===================== Product Identification =====================
MSDS NAME:BRASS BLACK METAL TOUCH-UP BB2, 170801
NIIN:00N091186
Status Code:A
MSDS Number: CJHYF
=== Responsible Party ===
Company:BIRCHWOOD CASEY
Address:7900 FULLER RD
City:EDEN PRAIRIE
State:MN
ZIP:55344
Country:US
Info Phone Num:612-937-7931
Emergency Phone Num:612-937-7940
Preparer's Name:RICHARD K. WILLIAMS
CAGE:0HLC1
=== Contractor Identification ===
Company:BIRCHWOOD LABORATORIES, INC.
Address:7900 FULLER RD
Box:City:EDEN PRAIRIE
State:MN
ZIP:55344-2138
Country:US
Phone:952-937-7931/FAX 952-937-7979
CAGE:0HLC1
============= Composition/Information on Ingredients =============
Name:SELENIOUS ACID (H*2SEO*3) (% W/W)
CAS:7783-00-8
RTECS #:VS7175000
< Wt:3.
OSHA PEL:0.2 MG/M3
ACGIH TLV:0.2 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:COPPER (II) SULFATE, PENTAHYDRATE (1:1:5); (CUPRIC SULFATE
- CUSO*4-5H*2O) (% W/W)
CAS:7758-99-8
RTECS #:GL8900000
< Wt:4.
Name:PHOSPHORIC ACID; (H*3PO*4) (% W/W)
CAS:7664-38-2
RTECS #:TB6300000
< Wt:8.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ZINC SULFATE (1:1) (ZNSO*4) (% W/W)
CAS:7733-02-0
RTECS #:ZH4800000
< Wt:5.
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:MOLYBDIC ACID, DIAMMONIUM SALT; (AMMONIUM MOLYBDATE
(NH*4)*2MOO*4) (% W/W)
CAS:13106-76-8
RTECS #:QA4960000
< Wt:4.
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
> Wt:76.
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) 1.7 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: PROD IS EYE IRRITANT. IT
CAN CAUSE REDNESS OF EYES, CONJ, IRITIS, SWELL OF EYELIDS,
WATER-MUCOID DISCHARGE & CORNEAL OPACITY. INHAL: TOX FUMES NOT
GENERATED NORMALLY. BRTHG MISTS CAN RSLT IN LOST SENSE OF SMELL,
NOSE & THROAT IRRIT, GARLIC ODOR OF BREATH, HDCH, DIZZ, LASSITUDE,
TREMORS, DFCLTY BRTHG, BRONCH, PNEUMIT, BRONCH ASTHMA. INGEST: MAY
PRDCE METALLIC TASTE, GARLIC ODOR OF BREA TH, HDCH, DIZZ,
LASSITUDE, NAUS, VOMIT, ABDOM PAIN, DIARR, DFCLTY BRTHG. TARGET
ORGANS: LIVER, KIDNEYS, SPLEEN, LUNGS, HEART, ADRENAL GLANDS,
PANCREAS. SKIN: PROD IS NOT PRIMARY SKIN IRRITANT. HOWEVER , IT CAN
PRDCE (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: REDNESS OF SKIN & SLIGHT EDEMA ON
PRLNGD/RPTD CONTACT. ALSO IT CAN CAUSE SKIN SENSIT IN SOME
INDIVIDUALS. CHRONIC: EYES: NO DATA SPECIFIC TO CHRONIC EXPOS. (SEE
ACUTE EYE EXPOS ABOVE.) INHA L: BESIDES EFTS AS IN ACUTE, CHRONIC
EXPOS MAY CAUSE WEAK, PALLOR, ANEMIA, ENLARGEMENT OF LIVER &
DEGENERATIVE CHGS IN TARGET ORGANS. PRECLUDE FROM CNTCT W/PROD
THOSE W/WILSON'S DISEASE OR DISEASES OF SKIN, LUNGS, LIVER,
KIDNEYS OR GI TRACT. (SEE TOXICOLOGICAL INFO.) SKIN: MAY CAUSE SKIN
SENSIT. TWA 16 MG/M3 AS MIST, BASED ON SELENIUM CONTENT OF PRODUCT.
