===================== Product Identification =====================
MSDS NAME:277 ALKALINE IODIDE AZIDE REAGENT
NIIN:00F004613
Status Code:A
MSDS Number: CJHYQ
=== Responsible Party ===
Company:HACH CO
Box:389
City:LOVELAND
State:CO
ZIP:80539-0389
Country:US
Info Phone Num:970-669-3050
Emergency Phone Num:800-227-4224
CAGE:91224
=== Contractor Identification ===
Company:HACH CO
Address:5600 LINDBERGH DR
Box:389
City:LOVELAND
State:CO
ZIP:80539
Country:US
Phone:970-669-3050/ 303-623-5716
CAGE:91224
============= Composition/Information on Ingredients =============
Name:SODIUM HYDROXIDE (SARA III)
CAS:1310-73-2
RTECS #:WB4900000
Minumum % Wt:50.
Maxumum % Wt:60.
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:POTASSIUM IODIDE
CAS:7681-11-0
RTECS #:TT2975000
Minumum % Wt:10.
Maxumum % Wt:20.
Name:SODIUM AZIDE (SARA III)
CAS:26628-22-8
RTECS #:VY8050000
< Wt:1.
OSHA PEL:S, C 0.1 PPM(HN3)
ACGIH TLV:C 0.11 PPM; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:60.
Maxumum % Wt:70.
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 27 MG/KG SODIUM AZIDE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYES/SKIN: CAUSES SEVERE BURNS.
HARMFUL IF ABSORBED THROUGH THE SKIN. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE SEVERE BURNS, COLLAPSE & DEATH. INHALATION:
SEVERE BURNS.
Effects of Overexposure:BURNS, ABDOMINAL PAIN, NAUSEA, RAPID PULSE,
RESPIRATIONS, VOMITING, SHOCK, HEADACHE, TACHYCARDIA, COLLAPSE.
IODINES OVERDOSE: SKIN RASH, RUNNY NOSE, HEADACHES, FEVER,
BRONCHITIS, HEADACHE.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE/SKIN/RESPIRATORY
CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. SKIN: WASH
W/PLENTY OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING.
GIVE 1-2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH IF
UNCONSCIOUS. INHALATI ON: REMOVE TO FRESH AIR. GIVE CPR IF
NECESSARY.OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA APPROPRIATE TO SURROUNDING FIRE
CONDITIONS.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF CONTAINED BREATHING
APPARATUS PRESSURE-DEMAND & FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:THIS MATERIAL WILL NOT BURN.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB LIQUID W/NON-REACTIVE SORBENT MATERIAL.
STOP FROM BEING RELEASED TO THE ENVIRONMENT. DIKE TO CONTAIN
MATERIAL FOR LATER DISPOSAL. WORK IN AN APPROVED FUME HOOD. FILTER
TO REMOVE SOLIDS. DILUTE W/EXCESS WATER, ADD AN EXCESS OF AQUEOUS
SODIUM NITRATE.SOLIDIFY SOLUTION. FLUSH REACTED MATERIAL TO THE
DRAIN W/A LARGE EXCESS OF WATER. EVACUATE AREA.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM ACIDS, OXIDIZERS.
Other Precautions:AVOID CONTACT W/EYES, CLOTHING & SKIN. DON'T BREATHE
MIST/VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ADEQUATE VENTILATION.
Ventilation:ADEQUATE VENTILATION
Protective Gloves:DISPOSABLE LATEX GLOVES
Eye Protection:CHEMCIAL SPLASH GOGGLES
Other Protective Equipment:LAB COAT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SODIUM AZIDE PRODUCES A LARGER BLOOD PRESSURE DROP IN PERSONS W/HIGH
BLOOD PRESSURE THAN IN PERSONS W/NORMAL BLOOD PRESSURE.
================== Physical/Chemical Properties ==================
Boiling Pt:>140.C, 284.F
Spec Gravity:1.565
pH:14
Evaporation Rate & Reference:(WATER=1): 0.01
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID; NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, STRONG ACIDS
Stability Condition to Avoid:HEATING, EXCESSIVE EXPOSURE TO AIR,
MOISTURE
Hazardous Decomposition Products:BY HEATING: SODIUM MONOXIDE, IODIDE
COMPOUNDS, NITROGEN OXIDES, IODINE PHOSPHORUS OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:NEVER PUT UNREACTED AZIDES DOWN THE DRAIN.
DISPOSE OF MATERIAL IN AN EPA APPROVED HAZARDOUS WASTE FACILITY.
RINSE THREE TIMES W/AN APPROPRIATE SOLVENT. DISPOSE OF EMPTY
CONTAINER AS NORMAL TRASH. DISP OSE OF IN ACCORDANCE W/LOCAL, STATE
& FEDERAL REGULATIONS. EPA WASTE ID NUMBER: D002; P105.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME: SODIUM HYDROXIDE
SOLUTION. DOT ID NUMBER UN1824. PACKING GROUP II.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 311/312: IMMEDIATE HEALTH HAZARD.
SECTION 313 40 CFR 372: THIS PRODUCT CONTAINS A CHEMICAL SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA. 302
SODIUM AZIDE 500 LBS. 304 CERCLA RQ 1000 LBS. CLEAN WATER ACT
40CFR 116.4 SODIUM HYDROXIDE: RQ=1000 LBS. 454 KGS. RCRA: CONTAINS
RCRA REGULATED SUBSTANCES . SECTIONS 13 EPA WASTE ID NUMBER. CPSC:
THE LABEL FOR THIS PRODUC T BEARS THE SIGNAL WORD POISON: BECAUSE
THE CONCENTRATION OF SODIUM HYDROXIDE IN THE PRODUCT IS GREATER
THAN/EQUAL TO 10%.
Federal Regulatory Information:OSHA: THIS PRODUCT MEETS THE CRITERIA
FOR A HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZARD COMMUNICATION
STANDARD 29CFR 1910.1200.
======================= Other Information =======================
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|