===================== Product Identification =====================
MSDS NAME:SHELL TURBINE FUEL, JP-5 WITHOUT FSII, 23141
NIIN:00N091285
Status Code:A
MSDS Number: CJHXM
=== Responsible Party ===
Company:SHELL OIL COMPANY
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-473-9461;713-241-2252
Emergency Phone Num:713-473-9461
Resp. Party Other MSDS Num.:52138-01
Chemtrec Ind/Phone:(800)424-9300
CAGE:54527
=== Contractor Identification ===
Company:SHELL OIL COMPANY
Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527
============= Composition/Information on Ingredients =============
Name:KEROSENE
CAS:8008-20-6
RTECS #:OA5500000
> Wt:96.5
Name:MINOR ADDITIVES
< Wt:.5
Name:NAPHTHALENE
CAS:91-20-3
RTECS #:OJ0525000
Minumum % Wt:0.
Maxumum % Wt:3.
OSHA PEL:50 MG/M3;10 PPM
ACGIH TLV:52 MG/M3;10 PPM
ACGIH STEL:79 MG/M3;15 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HLTH EFTS NOTED BELOW ARE CONSISTENT
W/REQS UNDER OSHA HAZ COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT: BASED ON ESSENTIALLY SIMILAR PROD TESTING, LIQ IS
PRESUMED TO BE MINIMALLY IRRIT TO E YES. PRLNGD & RPTD CONTACT MAY
BE MORE IRRIT. SKIN CONTACT: BASED ON ESSENTIALLY SIMILAR PROD
TESTING, LIQ IS PRESUMED TO BE MODERATELY IRRIT TO SKIN. PRLNGD &
RPTD CONTACT CAN CAUSE DEFAT & DRYING OF SKIN WHICH MAY RSLT IN
SEV SKIN IRRIT & DERM. INHAL: INHAL OF MISTS MAY BE IRRIT TO UPPER
RESP TRACT. HIGH CONCS MAY RSLT IN CNS DEPRESS & CHEM PNEUMIT.
INGEST: INGEST OF PROD MAY RSLT IN VOMITING (E FTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: ASPIRATION (BRTHG) OF VOMITUS INTO
LUNGS MUST BE AVOIDED AS EVEN SMALL QTYS MAY RSLT IN ASPIRATION
PNEUMONITIS. SIGNS & SYMPS: IRRIT AS NOTED ABOVE. EARLY TO MODERATE
CNS (CENTRAL NERVOUS S YSTEM) DEPRESS MAY BE EVIDENCED BY
GIDDINESS, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON & DEATH MAY
OCCUR. ASPIR PNEUMIT MAY BE EVIDENCED BY COUGH, LABORED BRTHG &
CYANOSIS (BLUISH SKIN); IN SEV CASE S DEATH MAY OCCUR. OTHER HLTH
EFTS: NAPHTHALENE DID NOT CAUSE CANCER IN LIFETIME STUDIES IN RATS
& MICE. CONDUCTED BY NTP. KIDNEY DMG MAY RSLT FOLLOWING ASPIR
PNEUMIT. SEE TOXICOLOGICAL INFO FOR ADDNL HLTH INFO.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
Eyes: FLUSH EYES W/WATER. IF IRRIT OCCURS, GET MED ATTN.
SKIN: REMOVE CONTAM CLTHG/SHOES & WIPE EXCESS FROM SKIN. FLUSH SKIN
W/WATER. FOLLOW BY WASHING W/SOAP & WATER. IF IRRIT OCCURS, GET MED
ATTN. D O NOT REUSE CLTHG UNTIL CLEANED. INHAL: REMOVE VICTIM TO
FRESH AIR & PROVIDE OXYGEN IF BRTHG IS DFCLT. GET MED ATTN. INGEST:
DO NOT INDUCE VOMIT. IF VOMIT OCCURS SPONT, KEEP HEAD BELOW HIPS TO
PVNT AS PIR OF LIQ INTO LUNGS. GET MED ATTN. NOTE TO MD: IF MORE
THAN 2.0 ML/KG HAS BEEN INGESTED & VOMIT HAS NOT OCCURRED, EMESIS
SHOULD BE INDUCED W/SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO
PVNT ASPIR. IF SYMPS SUCH AS LOSS (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=60.C, 140.F
Lower Limits:0.7%
Upper Limits:5.0%
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON
DIOXIDE. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT
AND CAN BE REIGNITED ON SURFACE OF WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTOVE
EQUIPMENT . CAUTION. COMBUSTIBLE. DO NOT ENTER CONFINED FIRE SPACE
W/OUT FULL BUNKER GEAR. COOL FIRE EXPOSED CONTAINERS WITH WATER. IN
THE CASE OF LARGE FIRES, ALSO COOL SURROUNDING EQUIPMENT AND
STRUCTURES WITH WATER.
