===================== Product Identification =====================
MSDS NAME:FLUOBORIC ACID, 9528
NIIN:00N091412
Status Code:A
MSDS Number: CJKZZ
=== Responsible Party ===
Company:J.T. BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:1-800-582-2537
Emergency Phone Num:908-859-2151;800-424-8802(NRC)
Resp. Party Other MSDS Num.:F2608 -02
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:50.
Maxumum % Wt:52.
Name:BORATE (1-), TETRAFLUORO-, HYDROGEN; (FLUOBORIC ACID
(HBF4)) FORMULA: HBF*4, FORMULA WT: 87.81
CAS:16872-11-0
RTECS #:ED2685000
Minumum % Wt:48.
Maxumum % Wt:50.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: IRRITATION OF NOSE
AND THROAT. SKIN CONTACT: SEVERE IRRITATION OR BURNS. EYE CONTACT:
SEVERE IRRITATION OR BURNS. SKIN ABSORPTION: NONE IDENTIFIED.
INGESTION: MAY BE FATAL. CHRONIC: NONE IDENTIFIED. TARGET ORGANS:
NONE IDENTIFIED.
Explanation of Carcinogenicity:NONE IDENTIFIED.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
======================= First Aid Measures =======================
First Aid:INGESTION: CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE WATER, MILK OR MILK OF MAGNESIA. INHALATION: REMOVE
TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHI NG IS DIFFICULT, GIVE OXYGEN. SKIN: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING & SHOES. WASH CLOTHING BEFORE RE-USE. EYES: IMMEDIATELY
FLUSH WI TH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE IDENTIFIED. TOXIC GASES PRODUCED:
HYDROGEN FLUORIDE. EXPLOSION DATA - SENISITIVITY TO MECHANICAL
IMPACT & STATIC DISCHARGE: NONE IDENTIFIED. BAKER SAF-T-DATA*
SYSTEM: HEALTH; 4 - EXTREME (POISON) ; FLAMMABILITY: 0 - NONE;
REACTIVITY: 2 - MODERATE; CONTACT:4 - EXTREME (CORROSIVE).
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS & FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO
WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR
LIME. WITH CLEAN SHOVEL, C AREFULLY PLACE MATERIAL INTO CLEAN, DRY
CONTAINER & COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
Neutralizing Agent:SODA ASH/LIME. J.T. BAKER NEUTRASORB(R) OR TEAM(R)
'LOW NA+' ACID NEUTRALIZERS ARE FOR SPILLS OF THIS PRODUCT.
====================== Handling and Storage ======================
Handling and Storage Precautions:SAF-T-DATA* STORAGE COLOR CODE: WHITE
(CORROSIVE). KEEP CONTAINER TIGHTLY CLOSED. STORE IN
CORROSION-PROOF AREA. NOTE: WHEN HANDLING LIQUID PRODUCTS,
SECONDARY PROTECTIVE CONTAINERS MUST BE USED FOR C ARRYING.
Other Precautions:POISON! DANGER! CAUSES BURNS, MAY BE FATAL IF
SWALLOWED. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID
BREATHING VAPOR. USE WITH ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, A NIOSH
APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS
RECOMMENDED. IF CONCENTRATION EXCEES CAPACITY OF CARTRIDGE
RESPIRATOR, A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IS
ADVISED.
Ventilation:VENT HOOD. USE ADEQUATE GENERAL OR LOCAL EXHAUST
VENTILATION TO KEEP VAPOR & MIST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
UNIFORM, PROTECTIVE SUIT ARE RECOMMENDED. LAB COAT & APRON.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PHYSICAL DATA: ODOR THRESHOLD (PPM): N/A. COEFFICIENT WATER/OIL
DISTRIBUTION: N/A.
================== Physical/Chemical Properties ==================
Boiling Pt:=265.6C, 510.F
B.P. Text:AT 760 MM HG
Vapor Pres:7 MMHG @ 20C
Vapor Density:3 (AIR=1)
Spec Gravity:1.36 (H*2O=1)
Evaporation Rate & Reference:1 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:COLORLESS LIQUID.
Percent Volatiles by Volume:N/A (@ 21C)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CYANIDES, STRONG BASES.
