===================== Product Identification =====================
MSDS NAME:SODIUM HYPOCHLORITE SOLUTION
NIIN:00-900-6276
Status Code:A
MSDS Number: CJDSJ
=== Responsible Party ===
Company:HVC
Address:4600 DUES DR
City:CINCINNATI
State:OH
ZIP:45246-1009
Country:US
Info Phone Num:513-874-9261
Emergency Phone Num:513-874-9261
Preparer's Name:ALLAN T COWIE
Chemtrec Ind/Phone:(800)424-9300
CAGE:0W1X8
=== Contractor Identification ===
Company:HERBERT-VERKAMP-CALVERT CHEMICAL
Address:4600 DUES DRIVE
Box:18642
City:CINCINNATI
State:OH
ZIP:45246-1009
Country:US
Phone:513-874-9261
CAGE:1HD53
Company:HVC
Address:4600 DUES DR
Box:City:CINCINNATI
State:OH
ZIP:45246-1009
Country:US
Phone:513-874-9261
CAGE:0W1X8
============= Composition/Information on Ingredients =============
Name:SODIUM HYPOCHLORITE
CAS:7681-52-9
RTECS #:NH3486300
= Wt:12.5
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SODIUM CHLORIDE
CAS:7647-14-5
RTECS #:VZ4725000
= Wt:13.
Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
< Wt:1.2
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
> Wt:70.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:SKIN:MAY CAUSE SEVERE IRRITATION &/OR
BURNS. PROLONGED EXPOSURE MAY CAUSE DESTRUCTION OF THE DERMIS W/
IMPAIRMENT OF THE SKIN. BURNS MAY NOT BE IMMEDIATELY APPARENT.
EYES:SEVERE IRRITATION &/OR BURNS CAN OCCUR. CONTACT MAY CAUSE
IMPAIRMENTOF VISION & CORNEAL DAMAGE. INHALATION:IRRITATING TO
NOSE, MOUTH, THROAT, & LUNGS. MAY CAUSE BURNS TO THE RESP. TRACT W/
THE PROD'N OF LUNG EDEMA. INHAL'N OF HI GH CONC. OF MIST CAN RESULT
IN PERM. LUNG DAMAGE. INGESTION:IRRITATION &/OR BURNS CAN OCCUR TO
THE ENTIRE GASTROINTESTINAL TRACT. CHRONIC: MAY CAUSE LUNG DAMAGE,
TISSUE DESTRUCTION, & EYE BURNS. MAY ACT AS A SENSITIZER.
Effects of Overexposure:SKIN: REDNESS, SWELLING AND SCAB FORMATION.
EYES: SEVERE IRRITATION. INHALATION: SHORTNESS OF BREATH,
WHEEZING, CHOKING, CHEST PAIN. INGESTION:NAUSEA, VOMITING,
DIARRHEA, ABDOMINAL PAIN, BLEEDING A ND/OR TISSUE ULCERATION.
======================= First Aid Measures =======================
First Aid:SKIN:IMMEDIATELY FLUSH W/ LARGE AMTS. OF WATER FOR AT LEAST
15 MIN. CALL A DOCTOR IF IRRITATION OCCURS. REMOVE CONTAMINATED
CLOTHING & CLEAN BEFORE REUSE. EYES:IMMEDIATELY FLUSH W/ PLENTY OF
WATER FOR AT LEAST 15 MIN. WHILE HOLDING EYELIDSAPART. GET MEDICAL
ATTENTION. INHALATION:REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR
GIVE ARTIFICIAL RESPIRATION IF SITUATION WARRANTS. INGESTION:IF
CONSCIOUS, IMM EDIATELY GIVE 2 TO 4 GLASSES OF WATER. DO NOT INDUCE
VOMITING. CALL A DOCTOR AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF
THE PERSON IS UNCONSCIOUS OR IF HAVING CONVULSIONS.
===================== Fire Fighting Measures =====================
Flash Point:NOT FLAMMABLE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:USE WATER TO COOL CONTAINERS EXPOSED TO FIRE.
PRODUCT IS TOXIC TO FISH AND RUNOFF SHOULD BE CONTROLLED.
