===================== Product Identification =====================
MSDS NAME:ACETIC ACID GLACIAL
NIIN:00-100-2470
Status Code:A
MSDS Number: CJKZG
=== Responsible Party ===
Company:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:908-859-2151
Emergency Phone Num:908-859-2151
Chemtrec Ind/Phone:(800)424-9300
CAGE:62910
=== Contractor Identification ===
Company:AMEND DRUG AND CHEMICAL CO
Address:83 CORDIER ST
Box:City:HILLSIDE
State:NJ
ZIP:07205
Country:US
Phone:201-926-0333
CAGE:20979
Company:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910
============= Composition/Information on Ingredients =============
Name:ACETIC ACID GLACIAL
CAS:64-19-7
RTECS #:AF1225000
= Wt:100.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 MG/M3;10 PPM
ACGIH TLV:25 MG/M3;10 PPM
ACGIH STEL:37 MG/MG; 15 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 3,310 MG/KG
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY
SYSTEM, TEETH (NIOSH). ACUTE - NHALATION: CONCENTRATED VAPORS MAY
CAUSE SERIOUS DAMAGE TO LINING OF NOSE, THROAT, LUNGS. BREATHING
DIFFICULTIES MAY OCCUR. INGEST ION: CAN CAUSE SEVERE INJURY LEADING
TO DEATH. SYMPTOMS INCLUDE SORE THROAT, VOMITING, DIARRHEA.
INGESTION OF AS LITTLE AS 1 ML HAS CAUSED PERFORATION OF ESOPHAGUS.
SKIN: MAY CAUSE SERIOUS DAMAGE. EFF ECTS MAY INCLUDE REDNESS, PAIN,
BURNS. HIGH VAPOR CONCENTRATIONS MAY CAUSE SKIN SENSITIZATION. EYE:
MAY CAUSE SEVERE DAMAGE AND LOSS OF SIGHT. CHRONIC - EROSION OF
TEETH, INFLAMMATION OF NOSE, THROAT, BRONICHIAL TUBES, DARKENING
OF SKIN.
Explanation of Carcinogenicity:NOT LISTED (HMIS)
Effects of Overexposure:CONENTRATED VAPORS MAY CAUSE SERIOUS DAMAGE TO
LINING OF NOSE, THROAT, LUNGS. BREATHING DIFFICULTIES MAY OCCUR.
MAY CAUSE EROSION OF TEETH. INGESTION: CAN CAUSE SEVERE INJURY
LEADING TO DEATH. SYMPTOM S INCLUDE SORE THROAT, VOMITING,
DIARRHEA. MAY CAUSE SERIOUS SKIN DAMAGE. EFFECTS MAY INCLUDE
REDNESS, PAIN, BURNS. HIGH VAPOR CONCENTRATIONS MAY CAUSE SKIN
SENSITIZATION, TEARING, SEVERE EYE IRRITATI ON. EYE CONTACT MAY
CAUSE SEVERE DAMAGE AND LOSS OF SIGHT.
======================= First Aid Measures =======================
First Aid:NHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE
QUANTITIES OF WAT ER OR MILK IF AVAILABLE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN EXPOSURE: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. CALL A PHYSICIAN. EYE EXPOSURE:
WASH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING
LOWER AND UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=40.C, 104.F
Autoignition Temp:=427.C, 800.6F
Lower Limits:5.4
Upper Limits:16
Extinguishing Media:WATER. DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER
SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE
CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE.WATER M . WATER MAY BE USED TO FLUSH SPILLS AWAY
FROM EXPOSURES AND TO DILUTE SPILLS TO NON-FLAMMABLE MIXTURES.
Unusual Fire/Explosion Hazard:WATER DILUTED ACID CAN REACT WITH METALS
TO FORM HYDROGEN GAS. ABAOVE FLASH POINT, VAPOR-AIR MIXTURES ARE
EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. VAPORS CAN FLOW
ALONG SURFACES TO DISTANT IGNIT ION SOURCE AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. ISOLATE HAZARD AREA.
