===================== Product Identification =====================
MSDS NAME:59PB,59000 ENAMEL PLUS GLOSS SCREEN INK, 59102 FIRE RED
Status Code:A
MSDS Number: CJSXX
=== Responsible Party ===
Company:NAZDAR CHICAGO
Address:1087 N NORTH BRANCH ST
City:CHICAGO
State:IL
ZIP:60622
Country:US
Info Phone Num:800-736-7636
Emergency Phone Num:703-527-3887
Chemtrec Ind/Phone:(800)424-9300
CAGE:76708
=== Contractor Identification ===
Company:NAZDAR CO
Address:1087 N NORTH BRANCH ST
City:CHICAGO
State:IL
ZIP:60622-4234
Country:US
Phone:312-943-8338
CAGE:FO883
Company:NAZDAR COMPANY
Address:1087 N NORTH BRANCH ST
Box:City:CHICAGO
State:IL
ZIP:60622-4292
Country:US
Phone:312-943-8338;800-736-7636
CAGE:76708
============= Composition/Information on Ingredients =============
Name:RESIN MIXTURES; VP: <1 MMHG @ 20C
Minumum % Wt:29.
Maxumum % Wt:46.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM); (PETROLEUM
DISTILLATE ALIPHATIC HYDROCARBON) VP: 0.5 MMHG @ 20C
CAS:64742-88-7
Minumum % Wt:0.
Maxumum % Wt:31.
Other REC Limits:N/K
OSHA PEL:100 PPM
OSHA STEL:N/K
ACGIH TLV:100 PPM
ACGIH STEL:N/K
CAS:7727-43-7
RTECS #:CR0600000
Minumum % Wt:2.
Maxumum % Wt:27.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
CAS:7439-92-1
RTECS #:OF7525000
Minumum % Wt:3.
Maxumum % Wt:24.
Other REC Limits:N/K
OSHA PEL:0.050 MG/M3
OSHA STEL:N/K
ACGIH TLV:0.15 MG/M3
ACGIH STEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:STODDARD SOLVENT; (PETROLEUM DISTILLATE ALIPHATIC
HYDROCARBON) VP: 2.0 MMHG @ 20C
CAS:8052-41-3
RTECS #:WJ8925000
Minumum % Wt:.1
Maxumum % Wt:22.
Other REC Limits:N/K
OSHA PEL:2900 MG/M3;500 PPM
OSHA STEL:N/K
ACGIH TLV:525 MG/M3;100 PPM
ACGIH STEL:N/K
Name:HYDROTREATED HEAVY NAPHTHA (PETROLEUM); (PETROLEUM
DISTILLATE ALIPHATIC HYDROCARBON) VP: <10 MMHG @ 25C
CAS:64742-48-9
Minumum % Wt:0.
Maxumum % Wt:14.
Other REC Limits:300 PPM (SUPPLIER)
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Minumum % Wt:3.
Maxumum % Wt:13.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
CAS:7440-47-3
RTECS #:GB4200000
< Wt:6.
Other REC Limits:N/K
OSHA PEL:1 MG/M3
OSHA STEL:N/K
ACGIH TLV:0.5 MG/M3
ACGIH STEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:0.
Maxumum % Wt:4.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
Name:XYLENE; (DIMETHYLBENZENE) VP: 6.6 MMHG @ 20C. EXPERIMENTAL
TOXICITY DATA HAS GIVEN THE FOLLOWING RESULTS: ORAL LD50 RAT: 4300
MG/KG; INHALATION LC50 RAT: 6700 PPM
CAS:1330-20-7
RTECS #:ZE2100000
< Wt:2.
Other REC Limits:N/K
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL ETHYL KETOXIME; (ALKYL KETOXIME) VP: 4.0 MMHG @ 20C
CAS:96-29-7
RTECS #:FL9275000
< Wt:2.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:SOLVENT NAPHTHA; (PETROLEUM DISTILLATE AROMATIC
HYDROCARBON) VP: <1 MMHG @ 20C
CAS:64742-94-5
RTECS #:WF3100000
Minumum % Wt:0.
Maxumum % Wt:2.
Other REC Limits:100 PPM (INDUSTRY)
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
CAS:14464-46-1
RTECS #:VV7325000
Minumum % Wt:0.
