===================== Product Identification =====================
MSDS NAME:ARSENAL HERBICIDE
NIIN:01-356-8902
MSDS Number: CJKWV
=== Responsible Party ===
Company:AMERICAN CYANAMID CO
Address:ONE CYANAMID PLAZA
City:WAYNE
State:NJ
ZIP:07470-4028
Country:US
Info Phone Num:201-831-2000
Emergency Phone Num:201-835-3100
Resp. Party Other MSDS Num.:AG0910107-3
CAGE:05870
=== Contractor Identification ===
Company:AMERICAN CYANAMID CO
Address:ONE CYANAMID PLAZA
Box:City:WAYNE
State:NJ
ZIP:07470-4028
Country:US
Phone:201-831-2000
CAGE:05870
Company:AMERICAN CYANAMID CO
Box:400
City:PRINCETON
State:NJ
ZIP:08540
Country:US
CAGE:3A970
Company:AMERICAN CYANAMID CO
Address:697 RT 46
Box:City:CLIFTON
State:NJ
ZIP:07015
Country:US
Phone:973-683-2000
CAGE:70361
Company:AMERICAN CYANAMID CO, DAVIS AND GECK DIV
Address:1 CYANAMID PLAZA
Box:City:WAYNE
State:NJ
ZIP:07470-4028
Country:US
CAGE:2X913
Company:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
Contract Num:SP0450-00-M-SD79
CAGE:1HB45
Company:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
Contract Num:SP0450-01-M-ZC53
CAGE:1HB45
Company:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
Contract Num:SP0450-99-M-C682
CAGE:1HB45
============= Composition/Information on Ingredients =============
Name:ISOPROPYLAMINE SALT OF IMAZAPYR
CAS:81510-83-0
RTECS #:US5683500
= Wt:28.7
Other REC Limits:NONE SPECIFIED
OSHA PEL:NOT ESTABLISHED.
ACGIH TLV:NOT ESTABLISHED.
Name:INERT INGREDIENTS
= Wt:71.3
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS >5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-MAY CAUSE EYE AND SKIN
IRRITATION. MAY IRRITATE THE RESPIRATORY TRACT. IT IS SLIGHTLY
TOXIC IF INGESTED. CHRONIC-NO INFORMATION GIVEN BY MFR ON MSDS.
Explanation of Carcinogenicity:IMAZAPYR IS NOT LISTED AS A HUMAN
CARCINOGEN BY IARC, OSHA OR NTP, NOR IS THE ISOPROPYLAMINE SALT.
ISOPROPYLAMINE SALTS PRESENT IN THIS FORMULATION IS NOT LISTED AS
AHUMNAN CARCINOGEN BY THE IARC, OSH A OR NTP.
Effects of Overexposure:EYE AND SKIN IRRITATION. DUST/MIST MAY IRRITATE
THE RESPIRATORY TRACT. IT IS SLIGHTLY TOXIC IF INGESTED.
Medical Cond Aggravated by Exposure:A KNOWLEDGE OF THE AVAILABLE
TOXICOLOGY INFORMATION & OF THE PHYSICAL & CHEMICAL PROPERTIES OF
THE MATERIAL SUGGESTED THAT OVEREXPOSURE IS UNLIKELY TO AGGRAVATE
EXISTING MEDICAL CONDITIONS.
======================= First Aid Measures =======================
First Aid:IF ON SKIN: WASH SKIN WITH PLENTY OF SOAP & WATER. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS. IF IN EYES: FLUSH EYES
WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
IF SWALLOWED : DRINK 2 GLASSES WATER, INDUCE VOMITING IF THE PERSON
IS CONSCIOUS. OBTAIN MEDICAL ATTENTION PROMPTLY. IF INHALED: REMOVE
SUBJECT TO FRESH AIR. NOTE TO PHYSICIAN: THERE IS NO SPECIFIC
ANTIDOTE. TREAT MENT OF OVEREXPOSURE SHOULD BE DIRECTED AT THE
CONTROL OF SYMPTOMS & THE CLINICAL CONDITION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>98.9C, 210.F
Autoignition Temp:>93.3C, 200.F
Extinguishing Media:USE WATER, ALCOHOL FOAM, DRY CHEMICAL OR CO2 TO
EXTINGUISH FIRES.
Fire Fighting Procedures:WEAR SELF CONTAINED, POSITIVE PRESSURE
BREATHING APPARATUS AND FULL FIRE FIGHTING PROTECTIVE CLOTHING.
EVACUATE NON-ESSENTIAL PERSONNEL. USE AS LITTLE WATER AS POSSIBLE.
DIKE AREA TO PREVENT PESTICID E RUNOFF. USE SPRAY OR FOG-SOLID
STREAM MAY CAUSE SPREADING.
