TESTING.EYE:IRIT.MAY CUASE SEFVERE IRRIT,POSSIBLY
BURNS.CHRONIC:REP/RPOL CONTACT W/IRRIT MAY CAUSE CONJUNCT(SUPPLE)
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN STATUS:NONE.
Effects of Overexposure:INHAL:IRRIT.SKIN IRRIT,DERM,EYE IRRIT,POSSIBLEY
EYE BURNS,CONJUNCTIVITIS.CENTRAL NERVOUS SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:TARGET ORGANS:NO DATA AVAILABLE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FRM EXPO TO FRESH AIR IMMED.PERFORM ART RESP IF
NECESSARY.KEEP WARM/@REST.TREAT SYMPT/SUPPROT.SKIN:REMOVE CONTAM
CLOTH/SHOES IMMED.WASH W/SOAP/MILD DETERGENT/LG ATMS OF WATER TIL
NO EVIDE NCE OF CHEM REMAINS(@LEAST 15-20MINS).EYE:WASH IMMED W/LG
AMTS OF WATER OR NORMAL SALINE,LIFT LIDS OCCASIONALLY,TIL NO
EVIDENCE OF CHEM REMAINS(@LEAST 15-20MINS).INGEST:VOMIT OCCURS HELP
PREVENT(SUPP)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:340F,171C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:2.4
Upper Limits:NP
Extinguishing Media:DRY CHEM,CO2,WATERSPRAU,REG FOAM.LG FIRE:USE
WATERSPRAY,FOG,REG FOAM.
Fire Fighting Procedures:MOVE CNTNR FRM FIRE AREA W/O RISK.DONT SCTTER
SPILL MATL W/HIGH-PRESSURE WATER STREAMS.DIKE FIRE-CONTROL WATER
FOR LATER DISPO.USE AGENTS SUITABLE FOR TYP(SUPP)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP & PLACE IN SUITABLE CLEAN,DRY
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL.DONT FLUSH SPILLED
MATL INTO SEWER.KEEP UNNECESSARY PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN
STORING OF THIS SUBSTANCE.
Other Precautions:ANTIDOTE:NO SPECIFIC ANTIDOTE.TREAT
SYMPTOMATICALLY/SUPPROTIVELY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPEC RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORKPLACE/BASED ON SPEC OPERATION/NOT EXCEED WORK
LIMITS OR RESP/JOINT APPROV NIOOSH/MSHA:TYP C SUPPAIR W/FULL FCPC
IN PRESS-DEMAND/+PRESS MO DE/HELMET/HOOD CONT FLOW-MODE;ETC.
Ventilation:PROVIDE LOC EXHAU/PROCESS ENCLOSURE VENTI.VENTI EQPMT
SHOULD BE EXPLO-PROOF IF EXPLO CONC OF DUST/VAP/FUME PRESENT.
Protective Gloves:MUST WEAR APPROP PROT GLOVE
Eye Protection:MUST WEAR SPLASH-PROOF/DUST-RESIST(WORK)
Other Protective Equipment:MUST WEAR APPROP PROT(IMPERV)CLOTH/EQPMT TO
PREVENT REP/PROL SKIN CONTACT W/SUBST.EYEWASH FOUNTAIN W/IN IMMED
WORKAREA.
Work Hygienic Practices:EYE:SAF GOGG.
Supplemental Safety and Health
FIREFIGHT:OF SURROUNDING FIRE.AVOID BREATH HAZ VAP,KEEP UPWIND.
HEALTH:INGEST:MAY CAUSE CNS DEPRESS.CHRONIC:CARC STUDY FOUND NO
CONVINC EVIDENCE IN ANIMALS;HOWEVER ALVEOLAR/BRONCHIOLAR CARC/BRAIN
TUMO RS SUGG POSSIBLE CARC EFFECT. 1STAID:15-20MINS).GET MED ATTN
IMMED.INGEST:ASPIRATION.IN ALL CASES GET MED ATTN IMMED.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:662F,350C
Melt/Freeze Pt:M.P/F.P Text:208F,98C
Decomp Temp:Decomp Text:NP
Vapor Pres:0.04
Vapor Density:4.1
Spec Gravity:1.36
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:1-10%
Appearance and Odor:WHITE TO PALE YELLOW OR LIGHT TAN,CRYSTALLINE
POWDER/FLAKES,NO/SLIGHT CHAR ODOR
Percent Volatiles by Volume:0
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS(STRONG):FIRE & EXPLOSION HAZARD.
Stability Condition to Avoid:MAY DETONATE @220C OR DURING VACUUM
DISTILLATION.MAY BURN BUT DOESNT IGN READILY.AVOID STRO OXID/EXCESS
HEAT/SPARK/OPFLM
Hazardous Decomposition Products:THERM DECOMPO PROD MAY INCLUDE HIGHLY
TOXIC FUMES OF HYDRYOGEN CYANIDE & TOXIC OXIDES OF CARBON &
NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS
WHEN DISPOSING THIS SUBSTANCE.DISPOSAL MUST BE IAW STDS APPLICABLE
TO GENERATORS OF HAZ WASTE 40CFR262,EPA HAZ WASTE #:D003.100LBS
CERCLA SEC 103 RQ.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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