Maxumum % Wt:.3
Other REC Limits:N/K
OSHA PEL:see Table Z-3
OSHA STEL:N/K
ACGIH TLV:0.05 MG/M3
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 10.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THE FOLLOWING INFO HAS BEEN DEVELOPED
BASED UPON USING PROD AS INTENDED BY MFR. POTENTIAL HLTH EFTS OF
PROD ARE BASED ON HAZS OF ITS COMPONENTS. ACUTE: EYES: EYE CONT
W/LIQ, VAPS/MISTS MAY CAUSE IRRIT , INCL BURNING, TEARING, REDNESS
& SWELL. SKIN: RPTD/PRLNG OVEREXP MAY CAUSE IRRIT/DERM. SYMPS MAY
INCL DRYNESS, CHAPPING & REDNESS. THIS MATL MAY BE ABSORBED THRU
SKIN. SKIN ABSORPTION IS POSS BUT HA RMFUL EFTS ARE NOT EXPECTED
FROM THIS RTE OF EXPOS UNDER NORM CNDTNS OF HNDLG & USE. INHAL:
RPTD & PRLNG OVEREXP MAY CAUSE RESP TRACT IRRIT. SYMPS MAY INCL CNS
DISORDERS SUCH AS HDCH, DIZZ, WEAK & FAT G. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE: IARC
MONOGRAPHS, VOLUME 68, 1998: GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
HUMAN: LUNG. "LEAD COMPOUNDS & I NORGANIC LEAD" IS CLASSIFIED AS AS
A GROUP 2B CARCINOGEN BY IARC. "CHROMIUM & CERTAIN CHROMIUM
COMPOUNDS" IS INCLUDED IN THE NTP AND IARC LISTS OF CARCINOGENS.
Effects of Overexposure:HLTH HAZ: INGEST: MAY CAUSE GI TRACT IRRIT.
SYMPS MAY INCL DROW & DIZZ. MAY CAUSE VOMIT. ASPIR OF MATL INTO
LUNGS MAY CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. CHRONIC/TARGET
ORGANS: RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM
BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING
CONTENTS MAY BE HARMFUL/FATAL. RPTD & PRLNG OVEREXP TO LEAD BY
INGEST MAY CAUSE METALLIC TASTE IN MOUTH, NAUS, DIGESTIVE
DISORDERS, ABDOM CRAMPS & INSOMNIA AS WELL AS BLOOD, NERV, URINARY
& REPRO DISORDERS & BIRTH DEFECTS. LEAD EXPOS NOT NORM EXPECTED
WHEN USING PROD AS INTENDED. (SUP DAT)
Medical Cond Aggravated by Exposure:PREGNANT WOMEN & PERS W/PREEXISTING
HLTH DISORDERS SHOULD CONSULT MD BEFORE USING PROD. RPTD & PRLNG
OVEREXP &/OR INDIVIDUAL SENSITIVITY MAY INCR POTENTIAL FOR & DEGREE
OF ADVERSE HLTH EFTS.
======================= First Aid Measures =======================
Eyes: AFTER INITIAL FLUSHING, REMOVE ANY CONTACT LENSES &
CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. IF IRRIT PERSISTS HAVE
EYES EXAMINED & TESTED BY MED PERSONNEL. SKIN: IMMED WASH W/SOAP &
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING & SHOES. GET MED ATTN IF IRRIT PERSISTS.
THOROUGHLY WASH/DISCARD CLOTHING & SHOES BEFORE REUSE. INHAL:
REMOVE TO FRESH AIR. IF NOT B REATHING, GIVE ARTIFICIAL
RESPIRATION/GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MED
ATTN IF BREATHING IS DIFFICULT. INGEST: DO NOT INDUCE VOMIT. CALL
MD/POISON CONTROL CENTER IMMED. NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=46.1C, 115.F
Lower Limits:1.0%
Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER MAY BE INEFFECTIVE BUT MAY BE USED TO COOL
CONTAINERS. FUMES RELEASED ON BURNING MAY BE TOXIC AND DANGEROUS.