Unusual Fire/Explosion Hazard:USE WATER SPRAY OR FOG, AS STREAM MAY
SPREAD FIRE. AVOID BODILY CONTACT WITH THE MATERIAL. AVOID
BREATHING DUSTS, VAPORS AND FUMES FROM BURNING MATERIALS. CONTROL
RUN-OFF WATER-IF WATER ENTERS A DRAIN AGE SYSTEM, ADVISE THE
AUTHORITIES DOWNSTREAM.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING &
PERSONAL PROTECTIVE EQUIPMENT. KEEP AWAY FROM DRAINS, SURFACE &
GROUND WATE, & SOIL. DIKE SPILL ARE TO PREVENT SPILL FROM
SPREADING. ABSORB SPILLS WITH AN INERT ABSORBENT SUCH AS GRANULAR
CLAY OR SAWDUST. SHOVEL OR SWEEP THE ABORBED SPILL INTO COVERED
CONTAINERS FOR PROPER DISPOSAL. "SEE OTHER INFORMATION"
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT CONTAMINATE WATER, FOOD, OR
FEED BY STORAGE OR DISPOSAL. STORE IN SECURE, DRY, WELL VENTILATED
SEPARATE ROOM, BUILDING OR COVERED AREA. NOT FOR USE OR STORAGE IN
OR AROUND THE HOME. KEEP AWAY F ROM SOURCES IF IGNITION & PROTECT
FROM EXPOSURE TO FIRE & HEAT. SEGREGATE FROM OXIDIZERS.
Other Precautions:EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT
RESIDUES. DO NOT REUSE. TRIPLE RINSE THE CONTAINER OR LINER
THOROUGHLY & RENDER IT UNUSABLE BY CRUSHING OR PUNCTURING. DISPOSE
OF BOTH THE CONTAINER & THE RINSATE IN A SAFE MANNER. "SEE
SUPPLEMENTAL DATA"
============= Exposure Controls/Personal Protection =============
Eye Protection:WEAR CHEMICAL SPLASH GOGGLES TO PREVENT CONTACT WITH THE
SKIN.
Other Protective Equipment:FOR END-USERS, REFER TO PRODUCT LABEL FOR
PERSONAL PROTECTIVE CLOTHING/EQUIPMENT IF REQUIRED.
Work Hygienic Practices:PREVENT CONTACT WITH SKIN. WASH THOROUGHLY WITH
SOAP AND WATER AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE REUSE.
Supplemental Safety and Health
IT IS THE ULTIMATE RESPONSIBILITY OF THE WASTE GENERATR TO DETERMINE AT
THE TIME OF DISPOSAL WHETHER THIS PRODUCT &/OR "EMPTY" CONTAINER
RESIDUE MEETS ANY HAZARDOUS WASTE CRITERIA.
================== Physical/Chemical Properties ==================
HCC:T5
NRC/State Lic Num:NONE
Spec Gravity:1.04 - 1.07
pH:6.6 - 7.2
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR BLUE LIQUID, SLIGHT AMMONIUM ODOR
Percent Volatiles by Volume:71
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AND REDUCING AGENTS. CORROSIVE TO MILD STEEL AND
BRASS.
Stability Condition to Avoid:NO INFORMATION GIVEN BY MFR ON MSDS.
Hazardous Decomposition Products:COMBUSTION MAY PRODUCE OXIDES OF
CARBON AND NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TOXICOLOGICAL DATA ON THIS PARTICULAR
FORMULATION IS NOT AVAILABLE. HOWEVER, DATA FROM A SIMILAR
FORMULATION PRODUCT HAVE SHOWN THE FOLLOWING; THE ACUTE ORAL LD50
FOR BOTH MALE & FEMALE ALBINO RATS IS >5,000 MG/KG INDICATING THAT
THIS MATERIAL IS NO MORE THAN SLIGHTLY TOXIC IF INGESTED. THE ACUTE
DERMAL LD50 FOR BOTH MALE & FEMALE ALBINO RABBITS IS >2148 MG/KG
INDICATING THAT THIS MATERIAL IS NO M ORE THAN SLIGHTLY TOXIC BY
SINGLE SKIN APPLICATION. THIS FORMULATION MAY BE IRRITATING TO THE
RABBIT EYE & MILDLY IRRITATING TO THE RABBIT SKIN.
TERATOGENICITY-NO TERATOGENIC OR FETOTOXIC EFFECTS WERE FOUND AT
ALL DOSE LEVELS TESTED MICE.
==================== Disposal Considerations ====================
Waste Disposal Methods:TO AVOID DISPOSAL, ALL ATTEMPTS SHOULD BE MADE
TO USE THIS PRODUCT COMPLETELY, IN ACCORDANCE WITH ITS REGISTERED
USE. IF THIS IS NOT POSSIBLE, HANDLE WITH CARE, & DISPOSE IN A SAFE
MANNER. FOLLOW ALL APPLIABLE COMMUNITY, NATIONAL OR REGIONAL
REGULATIONS REGARDING WASTE MANAGEMENT METHODS. " SEE OTHE R
PRECAUTIONS".
===================== Regulatory Information =====================
SARA Title III Information:SECTION 311 AND 312 HAZARD CATEGORIES:
IMMEDIATE HEALTH HAZARD-Y DELAYED HEALTH HAZARD-N FIRE HAZARD-N
REACTIVE HAZARD-N SUDDEN PRESSURE RELEASE HAZARD-N. SECTION 302
EXTREMELY HAZARDOUS SUBSTANCES-NO NE. SECTION 313 TOXIC
CHEMICALS-NONE. CERCLA REPORTABLE QUANTITY ARSENAL HERBICIDE-NONE
KNOWN.
Federal Regulatory Information:RCRA HAZARDOUS WASTE CODE(S) AND
STATEMENT(S) ARSENAL HERBICIDE-NONE KNOWN. IT IS THE RESPONSIBILITY
OF THE WASTE GENERATOR TO DETERMINE IF ANY HAZARDOUS WASTE CODE(S)
APPLY, PRIOR TO DISPOSAL.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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