===================== Product Identification =====================
MSDS NAME:TOLUENE (PART 2)
NIIN:01-407-8389
Kit Part:Y
MSDS Number: CGLHT
=== Responsible Party ===
Company:DEMAREE INFLATABLE BOATS INC
Address:SECOND AND OAK ST
Box:307
City:FRIENDSVILLE
State:MD
ZIP:21531
Country:US
Info Phone Num:301-746-5815
Emergency Phone Num:301-746-5815
Chemtrec Ind/Phone:(800)424-9300
CAGE:7X236
=== Contractor Identification ===
Company:CHAND CORP. (504-532-2512)
Address:157 HWY 654
Box:City:MATHEWS
State:LA
ZIP:70375
Country:US
Phone:504-532-2512
CAGE:0D5X4
Company:DEMAREE INFLATABLE BOATS, INC
Box:307
City:FRIENDSVILLE
State:MD
ZIP:21531
Country:US
Phone:800-342-8823
CAGE:7X236
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: >99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:BENZENE (SARA 313) (CERCLA)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: TRACE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2; 9596
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50= 5G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP/MIST IRRIT MUC
MEMBRANES.INHAL HIGHER CONC MAY CAUSE HEAD,NAU,VOMIT,COMA.INHAL
VERY HIGH CONC/PROL EXPO MAY CAUSE UNCONSC,DEATH.EYE:LIQUID
SEVERELY IRRIT.SKIN:BRIEF CONTACT MAY DRY SKIN.PROL /REP CONTACT
MAY IRRIT,CAUSE DERM.INGEST:VOMIT.VOMIT SPONT DONT BREATH VOMITUS
INTO LUNGS AS EVEN SM QUANT IN (SIGN/SYM)
Explanation of Carcinogenicity:PER MSDS:MATL NOT CONSIDERED TO BE
CARCINOGEN BY NTP/IARC/OSHA.CONTAINS TRACES OF BENZENE-PROP 65.
Effects of Overexposure:HEALTH:LUNGS MAY RESULT IN CHEM PNEUITIS & PULM
EDEMA/HEMORRHAGE.CHRONIC:PROL/REP EXPO TO HIGH CONC MAY CAUSE LOSS
OF APPETITE,NOSE BLEEDS,LIVER/KIDNEY/NEURAL DYSFUNCTION.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN,AND
RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE ART RESP.GET IMMED
MED ATTN.EYE:IMMED FLUSH W/LOTS OF RUNNIG H2O FOR 15MINS,LIFT
EYELIDS OCCASIONALLY.GET IMMED MED ATTN.SKIN:IMMED WASH W/LOTS OF
SOAP/H2O.RE MOVE CONTAM CLOTH/SHOES.IRRIT PERSISTS AFT WASH GET MED
ATTN.INGEST:DONT INDUCE VOMIT.GET IMMED MED ATTN.VOMIT OCCURS SPONT
KEEP HEAD BEL HIPS-PREVENT BREATH VOMITUS INTO LUNG.NOTE TO
DR:(SUPPLEMENTA)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:40.0F,4.4C
Autoignition Temp:Autoignition Temp Text:N/DATA
Lower Limits:1.2
Upper Limits:7.6
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CO2. DONT
USE DIRECT WATER STREAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SCBA & FULL
PROTECTIVE CLOTHING.USE WATER SPRAY TO COOL NEARBY CONTAINERS &
STRUCTURES EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:AVOID H2O ACCUM-PROD WILLFLOAT ON H2O,MAY
REIGN ON SURF.EXT ALL NEARBY IGN SOURCES.VAP HEAVIER THAN
AIR,TRAVEL ALONG SURF TO DISTANT IGN SOURC-FLASHBACK(SUPPLE)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PPE(RUBB BOOT/APRON,CHEM RESIST
GLOVE,SCBA IN PRESSURE DEMAND MODE,SUPP AIR RESP).SM-FULL FCPC
AIRPURIF CARTRIDGE RESP EQP FOR ORG VAP SAT.WEAR EYE PROT.EXT ALL
IGN SOURCES/EQPMT ELECTR GROUND.SM :MOP/WIPE,DISPO.LG:DIKE
W/SOIL/NONCOMBUST(NEUTRAL)
Neutralizing Agent:SPILL:MATL.KEEP OUT OF SEWER/STORM DRAIN/SURF
H2O/SOIL.COMPLY W/SPILL REPORT REG
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL DRY WELL VENTI PLACE
AWAY FRM INCOMPAT MATLS.VENT CNTNR FREQ,OFT IN WARM WEATHER-RELIEVE
PRESSURE.HNDLG PROD ELECTR GROUND ALL EQPMT.