======================= First Aid Measures =======================
Eyes: IMMED RINSE EYES THOROUGHLY W/CLEAN WATER FOR AT LEAST
15 MIN. INSTILLATION OF AQUEOUS 10% SODIUM THIOSULFATE SOLN IS ALSO
RECOM. CONSULT MD. INHAL: REMOVE FROM EXPOS. IF BRTHG DFCLT,
PROVIDE AR TF RESP OR OXYGEN. CONSULT A MD. WATCH FOR DELAYED PULM
EDEMA. DIURETICS SPEED ELIMINATION OF SELENIUM. VITAMIN B COMPLEX,
VITAMIN C & METHIONINE SUPPLEMENTS ARE RECOM. INGEST: IF BRTHG
DFCLT, PROVID E ARTF RESP OR OXYGEN. IF VICTIM IS CONSCIOUS & NOT
VOMIT, INDUCE EMESIS. SEEK MED ATTN. A DIURETIC WILL SPEED
ELIMINATION OF SELENIUM. VITAMIN B COMPLEX, VITAMIN C & METHIONINE
SUPPLEMENTS ARE RECOM. SKIN: REMOVE CONTAM CLTHG (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
NON-FLAMMABLE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . NON-FLAMMABLE.
Unusual Fire/Explosion Hazard:NON-FLAMMABLE. NON-EXPLOSIVE EXCEPT WITH
WATER-REACTIVE SUBSTANCES.
================== Accidental Release Measures ==================
Spill Release Procedures:REVIEW CURRENT LOCAL, STATE & FED CODES,
STATUTES & REGS TO DETERMINE APPROP AGENCIES TO BE NOTIFIED &
CNDTNS UNDER WHICH THEY SHOULD BE NOTIFIED. RECOVER AS MUCH FREE
LIQ AS POSS & COLLECT IN ACID-RE SISTANT CNTNR. USE ABSORB TO PICK
UP RESIDUE. AVOID DISCHARGING LIQ DIRECTLY INTO SEWER OR SURF
WATERS. CERCLA REPORTABLE QUANTITY IS 1 LB FOR SELENIOUS ACID
(APPROX 5.5 GALLONS OF PROD).
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CO-LOADING OR STORING WITH
CYANIDES, WATER-REACTIVE SUBSTANCES OR STRONG REDUCING AGENTS.
STORE IN ACID-RESISTANT CONTAINERS. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE.
Other Precautions:WORKERS HANDLING THE PRODUCT SHOULD WASH BEFORE
SMOKING OR EATING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED HIGH EFFICIENCY PARTICULATE
FILTER RESPIRATOR, SUPPLIED-AIR RESPIRATOR OR SELF-CONTAINED
BREATHING APPARATUS EACH WITH FULL FACEPIECE, HELMET OR HOOD IS
MISTING IS LIKELY.
Ventilation:LOCAL EXHAUST: TO KEEP MISTS BELOW TLV. MECHANICAL: NO
INFORMATION. SPECIAL: EQUIPMENT FOR CONTAINMENT & COLLECTION OF
MISTS IF SPRAY APPLICATION USED.
Protective Gloves:RUBBER OR PLASTIC GLOVES.
Eye Protection:ANSI APPRVD CHEMICAL WORKER GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . AS
APPROPRIATE TO OPERATION TO GUARD AGAINST CONTAMINATION OF CLOTHING
& PROLONGED OR REPEATED SKIN CONTACT.
Supplemental Safety and Health
FIRST AID PROC: TO AVOID PRLNGD CONTACT. WASH AFFECTED AREAS W/SOAP &
WATER. APPLICATION OF 10% SODIUM THIOSULFATE CREAM HAS BEEN RECOM.
WASTE DISP METH: NUMBER D010 (EP TOXICITY-SELENIUM). WASTES CAN BE
DISPOSED OF THRU LICENSED WASTE DISP COMPANY. TO TREAT LIQ &
CONVERT IT TO SOLID WASTE, ADD 2 (ECOLOGICAL INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=102.2C, 216.F
B.P. Text:APPROX
Vapor Pres:NO DATA
Vapor Density:<1 (AIR=1)
Spec Gravity:1.130 (H*2O=1)
pH:0.99 UNDILUTED
Evaporation Rate & Reference:>1 (ETHYL ETHER=1)
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:ODORLESS BLUE LIQUID.
Percent Volatiles by Volume:OTHER INFO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CYANIDES, WATER-REACTIVE SUBSTANCES, ORGANIC SOLVENTS, OILS, STRONG
REDUCING AGENTS.
Hazardous Decomposition Products:REACTION W/ORGANICS & STRONG REDUCING
AGENTS CAN PRDCE VOLAT ORGANOSELANIDES OR HYDROGEN SELENIDE.
THERMAL DECOMP AFTER EVAP TO DRYNESS CAN PRDCE SELENIUM DIOXIDE
FUMES & OXIDES OF SULFUR & PHOSPHORUS.
