===================== Product Identification =====================
MSDS NAME:HYDROCHLORIC ACID SOLUTIONS
NIIN:00-823-8010
Status Code:A
MSDS Number: CJHWW
=== Responsible Party ===
Company:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637
Preparer's Name:J.C. WATTS
Chemtrec Ind/Phone:(800)424-9300
CAGE:18873
=== Contractor Identification ===
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-99-M-C727
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:HYDROGEN CHLORIDE (20 DEG = 31.5%, 22 DEG = 36.2%, 23 DEG =
37.1%)
CAS:7647-01-0
RTECS #:MW4025000
Minumum % Wt:31.5
Maxumum % Wt:37.1
Other REC Limits:AEL 5 PPM (DUPONT)
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:62.9
Maxumum % Wt:68.5
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, TEETH,
RESPIRATORY AND GASTROINTESTINAL TRACTS (HMIS). HUMAN HEALTH
EFFECTS - THIS PRODUCT IS CORROSIVE. OVEREXPOSURE BY SKIN CONTACT
INCLUDE SKIN BURNS OR ULCERATION. EYE CONTACT MAY CAUSE EYE
CORROSION WITH CORNEAL OR CONJUNCTIVAL ULCERATION. BY INHALATION,
THE EFFECTS INCLUDE DENTAL EROSION, IRRITATION OF THE UPPER
RESPIRATORY PASSAGES, WITH COUGHING AND DISCOMFORT. FATALITY MAY
OCCUR FROM GROSS OVEREXPOSURE. INGESTION CAUSES SEVERE ACID BURNS
OF THE MOUTH, THROAT, ESOPHAGUS, AND STOMACH WITH PAIN. VOMITING
AND DIARRHEA OF DARK BLOOD MAY OCCUR WITH PENETRATION O F THE
ESOPHAGUS OR STOMACH.
Effects of Overexposure:SKIN BURNS OR ULCERATION, EYE CORROSION WITH
CORNEAL OR CONJUNCTIVAL ULCERATION, DENTAL EROSION, IRRITATION OF
THE UPPER RESPIRATORY PASSAGES, COUGHING AND DISCOMFORT, DEATH,
SEVERE ACID BURNS OF THE MOUTH, THROAT, ESOPHAGUS, AND STOMACH
WITH PAIN, VOMITING AND DIARRHEA OF DARK BLOOD
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:SKIN: IMMEDIATELY SHOWER EXPOSED AREA WITH WATER WITHIN
SECONDS AFTER CONTACT AND REMOVE CONTAMINATED CLOTHING. FLUSH SKIN
FOR AT LEAST 5 MINUTES. CALL FOR MEDICAL HELP WHILE FLUSHING THE
SKIN. EYE: I MMEDIATELY FLUSH WITH LARGE AMOUNT OF WATER WHILE
HOLDING EYELIDS APART. CONTINUE FLUSHING FOR AT LEAST 5 MINUTES.
CALL A PHYSICIAN IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING.
GIVE LARGE QUANTITIE S OF WATER. CALL A PHYSICIAN IMMEDIATELY AND
TRANSFER PROMPTLY TO MEDICAL FACILITY. INHALATION: PERSONS EXPOSED
TO LARGE CONCENTRATIONS OF MATERIAL SHOULD BE GIVEN 100% HUMIDIFIED
OXYGEN (6 LITERS PER MINUTES). CALL A PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING MATERIAL. USE
WATER SPRAY TO COOL TANK/CONTAINERS AND REDUCE VAPORS. RUN-OFF FROM
FIRE CONTROL MAY BE A POLLUTION HAZARD.
Fire Fighting Procedures:NEUTRALIZE WITH LIME, SODA ASH, ETC., TO
PREVENT CORROSION OF METALS AND FORMATION OF HYDROGEN. WEAR FULL
PROTECTIVE CLOTHING WITH HOOD AND BREATHING AIR SUPPLY.
Unusual Fire/Explosion Hazard:MAY GENERATE FLAMMABLE, POTENTIALLY
EXPLOSIVE HYDROGEN GAS ON CONTACT WITH MOST METALS. EXPLOSIVE
CONCENTRATIONS OF HYDROGEN MAY ACCUMULATE INSIDE METAL EQUIPMENT.
HYDROCHLORIC ACID FUMES MAY BE RELEA SED FROM HEATING UNDER FIRE
CONDITIONS. FOLLOW APPROPRIATE NATIONAL FIRE PROTECTION ASSOCIATION
(NFPA) CODES.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE PERSONNEL. KEEP UPWIND OF LEAK. WEAR
SELF CONTAINED BREATHING APPARTUS (SCBA) AND FULL PROTECTIVE GEAR.
