===================== Product Identification =====================
MSDS NAME:BORIC ACID
NIIN:00N092793
Status Code:A
MSDS Number: CJVHL
=== Responsible Party ===
Company:NORTH AMERICAN CHEMICAL COMPANY
Address:8300 COLLEGE BOULEVARD
City:OVERLAND
State:KS
ZIP:66210
Country:US
Info Phone Num:619-372-2291
Emergency Phone Num:619-372-2291
Chemtrec Ind/Phone:(800)424-9300
CAGE:CANCH
=== Contractor Identification ===
Company:NORTH AMERICAN CHEMICAL COMPANY
Address:8300 COLLEGE BOULEVARD
Box:City:OVERLAND
State:KS
ZIP:66210
Country:US
Phone:619-372-2291
CAGE:CANCH
============= Composition/Information on Ingredients =============
Name:BORIC ACID
CAS:10043-35-3
RTECS #:ED4550000
> Wt:99.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MILD IRRIT TO NOSE & THROAT MAY
OCCUR WHEN PEL/TLV ARE EXCEEDED. EYES: DUST DOES NOT CAUSE IRRIT IN
NORM INDUS USE. SKIN: NON-IRRITATING TO INTACT SKIN. CAN BE READILY
ABSORBED THRU BROKEN/ABRA DED SKIN. INGEST: NOT INTENDED FOR
INGEST. AMTS >1 TEASPOONFUL, WHEN INGESTED, MAY CAUSE GI PROBLEMS.
REPRODUCTIVITY: A HUMAN STUDY OF OCCUP EXPOSED BORATE WORKER
POPULATION SHOWED NO ADVERSE REPRO EF TS. ANIMAL STUDIES OF SIMILAR
ORG BORATES DEMONSTRATED REPRO EFTS IN MALES. TARGET ORGANS: NO
TARGET ORGANS HAVE BEEN DETERMINED IN HUMANS. HIGH DOSE ANIMAL
INGEST STUDIES INDICATE THAT TESTES IS TARG ET ORGAN.
Effects of Overexposure:SYMPTOMS OF ACCIDENTAL OVEREXPOSURE TO BORIC
ACID HAVE BEEN ASSOCIATED WITH INGESTION OR BY ABSORPTION THROUGH
LARGE AREAS OF DAMAGED SKIN. THESE MAY INCLUDE NAUSEA, VOMITING,
AND DIARRHEA, WITH DELAY ED EFFECTS OF SKIN REDNESS AND PEELING.
======================= First Aid Measures =======================
Eyes: CONTINUOUSLY FLUSH, OCCAS LIFTING UPPER & LOWER LIDS,
FOR AT LEAST 15 MINS. GET MED ATTN IF IRRIT PERSISTS. SKIN: IF
IRRIT OCCURS, WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & LGE
AMTS OF WATER . GET MED ATTN IF IRRIT PERSISTS. INHAL: NO SPECIFIC
TREATMENT IS NEC. PRLNG EXPOS TO DUST LEVELS IN EXCESS OF
REGULATORY LIMS SHOULD BE AVOIDED. REMOVE TO FRESH AIR. SUPPORT
BRTHG (GIVE OXYGEN/ARTF R ESP) . INGEST: IF >1 TEASPOONFUL
SWALLOWED, GIVE 2 GLASSES OF WATER TO DRINK & SEEK MED ATTN. NOTE
TO MD: ADULT INGEST OF A FEW GRAMS REQUIRES OBSERVATION ONLY. FOR
INGEST IN EXCESS OF 6 GRAMS, MAINTAIN ADEQ KIDNEY FUNC & (SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:ANY FIRE EXTINGUISHING MEDIA MAY BE USED ON NEARBY
FIRES.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:BORIC ACID IS NOT FLAMMABLE, COMBUSTIBLE,
OR EXPLOSIVE. BORIC ACID PRESENTS NO UNUSUAL HAZARDS WHEN INVOLVED
IN A FIRE. THIS PRODUCT IS AN INERT FIRE RETARDANT. FLAMMABILITY
CLASSIFICATION: FLAMMABILI TY CLASSIFICATION (29 CFR 1910.1200),
NON-FLAMMABLE SOLID.