=================== Toxicological Information ===================
Toxicological Information:WHILE SELENIUM, COPPER & ZINC ARE CLASSIFIED
AS ESSNTL TRACE ELEMENTS IN ANIMALS, THE REGISTRY OF TOXIC EFTS OF
CHEM SUBSTANCES CITES EXPERIMENTAL EVID OF MUTAGENIC, REPRO &
TUMORIGENIC EFTS OF SELENI TES, ZINC SULFATE & VARIOUS COPPER
CMPDS. IN ANIMAL STUDIES, SELENITES & ZINC SULFATE HAVE PRDCED
FETOTOX & TERATOGENIC EFTS. IMPLICATIONS OF EXPERIMENTAL DATA FOR
HUMAN EXPOS ARE UNCERTAIN. HOWEVER, IT WOULD BE PRUDENT FOR
PREGNANT INDIVIDUALS TO AVOID CNTCT W/PROD. W/REGARD TO
CARCINOGENESIS IN ANIMALS, STATUS OF SELENIUM IS INDEFINIE
ACCORDING TO IARC. AMONG RATS SURVIVING (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:SUPDAT: OUNCES OF DEGREASED STEEL WOOL OR STEEL MACHINING
FINES OR TURNINGS PER GALLON OF DILUTED PROD OR 8 OUNCES PER GALLON
OF CONCENTRATE. STIR FREQUENTLY OR CONTINUOUSLY FOR AT LEAST 2 HRS.
PERIOD ICALLY ADJUST PH DOWN TO 1.5 W/NITRIC ACID. WHEN RXN IS
COMPLETE, ADJUST PH TO 8 W/SODIUM BICARBONATE OR SODIUM HYDROXIDE &
FILTER. LIQ CAN GO DOWN THE DRAIN. TOXICOLOGICAL INFO: 18 TO 24
MONTHS ON DI ETS CONTAINING 4, 7 OR 10 PPM SELENIUM, SOME DEVELOPED
ADENOMA OR LOW-GRADE CARCINOMA IN CIRRHOTIC LIVERS & FEW OTHERS HAD
ADVANCED ADENOMATOID HYPERPLASIA. OTHER ANIMAL OR EPIDEMIOLOGICAL
STUDIES (SA RA III INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:REVIEW CURRENT LOC, STATE & FED STATUTES, CODES,
LAWS & REGS TO DETERMINE CURRENT STATUS & APPROP DISP METH FOR
LISTED INGREDS. WASTE BRASS BLACK BB2 OR ITS SOLNS ARE ASSIGNED EPA
HAZ WASTE NUMBER U20 4 (CNTNS SELENIOUS ACID). PRECIPITATES
FILTERED FROM USED SOLN OR GENERATED FROM TREATING LIQ ARE AS
SIGNED EPA HAZ WASTE (SUPDAT)
=================== MSDS Transport Information ===================
Transport Information:HAZARDOUS MATERIALS DESCRIPTION AND PROPER
SHIPPING NAME (49 CFR 172.101): CORROSIVE LIQUID N.O.S. UN1760/IMCO
CLASS 8 OR CONSUMER COMMODITY ORM-D.
===================== Regulatory Information =====================
SARA Title III Information:ECOLOGICAL INFO: SUGGEST THAT SELENIUM MAY
HAVE ANTI-CARCINOGENIC EFTS. ACCORDING TO NIOSH/OSHA OCCUPATIONAL
HEALTH GUIDELINES FOR CHEMICAL HAZARDS, "ANIMAL DATA SUGGEST THAT
REPEATED EXPOSURE TO SOLU BLE MOLYBDENUM COMPOUNDS MIGHT BE
ASSOCIATED WITH GOUT."
Federal Regulatory Information:HAZARD CLASS (49 CFR 172.101) CORROSIVE
MATERIAL OR NOT APPLICABLE FOR ORM-D.
State Regulatory Information:FOLLOWING INGREDS ARE LISTED UNDER
MICHIGAN CRITICAL MATLS REGISTER, ACT 293 OR HAZ WASTE MANAGEMENT
ACT, ACT 64 OF 1981: FROM TABLE 302B - SELENIOUS ACID (ID #: A204,
PARAMETER #: 7783-00-6); FROM TA BLE 303 - COPPER & CMPDS (ID #:
001D, PARAMETER #: CLASS-01-8); FROM TALBE MISCELLANEOUS -- COPPER
& CMPDS (ID #: NONE, PARAMETER #: CLASS-01-7) & ZINC & CMPDS (ID #:
NONE, PARAMETER #: CLASS-02-7).
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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