DIKE SPILL. PREVENT MATERIAL FROM ENTERING SEWERS, WATERWAYS, OR
LOW AREAS. FOLLOW APPL ICABLE LOCAL, STATE, AND FEDERAL LAWS AND
REGULATIONS. FLUSH AWAY TRACES WITH WATER. NEUTRALIZE SPILL WITH
LIME, SODA ASH. DO NOT FLUSH TO SEWER BEFORE NEUTRALIZATION.
Neutralizing Agent:SODA ASH OR LIME.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PLACE. KEEP CONTAINER
TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS AND FLAMES. DO NOT
STORE OR MIX WITH CYANIDES, SULFIDES, OR FORMALDEHYDE. PROTECT
CONTAINERS FROM DAMAGE.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. AVOID
BREATHING VAPORS OR MIST. WASH THOROUGHLY AFTER HANDLING. NIOSH
IDLH FOR HYDROCHLORIC ACID IS 50 PPM. THIS IS USED ONLY TO SELECT
RESPIRAOR FOR THE H EALTHY WORKER POPULATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE LIMITS MAY BE EXCEEDED, WEAR NIOSH
APPROVED RESPIRATORY PROTECTION.
Ventilation:USE SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW
RECOMMENDED LIMITS.
Protective Gloves:NEOPRENE RUBBER WHERE THERE IS POTENTIAL FOR SKIN
CONTACT
Eye Protection:CHEMICAL SPLASH GOGGLES AND FULL-LENGTH FACE SHIELD OR
AN ACID HOOD
Other Protective Equipment:RUBBER BOOTS, FULL ACID SUIT OF NEOPRENE,
VINYL, OR OTHER ACID RESISTANT MATERIAL WITH HOOD, GLOVES, AND
SELF-CONTAINED BREATHING APPARATUS, EYE BATH, WASHING FACILITY,
EMERGENCY SHOWER
Work Hygienic Practices:WASH PROTECTIVE CLOTHING AND EQUIPMENT UNDER A
SAFETY SHOWER AFTER EXPOSURE OR SUSPECTED EXPOSURE TO HYDROCHLORIC
ACID.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:=50.C, 122.F
B.P. Text:122F - 183F
Melt/Freeze Pt:=-52.5C, -62.5F
M.P/F.P Text:-82.5 TO -87
Vapor Pres:35 @ 77F
Spec Gravity:1.16 - 1.184
pH:<1
Evaporation Rate & Reference:> 1 (BUTYL ACETATE = 1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS TO LIGHT YELLOW LIQUID WITH AN
ACRID, PUNGENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CYANIDES, SULFIDES, ORGANICS, MOST METALS, OXIDIZING AGENTS,
FORMALDEHYDE, ALKALIES
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS
=================== Toxicological Information ===================
Toxicological Information:ANIMAL DATA: INHALATION - 1 HR- LC50 (RATS):
2,810 PPM. ORAL LD50 (RABBITS): 900 MG/KG. THE COMPOUND IS
CORROSIVE TO EYES & SKIN. TOXIC EFFECTS INCLUDE: RESPIRATORY
IRRITATION, CORNEAL OPACITY & CORRO SION OF MUCOSAL SURFACES.
EFFECTS FROMPROLONGED & REPEATED EXPOSURE: CHANGES TO NASAL CAVITY
WITH NECROSIA, REDUCED WEIGHT GAIN, DECREASED LIVER WEIGHT. EFFECTS
FROM INGESTION: GASTRIC MUCOSAL DAMAGE, DECREASED WEIGHT GAIN,
MORTALITIES, NON-SPECIFIC CHANGE, DECREASE IN RELATIVE & ABSOLUTE
SPLEEN. TESTS HAVE NOT BEEN PERFORMED FOR MUTAGENIC, DEVELOPMENTAL
OR REPRODUCTIVE EFFECTS.
===================== Ecological Information =====================
Ecological:ECOTOXICOLOGICAL DATA: AQUATIC TOXICITY: 96 HOUR LC50
(MOSQUITO FISH): 282 MG/L. SLIGHTLY TOXIC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL LAWS AND REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT/IMO: PROPER SHIPPING NAME: HYDROCHLORIC ACID,
HAZARD CLASS: 8; UN NO.: 1789; DOT/IMO LABEL: CORROSIVE; PACKING
GROUP: II.
===================== Regulatory Information =====================
SARA Title III Information:TITLE III SECTIONS 311/312: ACUTE-YES;
CHRONIC-YES; FIRE-NO; REACTIVITY-NO; PRESSURE-NO. SARA EXTREMELY
HAZARDOUS SUBSTANCE-ONLY HYDROGEN CHLORIDE GAS; SARA TOXIC
CHEMICAL-YES.
Federal Regulatory Information:SUPERFUND REPORTABLE DISCHARGE-5000 LB.
TSCA INVENTORY STATUS: REPORTED/INCLUDED. CERCLA HAZARDOUS
SUBSTANCE-YES.
State Regulatory Information:NONE SPECIFIED BY MANUFACTURER.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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