Unusual Fire/Explosion Hazard:HEAT WILL INCREASE THE DECOMPOSITION OF
THE PRODUCT INTO CHLORINE GAS WHICH IS AN OXIDIZER AND WILL SUPPORT
COMBUSTION. PRODUCT WILL REACT WITH MANY METALS TO FORM OXYGEN
WHICH SUPPORTS COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: FLUSH WITH PLENTY OF WATER TO
SEWER SYSTEM. ALTERNATELY, ABSORB WITH AN ABSORBENT AND PLACE
MATERIAL INTO A CLEAN, LABELED CONTAINER FOR PROPER DISPOSAL AS
WASTE. LARGE SPILLS: HANDLE SAM E AS ABOVE. NEUTRALIZATION OF WASH
OR FLUSH WATER IS NECESSARY BEFORE DISCHARGING.
Neutralizing Agent:CHLORINE MAY BE NEUTRALIZED WITH SODIUM
METABISULFITE, SODIUM THIOSULFATE, SODIUM SULFITE OR HYDROGEN
PEROXIDE.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN OR
CLOTHING. DON'T BREATHE MISTS. DO NOT EXPOSE CONTAINERS TO
TEMPERATURES ABOVE 90 DEGREES F. ALWAYS KEEP CONTAINERS CLOSED WHEN
NOT IN USE. DO NOT REMOVE THE VENTED CLO SURE OR DRUM MAY BUILD UP
PRESSURE AND RUPTURE. PRODUCT IS AN OXIDIZER AND MAY INITIATE
COMBUSTION.
Other Precautions:DO NT REUSE EMPTY CONTAINERS WITHOUT PROPER
RECONDITIONING. EMPTY DRUMS CONTAIN PRODUCT RESIDUE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF USE CONDITIONS REQUIRE, USE NIOSH APPROVED
RESPIRATOR FOR MISTS AND/OR CHLORINE. IF RESPIRATORS ARE USED,
OBSERVE REQUIREMENTS OF 29 CFR 1910.134.
Ventilation:SUFFICIENT GENERAL OR LOCAL EXHAUST TO CONTROL ANY MIST OR
AEROSOLS IF PRESENT.
Protective Gloves:NEOPRENE OR PVC GLOVES.
Eye Protection:SAFETY GLASSES AND FACE SHIELD AND GOGGLES
Other Protective Equipment:RECOMMEND USE OF APRON TO MINIMIZE CONTACT.
Work Hygienic Practices:NONE
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:=104.4C, 220.F
B.P. Text:APPROXIMATELY
Melt/Freeze Pt:=-20.6C, -5.F
M.P/F.P Text:APPROXIMATELY
Vapor Pres:12.1(MM HG @20DEG C)
Vapor Density:N/D
Spec Gravity:1.220GM/ML
pH:12.5, APPROX
Evaporation Rate & Reference:<1 (BUAC=1)
Solubility in Water:100%
Appearance and Odor:CLEAR, YELLOW LIQUID WITH CHLORINE ODOR
Percent Volatiles by Volume:10%, APPROX
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
ACIDS, OTHER ORGANIC MATERIALS, OXIDIZERS, NITROGEN CONTAINING
COMPOUNDS AND ALL METALS EXCEPT TITANIUM. WHEN MIXED WITH AMMONIA
SOLUTION, A TOXIC GAS WILL BE FORMED.
Stability Condition to Avoid:PRODUCT DECOMPOSES WITH AGE. DO NOT EXPOSE
TO DIRECT SUNLIGHT OR TO TEMPERATURES ABOVE 90 DEGREES F. DO NOT
STORE IN ANY TYPE OF METAL CONTAINER.
Hazardous Decomposition Products:CHLORINE GAS AND OXYGEN.
Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:NO DATA AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOLLOW ALL LOCAL, STATE AND FEDERAL REGULATIONS
FOR HAZARDOUS WASTE. PRODUCT IS SUBJECT TO LAND DISPOSAL
RESTRICTIONS UNDER 40 CFR 268.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION.
CLASS 8. UN1791. PACKAGING GROUP III.
===================== Regulatory Information =====================
SARA Title III Information:NO SECTION 313 CHEMICALS.
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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