Other Precautions:USE ONLY NON-SPARK TOOLS.KEEP CNTNR TIGHTLY CLSD WHEN
NOT IN USE.DONT USE PRESSURE TO EMPTY.DONT CUT/WEL/DRILL ON/NEAR
CNTNR.IGN MAY OCCUR @BEL AUTOIGN/IGN TEMP.EMPTY CNTNR CAN HAVE
RESIDUES/GAS/MIST, ARE SUBJ TO PROPER WASTE DISPO AS ABOVE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE CONDITIONS GENERATE VAP/MIST WEAR
NIOSH-APPROV RESP APPROPRIATE FOR EMISSION LEVELS.APPROP RESP:FULL
FCPIECE,HALF MASK AIR-PURIFY CARTRIDGE RESP EQUIPPED FOR ORG
VAP/MIST,SCGA IN PRESSURE DEMAND M OD,SUPPLIED-AIR RESP.
Ventilation:EXPLO-PROOF VENTI CAPABLE OF MAINTAINING EMISSIONS @PT OF
USE BEL PEL.
Protective Gloves:CHEMICAL-RESISTANT GLOVES-PVA GLOVES
Eye Protection:CHEM GOGG
Other Protective Equipment:CONTACT LENSES SHOULDNT BE WORN WHEN WORK
W/CHEM-MAY CONTRIBUTE TO SEVER OF EYE INJURY.CHEM RESIST
CLOTH.EYEWASH(HYGPRC)
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE. SAF SHOWER
NEARBY/READY TO USE.WSH WELL AFT HNDLG.DONT GET IN EYE/SKIN/CLOTH.
Supplemental Safety and Health
1STAID:>2.0ML/KG INGEST/VOMIT HASNT OCCUR EMESIS SHOULD BE INDUCE
W/SUPERV.KEEP HEAD BEL HIPS-PREVENT ASPIRATION.SYMPT(LOSS OF GAG
REFLEX,CONVULS)OCCUR BEF EMESIS CONSIDER GASATRIC LAVAGE W/ACUFFED
EN DOTRACHEAL TUBE. FIRE/EXPLO:EXPLO VAP/AIR MIX >FLASH PT/FLAMM
LIMITS.HOT ORG CHEM VAP/MIST SUSCEPT SUDDEN SPONT COMBUST.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=111.C, 231.8F
Melt/Freeze Pt:=-95.C, -139.F
Vapor Pres:22
Vapor Density:3.2
Spec Gravity:0.87
pH:NO DAT
Viscosity:NP
Evaporation Rate & Reference:2.0, BUTYL ACETATE=1
Solubility in Water:0.05% NEGLIGIBLE
Appearance and Odor:COLORLESS, CLEAR LIQUID, AROMATIC ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDZING MATERIALS.
Stability Condition to Avoid:HEAT,SPARKS,AND OPEN FLAMES.
Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE,CARBON
DIOXIDE,& UNIDENTIFIED ORGANIC CMPDS IN BLACK SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA-CERCLA REPORT TO NRC 800-424-8802
AIR/LAND/H2O RELEASE EXCEED RQ(1000LBS).EPA-RCRA TOLUENE BECOMES
WASTE MATL-U220.REF:LATEST EPA/STATE/REGS REGARD PROPER DISPO.DISPO
IN MANNER APPROV FOR MATL.CON SULT FED/STATE/LOC REG AGENCIES.SEC
313SARA CHEM.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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