Stability Condition to Avoid:NONE IDENTIFIED.
Hazardous Decomposition Products:HYDROGEN FLUORIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TOXICITY OF COMPONENTS: LD50:
(INTRAPERITONEAL,MOUSE) 190 G/KG (FOR WATER). LD50:
(INTRAVENOUS,MOUSE) 25 G/KG (FOR WATER). REPRODUCTIVE EFFECTS: NONE
IDENTIFIED.
===================== Ecological Information =====================
Ecological:TRANSPORT INFO: DATA IS MEANT AS A GUIDE TO OVERALL
CLASSIFICATION OF PROD & IS NOT PACKAGE SIZE SPECIFIC, NOR SHOULD
IT BE TAKEN AS A WARRANTY/REPRESENTATION FOR WHICH COMPANY ASSUMES
LEGAL RESPONSI BILITY -- THE INFO IS OFFERED SOLELY FOR YOUR
CONSIDERATION, INVESTIGATION & VERIFICATION. ANY USE OF INFO MUST
BE DETERMINED BY USER TO BE I/A/W APPLIC FED, STATE & LOC LAWS &
REGS. SEE SHIPPER REQUI REMENTS 49 CFR 171.2, CERTIFICATION
172.204, & EMPLOYEE TRAINING 49 CFR 173.1(B). U.S. CUSTOMS
HARMONIZATION NUMBER: 28111900004.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002
(CORROSIVE WASTE).
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC(D.O.T.): PROPER SHIPPING NAME:FLUOBORIC
ACID. HAZ CLASS:8. UN/NA:UN1775. PACKAGING GRP:II. LBLS:8 CORR.
REGULATORY REFERENCES:49 CFR 172.101; 173.283.
INTERNATIONAL(I.M.O.): PROPER SHIPPING N AME:FLUOBORIC ACID. HAZ
CLASS:8. I.M.O. PG:8175. UN:UN1775. MARINE POLLUTANTS:NO. PACKAGING
GRP:II. LBLS:CORR. REGULATORY REFERENCES:49 CFR PART 176; IMDG
CODE. AIR(I.C.A.O.): PROPER SHIPPNG NAME:FLUO BORIC ACID. HAZ
CLASS:8. UN:UN1775. PACKAGING GRP:II. LBLS:CORR. REGULATORY
REFERENCES:49 CFR PART 175; ICAO -- MFR BELIEVES TRANSPORTATION
DATA & REFERENCES CNTND HEREIN TO BE FACTUAL & OPINION OF QU
ALIFIED EXPERTS. (ECOLOGICAL INFO)
===================== Regulatory Information =====================
SARA Title III Information:SARA/TITLE III HAZARD CATEGORIES & LISTS:
ACUTE: YES. CHRONIC: YES. FLAMMABILITY: NO. PRESSURE: NO.
REACTIVITY: NO. EXTREMELY HAZARDOUS SUBSTANCE: NO. CERCLA HAZARDOUS
SUBSTANCE: NO. SARA 313 TOXIC CH EMICALS: NO.
Federal Regulatory Information:TSCA INVENTORY: YES. THE INFORMATION IN
THIS MSDS MEETS THE REQUIREMENTS OF THE U.S. OCCUPATIONAL SAFETY &
HEALTH ACT & REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200
ET. SEQ.) & THE CANADIAN WO RKPLACE HAZARDOUS MATERIALS INFORMATION
SYSTEM.
State Regulatory Information:OTHER INFO: READ ALL PRECAUTIONARY INFO.
AS NEW DOCUMENTED GENERAL SAFETY INFO BECOMES AVAILABLE, BAKER WILL
PERIODICALLY REVISE THIS MSDS. NOTE: CHEMTREC, CANUTEC & NATIONAL
RESPONSE CENTER EMERGENCY TELEPHONE NUMBERS ARE TO BE USED ONLY IN
THE EVENT OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE,
EXPOSURE, OR ACCIDENT INVOLVING CHEMICALS. NON-EMERGENCY QUESTIONS
SHOULD BE DIRECTED TO CUST OMER SERVICE (1-800-JTBAKER) FOR
ASSISTANCE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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