===================== Product Identification =====================
MSDS NAME:CO-114-2 (PRODUCT CODE 032096-05)
NIIN:01-425-9632
Status Code:A
MSDS Number: CJSVW
=== Responsible Party ===
Company:PRAXAIR SURFACE TECHNOLOGIES INC
Address:1555 MAIN STREET
City:INDIANAPOLIS
State:IN
ZIP:46224-3283
Country:US
Info Phone Num:317-240-2650
Emergency Phone Num:317-240-2209
Preparer's Name:DELMAR BEIGHT
Chemtrec Ind/Phone:(800)424-9300
CAGE:0FGH2
=== Contractor Identification ===
Company:PRAXAIR SURFACE TECHNOLOGIES INC
Address:1555 MAIN STREET
Box:City:INDIANAPOLIS
State:IN
ZIP:46224-3283
Country:US
Phone:317-240-2650
CAGE:0FGH2
Company:STARGHILL TECHNOLOGIES CORP
Address:3850 OAKMAN BLVD
Box:City:DETROIT
State:MI
ZIP:48204-1119
Country:US
Phone:313-933-4141
Contract Num:SP0490-95-D-4037
CAGE:0VYG8
============= Composition/Information on Ingredients =============
Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Name:CHROMIUM
CAS:7440-47-3
RTECS #:GB4200000
Minumum % Wt:20.
Maxumum % Wt:50.
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Minumum % Wt:20.
Maxumum % Wt:50.
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 MG/M3
Name:TUNGSTEN
CAS:7440-33-7
RTECS #:YO7175000
Minumum % Wt:5.
Maxumum % Wt:20.
ACGIH TLV:5 MG/M3
ACGIH STEL:10 MG/M3
Name:FERRO-VANADIUM
CAS:12604-58-9
RTECS #:LK2900000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): UNKNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE- SKIN:MAY CAUSE ALLERGIC
DERMATITIS, USUALLY IN FOLDS OF SKIN. MAY CAUSE ULCERS. EYES: MAY
CAUSE IRRITATION. INGESTION: CENTRAL NERVOUS SYSTEM DEPRESSION.
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY ALSO CAUSE
INTERSITITIAL PNEUMONITIS & SENSITIZATION OF THE RESPIRATORY TRACT
IN SUSCEPTIBLE INDIVIDUALS. CHRONIC- MAY CAUSE SENSITIZATION IN
SUSCEPTIBLE INDIVIDUALS. EYES: CAN CAUSE CORNEAL DAMAGE,
POLYCYTHEMIA, HYPERPLASIA OF THE THYROID GLAND, & DAMAGE TO THE
ALPHA CELLS OF THE PANCREAS. INHALATION: MAY CAUSE EMPHYSEMA OR
PULMONARY FIBROTIC DISEASE. ECZEMA/NEURODERMATITIS FROM NICKEL.
Explanation of Carcinogenicity:NICKEL & CHROMIUM HAVE BEEN DETERMINED
TO CAUSE CANCER IN EXPERIMENTAL ANIMALS (IARC, NTP). NICKEL IS
LISTED AS A PROBABLE HUMAN CARCINGEN. CHROMIUM IS LISTED AS A HUMAN
CARCINOGEN.
Effects of Overexposure:ACUTE- SKIN: REDNESS & PAPULAR FORMATION IN
SUSCEPTABLE INDIVIDUALS. MAY CAUSE ULCERS PROGRESSING TO DRY &
SCALY SKIN, FEVER. EYES: REDNESS & EXCESS REDNESS OF THE
CONJUNCTIVA. INGESTION: MAY CAUSE NA USEA, ABDOMINAL PAIN,
VOMITING, DIARRHEA, DIZZINESS, INCOORDINATION AND OTHER CNS
SYMPTOMS AND BURNING SENSATION. INHALATION: CHEST PAIN, VOMITING,
DIARRHEA, BURNING SENSATION, AND CENTRAL NERVOUS SYS TEM DEPRESSION
SYMPTOMS. CHRONIC- SKIN: MAY SPREAD TO THE WHOLE BODY WITH
LESIONS, ITCHING, SORENESS, BURNING SENSATION & REDNESS SKIN-MAY
CAUSE ALLERGIC DERMATITIS, WITH REDNESS & PAPULAR FORMATION IN
SUSCEPTIBLE INDIVIDUALS, WHICH USUAL
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY ALSO
AGGRAVATE AN EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:SWALLOWING-GIVE AT LEAST 2 GLASSES OF MILK OR WATER. INDUCE
VOMITING, UNLESS PATIENT IS UNCONSCIOUS. CALL A PHYSICIAN.