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP
WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO
DIRECT FLAME CONTACT SHO ULD BE COOLED WITH LARGE QUANTITIES OF
WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:CAUTION. COMBUST. LG SPILLS: ELIM POTNTL
SOURCES OF IGNIT. WEAR APPROP NIOSH APPRVD RESP & OTHER PROT CLTHG.
SHUT OFF SOURCE OF LEAK ONLY IS SAFE TO DO SO. DIKE & CNTN. REMOVE
W/VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP
RESIDUE W/ABSORB SUCH AS CLAY, SAND OR OTHER SUITABLE MATL; PLACE
IN NON-LEAKING CNTNRS & SEAL TIGHTLY FOR PROPER DISPOSAL. FLUSH
AREA W/WATER TO (SUPDAT)
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP LIQUID & VAPOR AWAY FROM HEAT,
SPARKS & FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN
LIQUID PROD IN ABSENCE OF SPARKS OR FLAME. EXTING PILOT LIGHTS,
CIGARETTES & TURN OF OTHER SOURCE S OF IGNIT PRIOR TO USE AND UNTIL
ALL VAPS ARE GONE. VAPS MAY ACCUMULATE & TRAVEL TO (OTHER INFO)
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE (ONLY)
WITH ADEQUATE VENTILATION. CONTAINERS, EVEN THOSE THAT HAVE BEEN
EMPTIED, CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILL, GRIND,
WELD OR PERFORM OPE RATIONS ON OR NEAR CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS (SEC IV) USE A NIOSH APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER A NIOSH
APPROVED ATMOSPHERE-SUPP LYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT GLOVES - NEOPRENE.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR CLOTHING TO MINIMIZE CONTACT. TEST DATA FROM PUBLISHED
LITERATURE &/OR GLOVE & CLOTHING MFRS INDICATE BEST PROTECTION IF
PROVIDED BY NEOPRENE.
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE.
Supplemental Safety and Health
FIRST AID PROC: OF GAG REFLEX, CONVULSIONS OR UNCON OCCUR BEFORE
EMESIS, GASTRIC LAVAGE USING CUFFED ENDOTRACHEAL TUBE SHOULD BE
CONSIDERED. SPILL PROC: REMOVE TRACE RESIDUE; DISPOSE OF SLUSH SOLN
AS ABOVE. SM SPILLS: TAKE UP W/ABOSRB MATL & PLACE IN NON-LEAKING
CNTNRS FOR PROPER DISPOSAL.
================== Physical/Chemical Properties ==================
Boiling Pt:=160.C, 320.F
Melt/Freeze Pt:=-46.1C, -51.F
Vapor Pres:NOT AVAILABLE
Vapor Density:>1 (AIR=1)
Spec Gravity:0.81 (H*2O=1)
Viscosity:CS (40F): 1
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, WHITE LIQUID; KEROSENE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, FLAME.
Hazardous Decomposition Products:THERMAL DECOMP PRODS ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. COMPLEX MIX OF AIRBORNE SOLID, LIQ,
PARTICULATES & GASES WILL EVOLVE WHEN THIS MATL UNDERGOES PYROLYSIS
OR COMBUST. CARBON (OTHER INFO)
=================== Toxicological Information ===================
Toxicological Information:KEROSENE HAS BEEN SHOWN TO PRDCE SKIN CANCER
IN EXPERIMENTAL ANIMALS UPON RPTD DERMAL APPLICATN OVER LIFETIME OF
ANIMALS & INTERIM RSLTS FROM ONGOING MOUSE SKIN PAINTING STUDY
W/HYDRODESULFURIZED KERO SENE HAVE REPORTED TUMOR PRODUCTION,
HOWEVER, RECENT TWO YR SKIN PAINTING STUDY ON REPRESENTATIVE JP-5
WAS FOUND TO BE NEG FOR CARCIN. PETRO HYDROCARBS OF SIMILAR
COMPOSITION & BOILING RANGE HAVE BEEN SHOWN TO PRDCE KIDNEY DMG &
TUMORS IN MALE RATS FOLLOWING PRLNGD INHAL EXPOS (NOT DISSIMILAR
FROM THOSE EFTS SEEN IN MALE RATS EXPOSED TO VARIOUS PETRO NAPHTHAS
& BLENDED GASOLINE).