================== Accidental Release Measures ==================
Spill Release Procedures:MAY DMG TREES & VEGETATION. FOR DRY SPILLS,
SWEEP UP, VACUUM/SHOVEL & PLACE IN CONTRS FOR DISP I/A/W APPLIC
REGS. AVOID CONTAM OF BODIES OF WATER DURING CLEANUP. BORIC ACID
WILL CAUSE LOCALIZED CONTAM OF SURROUNDING WATERS DEPENDING ON AMT
DISSOLVED IN THESE WATERS. SOME DMG TO LOC VEGETATION, FISH, &
OTHER AQUATIC LIFE MAY BE EXPECTED. UNDER USUAL CNDTNS, NO PROT
EQUIP IS REQUIRED. (OTHER INFO)
====================== Handling and Storage ======================
Handling and Storage Precautions:DRY, INDOOR STOR UNDER NORMAL ATM
CNDTNS IS REC. TO MAINTAIN PACKAGE INTEGRITY & TO MIN CAKING OF
PROD, BAGS SHOULD BE HANDLED ON "FIRST-IN-FIRST-OUT" BASIS. GOOD
HOUSEKEEPING SHOULD BE MAINTAINED TO MIN DUST ACCUM & GENERATION.
BORIC ACID MAY CAKE IN MOIST CNDTNS.
Other Precautions:AVOID CONTAMINATION OF FOOD OR FEED. NOT FOR FOOD,
DRUG OR PESTICIDAL USE. PRACTICE GOOD HOUSEKEEPING. REFER TO MSDS.
KEEP OUT OF THE REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROPRIATE NIOSH CERTIFIED RESPIRATORS WHEN
LEVELS ARE EXPECTED TO EXCEED EXPOSURE LIMITS.
Ventilation:USE LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE LEVELS BELOW
EXPOSURE LIMITS.
Protective Gloves:NOT REQUIRED UNDER NORMAL CONDITIONS. WEAR IMPERVIOUS
GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . USE SKIN PROTECTION IF EXCESSIVELY DUSTY OR IF
SKIN IS DAMAGED.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING, AND BEFORE EATING, DRINKING, OR SMOKING.
Supplemental Safety and Health
FIRST AID PROC: FORCE FLUIDS. GASTRIC LAVAGE IS REC FOR SYMPTOMATIC
PATIENTS ONLY. HEMODIALYSIS SHOULD BE RESERVED FOR MASSIVE ACUTE
INGEST/PATIENTS W/RENAL FAILURE. BORIC ACID ANALYSIS OF URINE/BLOOD
IS USEFUL ONLY FOR DOCUMENTING EXPOS & SHOULD NOT BE USED FOR
EVALUATING SEV OF POIS/TO GUIDE TREATMENT. (OTHER INFO)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=169.C, 336.2F
Spec Gravity:1.44 (H*2O=1 @ 4C)
pH:OTHER INFO
Solubility in Water:4.7% @ 20C; 27.5% @ 100C
Appearance and Odor:WHITE GRANULAR OR POWDER SOLID; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BORIC ACID REACTS AS A WEAK ACID WHICH MAY CAUSE CORROSION OF BASE
METALS. REACTION WITH STRONG REDUCING AGENTS SUCH AS METAL HYDRIDES
OR ALKALI METALS WILL GENERATE HYDROGEN GAS WHICH COULD CREATE AN
EXPLOSIVE HAZARD.
Stability Condition to Avoid:FORMS PARTIAL HYDRATE IN MOIST AIR. WHEN
HEATED, WATER IS LOST FORMING METABORIC ACID (HBO*2). ON FURTHER
HEATING, THE MATERIAL IS CONVERTED BORIC ACID (B*2O*2).
Hazardous Decomposition Products:NONE KNOWN.
