===================== Product Identification =====================
MSDS NAME:A669S 500 AMMONIUM HYDROXIDE 01260
NIIN:00F037967
MSDS Number: CGHJK
=== Responsible Party ===
Company:FISHER SCIENTIFIC CHEMICAL DIV
Address:1 REAGENT LN
City:FAIR LAWN
State:NJ
ZIP:07410-2802
Country:US
Info Phone Num:201-796-7100/201-796-7523
Emergency Phone Num:201-796-7100/201-796-7523
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:AMMONIUM HYDROXIDE, AQUA AMMONIA *98-1*
CAS:1336-21-6
RTECS #:BQ9625000
Fraction by Wt: 28-30%
Other REC Limits:25 PPM
ACGIH TLV:25 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 350 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE BURNS & POSSIBLE
IRREVERSIBLE DAMAGE. SKIN: SEVERE IRRITATION, BURNS. INGESTION:
HARMFUL, MAY CAUSE SEVERE & PERMANENT DAMAGE TO THE DIGESTIVE
TRACT, CORROSION & BURNS TO THE GI TRACT. IN HALATION: EFFECTS MAY
BE DELAYED, SEVERE IRRITATION OF THE UPPER RESPIRATORY TRACT, BURNS
& LUNG DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNS, IRRITATION, PENETRATING ULCERS, BROWN
STAINS, THROAT CONSTRICTION, VOMITING, CONVULSIONS, SHOCK,
COUGHING, BREATHING DIFFICULTY, COMA.
======================= First Aid Measures =======================
Eyes: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: RINSE
W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE
VOMITING. IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. NOTES
TO PHYSICIAN: AFTER INHALATION, OBSERVE FOR 24-48 HOURS AS
PULMONARY EDEMA MAY BE DELAYED. NO SPECIFIC ANTIDOTE. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Lower Limits:16
Upper Limits:25
Extinguishing Media:SMALL: WATER SPRAY, DRY CHEMICAL, CO2/CHEMICAL
FOAM.
Fire Fighting Procedures:WEAR SCBA IN PRESSURE DEMAND MSHA/NIOSH
(APPROVED/EQUIVALENT) & FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 1202F.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/INERT MATERIAL, THEN PLACE INTO A
CHEMICAL WASTE CONTAINER. NEUTRALIZE W/SODIUM BICARBONATE.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN A WELL VENTILATED AREA.
DON'T STORE IN DIRECT SUNLIGHT. STORE IN A COOL, DRY WELL
VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:DON'T GET ON SKIN/EYES. DON'T INGEST/INHALE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW
EXPOSURE LIMITS.
Protective Gloves:PROTECTIVE
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MAT TO AVOID: HYDROFLUORIC ACID/IODINE/NITRIC
ACID/OLEUM/PROPIOLACTONE/PROPYLENE OXIDE/SILVER NITRATE/SILVER
OXIDE/SILVER OXIDE & ETHYL ALCOHOL/NITROMETHANE/SILVER
PERMANGANATE/SULFURIC ACID/HALOGENS. FORMS EXPLOSIVE COMPOUNDS
W/MANY HEAVYMETALS & HALIDE SALTS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:82.4F
Melt/Freeze Pt:M.P/F.P Text:-106.6F
Vapor Pres:237.8
Vapor Density:1.2
Spec Gravity:0.9
pH:13.6
Evaporation Rate & Reference:(WATER = 1): 1
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID W/STRONG AMMONIA ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACROLEIN/ACRYLIC ACID/CHLOROSULFONIC ACID/DIMETHYL
SULFATE/FLUORINE/GOLD & AQUA REGIA/HYDORCHLORIC ACID. (SEE SUPP)
Stability Condition to Avoid:HIGH TEMPS, INCOMPATIBLE MATERIALS, DIRECT
SUNLIGHT.
Hazardous Decomposition Products:NITRIC OXIDE & AMMONIA FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. UN2672.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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