===================== Product Identification =====================
MSDS NAME:DURACELL LITHIUM MANGANESE DIOXIDE BATTERIES, DL223A
NIIN:01-417-9567
Status Code:A
MSDS Number: CJDSS
=== Responsible Party ===
Company:GILLETTE MEDICAL EVALUATION LABORATORIES
Address:401 PROFESSIONAL DRIVE
Box:UNKNOW
City:GAITHERSBURG
State:MD
ZIP:20879
Country:US
Emergency Phone Num:617-449-7600
Resp. Party Other MSDS Num.:GMEL #1232
CAGE:9X831
=== Contractor Identification ===
Company:ANTIQUE ADDICT
Address:MAIN ST
Box:196
City:PARROTT
State:GA
ZIP:31777
Country:US
Phone:912-623-4400
CAGE:9X831
Company:DURACELL INC TECHNICAL SALES AND MARKETING GROUP
Address:BERKSHIRE CORPORATE PARK
Box:City:BETHEL
State:CT
ZIP:06801
Country:US
Phone:203-796-4000
CAGE:90303
Company:GILLETTE MED EVAL LAB(BOUGHT DURACELL)
Address:401 PROFESSIONAL DRIVE
Box:City:GAITHERSBURG
State:MD
ZIP:20879
Country:US
Phone:301-590-9781
CAGE:MO079
Company:LASER PRODUCTS
Address:18300 MT BALDY CIR
Box:City:FOUNTAIN VALLEY
State:CA
ZIP:92708
Country:US
Phone:714-545-9444
CAGE:0MY77
============= Composition/Information on Ingredients =============
Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Minumum % Wt:65.
Maxumum % Wt:70.
Other REC Limits:N/K
OSHA PEL:C5 MG/M3
OSHA STEL:N/K
ACGIH TLV:5 MG/M3
ACGIH STEL:N/K
Name:1,2-DIMETHOXYETHANE; ( FL PT METH: CC; FL PT: 42.8F/6C
(APPROXIMATELY 14%))
CAS:110-71-4
RTECS #:KI1451000
Minumum % Wt:10.
Maxumum % Wt:15.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:LITHIUM
CAS:7439-93-2
RTECS #:OJ5540000
Minumum % Wt:5.
Maxumum % Wt:10.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:PROPYLENE CARBONATE
CAS:108-32-7
RTECS #:FF9650000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:ETHYLENE CARBONATE
CAS:96-49-1
RTECS #:FF9550000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:3.5 MG/M3
OSHA STEL:N/K
ACGIH TLV:3.5 MG/M3
ACGIH STEL:N/K
Name:LITHIUM TRIFLUOROMETHANESULFONATE
CAS:33454-82-9
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS & METALS ARE CONTAINED
IN SEALED CAN. FOR CONSUMER USE, ADEQUATE HAZ WARNINGS ARE
INCLUDED ON BOTH PACKAGE & ON BATTERY. POTENTIAL FOR EXPOS SHOULD
NOT EXIST UNLESS BATTERY LEAKS, IS EXPOSED TO HIGH TEMPERATURE/IS
MECHANICALLY, PHYSICALLY/ELECTRICALLY ABUSED. ACUTE: INHAL: NOT
ANTICIPATED. RESPIRATORY (& EYE) IRRIT MAY OCCUR IF FUMES ARE
RELEASED DUE TO HEAT/ABUNDANCE OF LEAKI NG BATTERIES. INGEST:
IRRIT TO INTERNAL/EXTERNAL MOUTH AREA. SKIN CONT: IRRITMAY OCCUR
FOLLOWING EXPOS TO LEAKING BATTERY. SKIN ABSORPTION: NOT
ANTICIPATED. EYE CONTACT: IRRIT MAY OCCUR FOLLOWING EXPOS TO
LEAKING BATTERY.
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAMS, VOLUME 65,
PAGE 149, 1996: GROUP 2B. ANIMAL: LUNG.
======================= First Aid Measures =======================
Eyes: NOT ANTIC. IF BATTERY IS LEAKING & MATL CONTACTS EYES,
FLUSH W/COPIOUS AMTS OF CLEAR, TEPID WATER FOR 30 MINS. CONT MD AT
ONCE. SKIN: NOT ANTIC. IF BATTERY IS LEAKING, IRRIGATE EXPOSED
SKIN W/COPIOUS AMTS OF CLEAR, TEPID WATER FORAT LEAST 15 MINS. IF
IRRIT, INJURY/PAIN PERSISTS, CONSULT MD. INHAL: NOT ANTIC. IF
BATTERY IS LEAKING, CONTENTS MAY BE IRRITATING TO RESP PASSAGES.