Unusual Fire/Explosion Hazard:OSHA FLAMMABILITY CLASSIFICATION (NFPA):
CLASS II COMBUSTIBLE LIQUID. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS, AND OPEN FLAME. KEEP CONTAINERS TIGHTLY CLOSED.
VAPORS MAY BE HEAVIER THAN AIR AN D CAN TRAVEL TO A SOURCE OF
IGNITION THEN FLASH BACK. CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT
SURFACES AND ELECTRICAL, STATIC OR FRICTIONAL SPARKS). AVOID
CONTACT OR BREATHING VAPORS. VENTILATE AREA. CONTAIN RELEASE AND
REMOVE WITH INERT ABSORBENT. U SE NON-SPARKING TOOLS TO PLACE
MATERIAL IN APPROPRIATE CONTAINER FOR DISPOSAL. THE NATIONAL
RESPONSE CENTER (800-424-8802) AND LOCAL AUTHORITIES SHOULD BE
CONTACTED FOR ANY REPORTABLE SPILL/RELEASE.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE IN A WELL-VENTILATED AREA. FOLLOW
ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED;
CONTAINER MAY RETAIN PRODUCT RESIDUES. STORE IN CLOSED CONTAINERS
IN COOL, DRY, WELL-VENTILATED AREA A WAY FROM SOURCES OF IGNITION.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:SMOKE IN DESIGNATED AREAS ONLY. AVOID PROLONGED OR
REPEATED OVEREXPOSURE TO THIS PRODUCT. KEEP OUT OF REACH OF
CHILDREN. FOLLOW LABEL DIRECTIONS CAREFULLY. DO NOT TAKE
INTERNALLY. HARMFUL OR FATAL IF SWALLOWED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF CONCS OF HAZ INGS EXCEED EXPOS LIMITS LISTED
IN INGS SECTION/IF MATL IS HANDLED UNDER MIST, SPRAY/DUST-FORMING
CNDTNS, AN APPROP HALF MASK/FULL FACE NIOSH APPRVD RESP W/N100
(99.97% EFFICIENCY) CAR TRIDGES SHOULD BE USED. IF NO EXPOS LIMITS
ARE LISTED IN INGS SECTION, FOLLOW GEN SFTY GUIDELINES IN 29 CFR
1910.134 RESP PROT/OTHER APPLIC RESP STANDARD.
Ventilation:USE APPLICABLE ENGINEERING CONTROLS, WORK PRACTICES, AND
PERSONAL PROTECTIVE EQUIPMENT TO ENSURE ALL CONCENTRATIONS ARE KEPT
BELOW EXPOSURE LIMITS.
Protective Gloves:USE NEOPRENE, NITRILE OR OTHER GLOVES RESISTANT TO
CHEMICALS LISTED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . SOLVENT RESISTANT APRONS ARE RECOMMENDED. CONTACT A
REPUTABLE SAFETY SUPPLY COMPANY FOR APPROPRIATE GLOVES.
Work Hygienic Practices:PREVENT PROLONGED SKIN CONTACT W/CONTAM
CLOTHING. WASH W/SOAP & WATER BEFORE EATING, SMOKING/USING TOILET
FACILITIES. SEPARATELY WASH/DISCARD CLOTHING & FOOTWEAR BEFORE
REUSE. (OTHER INFO)
Supplemental Safety and Health
EFTS OF OVEREXP: EXCESS EXPOS TO CRYSTALLINE SILICA IS A KNOWN CAUSE OF
SILICOSIS, A NONCANCEROUS LUNG DISEASE. OVEREXP SHOULD NOT OCCUR
DURING NORM USE. LEAD APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ
LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO .
================== Physical/Chemical Properties ==================
Boiling Pt:>148.9C, 300.F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Viscosity:GREATER THAN WATER
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT TESTED
Appearance and Odor:VISCOUS LIQUID WITH CHARACTERISTIC ODOR.
Percent Volatiles by Volume:38
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS/BASES, OXIDIZING/REDUCING AGENTS AND REACTIVE CHEMICALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT, IGNITION SOURCES,
SPARKS AND OPEN FLAME.
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION, E.G. CARBON MONOXIDE, CARBON DIOXIDE, AND
OTHER NOXIOUS GASES.