===================== Ecological Information =====================
Ecological:UNDER EPA-CWA, THIS PROD IS CLASSIFIED AS AN OIL UNDER
SECTION 311. SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE
SHEEN MUST BE REPORTED TO THE NRC, 800-424-8802. OTHER INFO:
CYTOGENETICS ASSAY. HYDRODESULFURIZED KEROSENE HAS BEEN FOUND
NEGATIVE IN BOTH THESE ASSAYS. NAPHTHALENE WAS NOT MUTAGENIC IN
AMES TEST OR MOUSE OR RAT CELL TRANSFORMATION ASSAY.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNDER EPA - RCRA (40 CFR 261.21), IF THIS
PRODUCT BECOMES A WASTE MATERIAL, IT WOULD BE IGNITABLE HAZARDOUS
WASTE, HAZARDOUS WASTE NUMBER D001. REFER TO LATEST EPA OR STATE
REGULATIONS REGARDING PROPE R DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
CLASS 3 (FLAMMABLE LIQUID), III. DOT PROPER SHIPPING NAME: FUEL,
AVIATION, TURBINE ENGINE. OTHER REQS: UN1863, GUIDE 128.
===================== Regulatory Information =====================
SARA Title III Information:EHS RQ (*1); EHS TPQ (*2) SEC-313 (*3); 313
CATEGORY (*4); 311/312 CATEGORY (*5). *1 = REPORTABLE QUANTITY OF
EXTREMELY HAZ SUBSTANCE, SEC 302. *2 = THRESHOLD PLANNING QTY,
EXTREMELY HAZ SUBSTANCE, SE C 302. *3 = TOX CHEM, SEC 313. *4 =
CATEGORY AS REQD BY SEC 313 (40 CFR 372.65.C), MUST BE USED ON
TOXIC RELEASE INVENTORY FORM. *5 = CATEGORY (FOR AGGREGATE
REPORTING REQUIREMENTS UNDER SARA 311, 312 ). HLTH: H-1 = IMMED
(AUCTE ) HLTH HAZ. H-2 IMMED (ACUTE) HLTH HAZ. H-2 = DELAYED
(CHRONIC) HLTH HAZ. PHYSICAL: P-3 = FIRE HAZARD; P-4 = SUDDEN
RELEASE OF PRESS HAZ; P-5 = REACTIVE HAZARD.
Federal Regulatory Information:COMPONENTS OF THIS PROD ARE LISTED ON
EPA/TSCA INVENTORY OF CHEM SUBSTANCES. PROT OF STRATOSPHERIC OZONE
ARE (PERSUANT TO SECTION 611 OF CLEAN AIR ACT AMENDMENTS OF 1990):
PER 40 CFR PART 82, THIS PRO D DOES NOT CNTN NOR WAS IT DIRECTLY
MFR W/ANY CLASS I OR CLASS II OZONE DEPLETING SUBSTANCES. BASED
UPON DATA AVAILABLE TO SHELL, COMPONENT 2 (MINOR ADDITIVES) IN THIS
PRODUCT IS NOT HAZARDOUS UNDER O SHA HAZARD COMMUNICATION (29 CFR
1910.1200).
State Regulatory Information:FOLLOWING CHEMS ARE SPECIFICALLY LISTED BY
INDIVIDUAL STATE; OTHER PROD SPECIFIC HLTH & SFTY DATA IN OTHER
SECTIONS OF MSDS MAY ALSO BE APPLIC FOR STATE REQS. FOR DETAILS ON
YOUR REGULATORY REQS YOU S HOLD CONTACT APPROP AGENCY IN YOUR
STATE. KEROSENE (>96.5):- RI, FL, PA, MA, NJ, CT, LA. NAPHTHALENE
(>0.3) RI, FL, PA, MA, NJ, CT, LA. NAPHTHALENE - (0-3): CA, CT,
FL, IL, LA, MA, ME, MN, NJ, PA, R I.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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