===================== Product Identification =====================
MSDS NAME:GLYCOL ETHER DM
NIIN:01-377-5075
Status Code:A
MSDS Number: CJQCD
=== Responsible Party ===
Company:CHEMICAL SPECIALISTS AND DEVELOPMENT
Address:5 HACKBERRY LANE
Box:3087
City:CONROE
State:TX
ZIP:77305
Country:US
Info Phone Num:409-756-1065/1083 FAX DAVID /SHANAN
Emergency Phone Num:800-274-5263
Resp. Party Other MSDS Num.:999.0004672-005.001
CAGE:4N760
=== Contractor Identification ===
Company:CHEMICAL SPECIALISTS AND DEVELOPMENT INC
Address:2210 HACKBERRY LN
Box:687
City:CONROE
State:TX
ZIP:77305
Country:US
Phone:409-756-1065
Contract Num:SP0450-99-M-NF06
CAGE:4N760
============= Composition/Information on Ingredients =============
Name:DIETHYLENE GLYCOL MONOMETHYL ETHER
CAS:111-77-3
RTECS #:KL6125000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Health Hazards Acute and Chronic:EYES: MAY CAUSE MILD EYE IRRITATION.
SKIN: MAY CAUSE MILD SKIN IRRITATION. SWALLOWING: SWALLOWING SMALL
AMOUNTS DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL
EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL. INHALATION:
BREATHING SMALL AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS
NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAY BE
AHRMFUL. SYMPTOMS USUALLY OCCUR AT C ONCENTRATION S HIGHER THAN THE
RECOMMENDED EXPOSURE LIMITS. TARGET ORGANS: LIVER, TESTES, KIDNEYS.
Explanation of Carcinogenicity:NO DATA.
Effects of Overexposure:STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING,
DIARRHEA), IRRITATION (NOSE, THROAT, AIRWAYS).
Medical Cond Aggravated by Exposure:PRE-EXISTING DISORDERS OF THE
LIVER, KIDNEYS, TESTES.
======================= First Aid Measures =======================
Eyes:IMMEDIATELY FLUSH GENTLY WITH WATER FOR AT LEAST 15
MINUTES, HOLD EYELIDS APART. IF SYMPTOMS DEVELOP, MOVE AWAY FROM
EXPOSURE. SEEK MEDICAL ATTENTION. SWALLOWING: SEEK MEDICAL
ATTENTION. IF SLEE PY OR DROWSY, NOTHING BY MOUTH. IF
CONSCIOU/ALERT, GIVE SYRUP OF IPECAC OR STICK FINGERS DOWN THROAT.
DO NOT LEAVE PERSON UNATTENDED. SKIN:REMOVE CONTAMINATED CLOTHES.
WASH EXPOSED AREA WITH SOAP & WA TER. IF SYMPTOMS PERSIST, SEEK
MEDICAL ATTENTION. LAUNDER CLOTHES BEFORE RESUE.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=91.7C, 197.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE USED TO EXTINGUISH FIRE BY
COOLING, AND DILUTING LIQUID WITH WATER. WEAR A SELF-CONTAINED
BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE
PRESSURE DEMAND MODE WITH APPR OPRIATE TURN-OUT GEAR AND CHEMICAL
RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY
HEAT, PILOT LIGHTS, OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS
DISTANT FROM MATERIAL HANDLING POINT. NEVER USE WELDING, CUTTING
TORCH ON DRUM(EVEN EMPTY) BECAUSE PRODUCT(EVEN JUST RESIDUE)CAN
IGNITE EXPLOSIVELY
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT
MATERIAL & TRANSFER TO HOOD. LARGE SPILL: ELIMINATE SOURCES OF
IGNITION. EXCLUDE UN PROTECTED PERSONS FROM SPILL AREA UNTIL
CLEAN-UP CPMPLETED. STOP SPILL AT SOURCE. PREVENT FROM SPREADING.
KEEP OUT OF SEWERS, WATERWAYS. NOTIFY AUTHORITIES IF RUN-OFF
OCCURS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS MAY BE HAZARDOUS WHEN
EMPTY. EMPTIES MAY RETAIN RESIDUE (VAPOR. LIQUID AND/OR SOLID). ALL
HAZARD PRECAUTIONS MUST BE GIVEN IN THE MSDS MUST BE OBSERVED. ALL
CONTAINERS SHOULD BE BONDED & GR OUNDED DURING MATERIAL TRANSFERS.
Other Precautions:SUDDEN RELEASE OF HOT ORGANIC VAPORS OR MISTS FROM
PROCESS EQUIPMENT DURING OPERATIONS INVOLVING ELEVATED TEMPERATURES
& PRESSURE, MAY RESULT IN IGNITIONS WITHOUT THE PRESENCE OF OBVIOUS
IGNITION SOUR CES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF OVEREXPOSURE HAS BEEN DETERMINED/ DOCUMENTED,
A NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN
ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REG-ULATIONS ALSO
PERMIT OTHER NIOSH/ MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS.
(SEE SAFETY EQUIPMENT SUPPLIER.) ENGINEERING OR ADMINISTRATIVE
CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:PROVIDE SUFFICIENT MECHANICAL(GENERAL AND/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE.
Protective Gloves:NITRILE RUBBER
Eye Protection:CHEMICAL SPASH GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING AND BOOTS. EMERGENCY EYE
WASH STATIONS & SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE
VICINITY OF POTENTIL EXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:=-85.C, -121.F
Vapor Pres:.000 @ 68F
Vapor Density:4.150
Spec Gravity:1.021 - 1.025
pH:N/D
VOC Grams/Liter:8.51
Viscosity:3.4 CPS
Evaporation Rate & Reference:.02 (N-BUTYL ACETATE)
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON
MONOXIDE.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
=================== Toxicological Information ===================
Toxicological Information:NO DATA.
===================== Ecological Information =====================
Ecological:NO DATA.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:US DOT: COMBUSTIBLE LIQUID, NOS, NA1993, PGIII
(ONLY IF CARRIED IN BULK PACKAGING---CONTAINER LARGER THAN 119
GALLONS).
===================== Regulatory Information =====================
SARA Title III Information:SARA 302 COMPONENTS: NONE. SECTION 311/312
HAZARD CLASS: DELAYED, FIRE. SARA 313 COMPONENTS: DIETHYLENE GLYCOL
MONOMETHYL ETHER, CAS # 111-77-3, 100%.
Federal Regulatory Information:TSCA: THE INTENTIONAL INGREDIENTS OF
THIS PRODUCT ARE LISTED. CERCLA RQ (40 CFR 302.4(A)) : NONE LISTED.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE. NEW
JERSEY RTK LABEL INFORMATION: DIETHYLENE GLYCOL MONOMETHYL ETHER,
CAS # 111-77-3. PENNSYLVANIA RTK LABEL INFORMATION: ETHANOL,
2-(2-METHOXYETHOXY)-, CAS # 111-77 -3.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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