SKIN-WASH THOROUGHLY WITH SOAP & WATER. INHALATION-REMOVE TO FRESH
AIR. GIVE ARTI FICIAL RESPIRATION IF NOT BREATHING. OXYGEN MAY BE
GIVEN IF NECESSARY. CALL A PHYSICIAN. EYES-FLUSH THOROUGHLY WITH
PLENTY OF WATER. IF DISCPMFORT PERSISTS, SEEK MEDICAL ATTENTION,
PREFERABLY AN OPTHA LMOLOGIST. NOTE TO PHYSICIAN: THE HAZARDS OF
THIS MATERIAL ARE MAINLY DUE TO ITS SENSITIZING & MILD IRRITATING
PROPERTIES. THERE IS NO SPECIFIC ANTIDOTE. TREATMENT OF SHOULD BE
DIRECTED AT THE CONTRO L OF SYMPTOMS & THE CLINICAL CONDITION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:USE SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL
TO EXTINGUISH METAL FIRES. USE APPROPRIATE EXTINGUISHER TO
EXTINGUISH COMBUSTABLE MATERIALS THAT MAY BE IGNITED BY THERMAL
FLAME.
Fire Fighting Procedures:CONSULT AND COMPLY WITH ANSI Z49.1 SAFETY IN
WELDING AND CUTTING, NFPA51B STANDARD FOR FIRE PREVENTION IN USE OF
CUTTING AND WELDING PROCESSES. NFPA51B OXYGEN-FUEL GAS SYSTEMS FOR
WELDING AND CUTTING, AND NFPA58 STANDARD FOR THE STORAGE AND
HANDLING OF LIQUIFIED PETROLEUM GASES.
Unusual Fire/Explosion Hazard:AIRBORNE DUST PARTICLES, ESPECIALLY METAL
DUST, AND ACCUMULATION OF SUCH SHOULD BE TREATED AS EXPLOSIVES. TO
MINIMIZE DANGER FROM DUST EXPLOSIONS, ADEQUATE VENTILATION SHOULD
BE PROVIDED TO SPRAY BOOT H IN ACCORDANCE WITH AMERICAN WELDING
SOCIETY PUBLICATION AWSC2.1-73, AND ACGIH PUBLICATION "INDUSTRIAL
VENTILATION".
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST
HAZARDS AND DISPOSE OF PER WASTE DISPOSAL METHOD.
====================== Handling and Storage ======================
Other Precautions:CAUTION: WHEN THERMAL SPRAYING - ELECTRICITY CAN
CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN
BURN EYES AND SKIN! WEAR RECOMMENDED EYE AND BODY PROTECTION.
FUMES, GAS, & DUST CA N HARM YOUR HEALTH. PROVIDE ENOUGH
VENTILATION AND WEAR RESPIRATORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DEPENDS UPON SPECIFIC USE, CONDITION, AND
LOCATION. IF THERE IS DUSTINESS, WEAR RESPIRATOR SELECTED PER OSHA
1910.134, AND OSHA 29 CFR 1910.252 AND ANSI Z49.1
Ventilation:LOCAL DUST PICK UP AND VENTILATION RECOMMENDED.
Protective Gloves:NOT REQUIRED.
Eye Protection:WHEN DUSTY USE GOGGLES PER OSHA 1910.13.
Other Protective Equipment:SEE ANSI Z49.1, ANSI Z87.1, ANSI Z88.2 FOR
HELMETS, FACE SHIELDS AND GOGGLES.
Supplemental Safety and Health
CAUTION: WHEN THERMAL SPRAYING-ELECTRICITY CAN CAUSE FATAL SHOCK! DO
NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN BURN EYES AND SKIN!
WEAR RECOMMENDED EYE ANDBODY PROTECTION. FUMES, GAS, AND DUST CAN
HARM YOUR HEALTH. PROVIDE ENOUGH VENTILATION AND WEAR
RESPIRATORS.(OTHER INFO)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NONE
Vapor Density:N/VOLATILE
Appearance and Odor:DUSTY DARK GRAY POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:WHEN THERMAL SPRAYING, DECOMPOSITION
PRODUCTS WILL VARY WITH OPERATING CONDITIONS. REASONABLY EXPECTED
DECOMPOSITION INCLUDE OXIDES SUB-OXIDES, AND COMPLEX OXIDES OF
MATERIALS LISTED IN SECTION II.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE PER LOCAL, STATE, AND FEDERAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:PROPER SHIPPING NAME: METAL ALLOY POWDER NOI ITEM
136500 SUB 1.
===================== Regulatory Information =====================
SARA Title III Information:7440-02-0, NICKEL, <5 PERCENT BY WEIGHT .
7440-47-3, CHROMIUM, <50 PERCENT BY WEIGHT. 7440-48-4, COBALT, <50
PERCENT BY WEIGHT.
State Regulatory Information:PROP 65 (CARCINOGEN): WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. CAS #7440-02-0, NICKEL; CAS #7440-47-3, CHROMIUM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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