=================== Toxicological Information ===================
Toxicological Information:ANIMAL STUDIES: METHYL ETHYL KETOXIME, IN A
CHRONIC ORAL TOXICITY ANIMAL STUDY, PRDCED ADVERSE EFT UPON RED
BLOOD CELLS AT ALL LEVELS TESTED. GROSS HISTOPATHOLOGIC ALTERATIONS
WERE OBSERVED IN SPLEEN, LUNG & KIDNEY. XYLENE CAUSES HARM TO
FETUS IN LAB ANIMAL STUDIES. RELEVANCE OF THESE FINDINGS TO HUMANS
IS UNCERTAIN. RPTD & PRLNG OVEREXP TO HIGH CONCS OF XYLENE HAS BEEN
SUGGESTED TO CAUSE THE FOLL OWING EFTS IN LAB ANIMALS: HEARING
LOSS, MILD REVERSIVLE LIVER EFTS, KIDNEY, LUNG, HEART, SPLEEN &
NERV SYS EFTS. FOR ANIMAL STUDIES, REFERENCE TSCA SECTION 4 TEST
RULE RSLTS/CONT MDR FOR FURTHER DETA ILS.
===================== Ecological Information =====================
Ecological:ECOTOXICITY/ENVIRONMENTAL FATE: NO DATA AVAILABLE. OTHER
INFO: NOTE: DUE TO BROAD SPECTRUM OF COLORS EACH MSDS MAY
REPRESENT, RANGES FROM OF SOME INGS LISTED MAY EXCEED THOSE
SPECIFIED IN THE CANADIAN CONTROLLED PROD REGS. IF SPECIFIC CONC
INFO IS NEEDED TO COMPLY W/THIS REG CONT MFR. EXPOS GUIDELINES: SEE
INGS SECTION "COMPOSITION, INFO ON INGS" FOR OCCUP EXPOS LIMS.
EXCESS CONCS OF NUISANCE DUST S/PARTICULATES NOT OTHERWISE
CLASSIFIED (PNOC)/REGULATED (PNOR) MAY REDUCE VISIBILITY & CAUSE
UNPLEASANT DEPOSITS IN EYES, EARS, & NASAL PASSAGES. (STATE REGS)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
COUNTY, STATE, PROVINCIAL AND FEDERAL REGULATIONS. EMPTIED
CONTAINERS MAY RETAIN HAZARDOUS PROPERTIES. EMPTY CONTAINERS SHOULD
BE DISPOSED OF IN AN ENVI RONMENTALLY SAFE MANNER IN ACCORDANCE
WITH APPLICABLE REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING DESCRIPTION: PRINTING INK. 3,
UN1210, PG III. IN THE U.S., THIS MATERIAL MAY BE RECLASSIFIED AS A
COMBUSTIBLE LIQUID AND IS NOT REGULATED, VIA SURFACE
TRANSPORTATION, IN CONTAINERS LESS THAN 119 GALLONS OR 450 LITERS
[PER 49 CFR 173.120 (B)(2)].
===================== Regulatory Information =====================
SARA Title III Information:THE FOLLOWING CHEMICALS ARE SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA (40 CFR
PART 372): LEAD COMPOUNDS, HEXAVALENT CHROMIUM, XYLENE.
Federal Regulatory Information:ALL INGREDIENTS IN INGREDIENTS SECTION
ARE LISTED ON THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
State Regulatory Information:ECOLOGICAL INFO: THE TLV AND PEL HAS BEEN
ESTABLISHED FOR ALL NON-TOXIC "NUISANCE DUSTS" THAT ARE NOT
OTHERWISE CLASSIFIED AND REFERS TO BOTH ORGANIC AND INORGANIC
DUSTS. EXPOSURE OR GENERATION OF THE SE DUSTS IS NOT ANTICIPATED
DURING NORMAL PRINTING OPERATIONS. THE USE OF DRY PIGMENTS AND
POWDERS, GRINDING OR SANDING OF PRINTED PRODUCTS MAY GENERATE
QUANTITIES OF THESE PARTICULATES. REFER TO INGR EDIENTS SECTION
COMPOSITION, INFORMATION ON INGREDIENTS FOR EXPOSURE LIMITS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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