REMOVE T O FRESH AIR. CONT MD IF IRRIT PERSISTS. INGEST: NOT
ANTIC. RINSE MOUTH & SURROUNDING AREA W/CLEAR, TEPID WATER FOR AT
LEAST 15 MINS. CONSULT MD IMMED FOR TREATMENT & TO RULE OUT
INVOLVEMENT OF ESO PHAGUS & OTHER TISS. (SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point:SEE ING 2
Extinguishing Media:WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL FIRE-EXPOSED BATTERIES AND ADJACENT STRUCTURES
WITH WATER SPRAY FROM A DISTANCE.
Unusual Fire/Explosion Hazard:BATTERIES MAY BURST AND RELEASE HAZARDOUS
DECOMPOSITION PRODUCTS WHEN EXPOSED TO A FIRE SITUATION.
================== Accidental Release Measures ==================
Spill Release Procedures:NOTIFY SAFETY PERSONNEL OF LARGE SPILLS.
EVACUATE THE AREA AND ALLOW VAPORS TO DISSIPATE. INCREASE
VENTILATION. AVOID EYE OR SKIN CONTACT. DO NOT INHALE VAPORS.
CLEAN-UP PERSONNEL SHOULD WEAR APP ROPRIATE PROTECTIVE GEAR.
REMOVE SPILLED LIQUID WITH ABSORBENT AND CONTAIN FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. AVOID
MECHANICAL OR ELECTRICAL ABUSE. DO NOT SHORT OR INSTALL
INCORRECTLY. BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF
DISASSEMBLED, CRUSHED, RECHARGED OR EXPOSED TO HIGH TEMPERATURES.
INSTALL BATTERIES IN ACCORDANCE WITH EQUIPMENT INSTRUCTIONS.
Other Precautions:DO NOT MIX BATTERY SYSTEMS, SUCH AS ALKALINE AND ZINC
CARBON, IN THE SAME EQUIPMENT. REPLACE ALL BATTERIES IN EQUIPMENT
AT THE SAME TIME. DO NOT CARRY BATTERIES LOOSE IN POCKET OR BAG.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE UNDER NORMAL USE CONDITIONS. USE NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION UNDER NORMAL USE CONDITIONS.
Protective Gloves:USE BUTYL GLOVES WHEN HANDLING LEAKING BATTERIES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:KEEP BATTERIES AWAY FROM SMALL CHILDREN.
Supplemental Safety and Health
FIRST AID PROC: NOTES TO MD: 1) POTENTIAL LEAKAGE OF DIMETHOXYETHANE,
PROPYLENE CARBONATE & LITHIUM TRIFLUOROMETHANE SULFONATE. 2)
DIMETHOXYETHANE RAPIDLY EVAPS. 3) UNDER CERTAIN MISUSE CNDTNS & BY
ABUSIVELY OPENING BATTERY, EXPOSED LITHIUM CAN REACT W/WATER OR
MOISTURE IN AIR CAUSING POTENTIAL THERMAL BURNS/FIRE.
================== Physical/Chemical Properties ==================
HCC:T6
Appearance and Odor:SMALL CYLINDRICAL BATTERIES. CONTENTS DARK IN
COLOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTENTS INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT HEAT, CRUSH, DISASSEMBLE, SHORT
CIRCUIT OR RECHARGE.
Hazardous Decomposition Products:THERMAL DEGRADATION MAY PRODUCE
HAZARDOUS FUMES OF MANGANESE AND LITHIUM; HYDROFLUORIC ACID;
OXIDES OF CARBON AND SULFUR AND OTHER TOXIC BY-PRODUCTS.
===================== Ecological Information =====================
Ecological:THESE BATTERIES PASS THE U.S. EPA'S TOXICITY CHARACTERISTIC
LEACHING PROCEDURE AND THEREFORE, MAY BE DISPOSED OF WITH NORMAL
WASTE.
==================== Disposal Considerations ====================
Waste Disposal Methods:NO SPECIAL PRECAUTIONS ARE REQUIRED FOR SMALL
QUANTITIES. LARGE QUANTITIES OF OPEN BATTERIES SHOULD BE TREATED
AS HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATIONS. DO NOT INCINERATE, SINCE BATTERIES
MAYEXPLODE AT EXCESSIVE TEMPERATURES.
=================== MSDS Transport Information ===================
Transport Information:DOT HAZARD CLASS/DOT SHIPPING NAME: NOT
APPLICABLE.
===================== Regulatory Information =====================
Federal Regulatory Information:ALL INGREDIENTS LISTED IN TSCA
INVENTORY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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