KEEP UNPROTECTED PERSONNEL AWAY. USE WATER SPRAY TO DILUTE SPILL TO
A NONFLAMMABLE MIXTURE. CONTA IN AND RECOVER LIQUID WHEN POSSIBLE.
COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR ABSORB WITH AN INERT
MATERIAL AND PLACE IN A CHEMICAL WASTE CONTAINER. DO NOT FLUSH TO
SEWERS. DO NOT USE COMBUSTIBLE
Neutralizing Agent:SODIUM BICARBONATE (HMIS)
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. PROTECT FROM
FREEZING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN.
EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE
ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL
FACEPIECE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE MAY BE WORN UP TO
TEN TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION
SPECIFIED BY THE RESPIRATOR SUPPLIER, WHICHEVER IS LESS.FOR
EMERGENCIES OR INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN,
USE A POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GOGGLES AND/OR A FULL FACE SHIELD
Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH
FACILITIES IN WORK AREA. WEAR IMPERVIOUS PROATECTIVE CLOTHING,
INCLUDING BOOTS, GLOVES, LAB COAAT, APRON OR COVERALLS, AS
APPROPRIATE, TO PREVENT SKIN CONTACT
Supplemental Safety and Health
WARNING: AIR PURIFYING RESPIRATORS SO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMO-SPHERES. BUTYL RUBBER AND TEFLON WILL
BREAKTHROUGH TIMES GREATER THAT 8 HOURS ARE SUITABLE MATERIALS FOR
PERSONAL PRO TECTIVE RQUIPMENT. ACETIC ACID CONTRACT SLIGHTLY UPON
FREEZING WHICH MAY CAUSE THE CONTAINER TO BURST.
================== Physical/Chemical Properties ==================
HCC:F6
Boiling Pt:=117.8C, 244.F
Melt/Freeze Pt:=16.7C, 62.F
Vapor Pres:11 @ 20C
Vapor Density:2.1
Spec Gravity:1.05
Evaporation Rate & Reference:0.97 (BUAC=1)
Solubility in Water:INFINITE IN WATER
Appearance and Odor:CLEAR COLORLESS LIQUID, STRONG VINEGAR-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, MOST METALS, CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID,
STRONG CAUSTICS, HEAT FLAME. AVOID CONTACT WITH CARBONATES,
HYDROXIDE, OXIDES, PHOSPHATES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. HEAT AND SUNLIGHT CAN CONTRIBUTE TO INSTABILITY.
RELEASES HEAT AND TOXIC, IRRITATING VAPORS WHEN MIXED WITH WATER.
Hazardous Decomposition Products:CARBON DIOXIDE, AND CARBON MONOXIDE
MAY FORM WHEN HEATED TO DECOMPOSITION. WILL ALSO RELEASE TOXIC AND
IRRITATING VAPORS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:SKIN RABBIT LD50: 1.06 G/KG
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE AND APPROVED WASTE
DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT
MAY CHANGE WASTE MANAGEMEN T OPTIONS. US REGULATIONS REQUIRE
REPORTING SPILLS IN EXCESS OF REPORTABLE QUANTITIES (5000 LBS), TO
NRC 424-8802.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE
(EHS) THRESHOLD PLANNING QUANTITY (TPQ) = 10,000 LBS. SECTION 313
CHEMICALS: TOXIC SUBSTANCE SUBJECT TO ANNUAL REPORTING REQUIREMENTS
LISTED AT 40 CFR 372.65. CERCLA SEC. 103: COMPREHENSIVE
ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (SUPERFUND),
RELEAE TO AIR, LAND OR WATER OF THESE HAZARDOUS SUBSTANCES WHICH
EXCEED THE REPORTABLE QUANTITY (RQ) MUST BE REPORTED TO THE
NATIONAL RESPONSE CENTER, (800-424-8802); LISTED AT 40 CFR 302.4
Federal Regulatory Information:RCRA: RESOURCE CONSEVATION AND RECOVERY
ACT. COMMERCIAL CHEMICAL PRODUCT WASTES DESIGNATED AS ACUTE HAZARDS
OR TOXIC UNDER 40 CFR 261.33. ACETIC ACID IS LISTED ON THE TSCA
INVENTORY.
State Regulatory Information:
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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