=================== Toxicological Information ===================
Toxicological Information:EYES: BORIC ACID, WHEN APPLIED TO EYES OF
ALBINO RABBITS (DRAIZE TEST), PRDCED EFTS OF MILD ERYTHEMA, & MILD
TO MOD DISCHARGE IN 5 OF 6 RABBITS. ALL SIGNS SUBSIDED BY 4TH DAY
AFTER APPLICATION. FIFTY YRS OF OCCUP EXPOS HISTORY INDICATES NO
HUMAN EYE INJURY FROM EXPOS TO BORIC ACID. SKIN: BORIC ACID WAS
APPLIED TO SKIN OF ALBINO RABBITS. SLIGHT TO NO IRRIT PERSISTED 72
HRS AFTER APPLICATION. NO EVI DENCE OF TISS DMG WAS FOUND. LOW
ACUTE DERMAL TOXICITY: LD50 FOR RABBITS IS EXPECTED TO BE >2,000
MG/KG OF BODY WT (TEST CONDUCTED PER 16 CFR 1500.41). BORIC ACID IS
NOT ABSORBED THRU INTACT SKIN. (ST ATE REGS)
===================== Ecological Information =====================
Ecological:NOTE: BORON IS THE ELEMENT IN BORIC ACID WHICH IS USED TO
CHARACTERIZE BORATE PROD ECOLOGICAL EFTS. TO CONVERT BORIC ACID TO
BORON MULTIPLY BY 0.1748. FISH TOXICITY: BORON NATURALLY OCCURS IN
SEAWATER AT AVERAGE CONC OF 5 MG B/LITER. IN LAB STUDIES ACUTE
TOXICITY (96-HR LC50) FOR UNDER-YEARLING COHO SALMON (ONCHORHYNCHUS
KISUTCH) IN SEAWATER WAS DETERMINED AS 40 MG B/L (ADDED AS SODIUM
METABORATE) . MIN LETHAL DOSE FOR MINNOWS EXPOSED TO BORIC ACID AT
20C FOR 6 HRS IS 18,000 TO 19,000 MG/L IN DISTILLED WATER, 19,000
TO 19,500 IN HARD WATER. CONT NEHC FOR MORE COMPLETE INFO .
==================== Disposal Considerations ====================
Waste Disposal Methods:SML AMTS OF BORIC ACID CAN USUALLY BE DISPOSED
OF AT MUNICIPAL LANDFILL SITES, & REQUIRES NO SPECIAL TREATMENT.
TONNAGE QTYS ARE NOT HOWEVER, REC FOR LANDFILL, & IF POSS SHOULD BE
REUSED FOR APPROP AP PLICATION. REFER TO STATE & LOC REGS FOR
APPLIC SITE-SPECIFIC REQS. BORIC ACID IS NOT CURRENTLY LIST ED
UNDER ANY SECTIONS OF U.S. (TRANSPORT INFO)
=================== MSDS Transport Information ===================
Transport Information:DOT IDENTIFICATION #: BORIC ACID IS NOT A DOT HAZ
MATL/HAZ SUBSTANCE. INTERNATIONAL TRANSPORTATION: BORIC ACID HAS NO
UN # & IS NOT REGULATED UNDER INTERNATIONAL RAIL, HIGHWAY,
WATER/AIR TRANSPORT REG S. --WASTE DISP METH: ENVIRON PROT AGENCY
(EPA) RCRA. CALIFORNIA HAZ WASTE DESIGNATION: CALIFORNIA IDENTIFIES
SUBSTANCES W/ACUTE LD50 OF LESS THAN 5,000 MG/KG AS "HAZ WASTES".
BORIC ACID IS, THEREFORE , A "HAZ WASTE" IF SPILLED IN CALIFORNIA,
& SHOULD BE HANDLED I/A/W APPLIC STATE REGS.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA (SUPERFUND): NOT LISTED UNDER ANY
SECTION.--FED REGS: RELATING TO HEAVY METAL LIMITATIONS ON
COMPONENTS OF PACKAGING MATLS. FED DRUG AGENCY (FDA): PURSUANT TO
21 CFR 175.104, 175.180, & 181.30, BORIC ACID IS APPRVD BY DFA FOR
USE IN ADHESIVE COMPONENTS OF PACKAGING MATLS, AS COMPONENT OF
PAPER COATINGS ON SUCH MATLS/FOR USE IN MANUFACTURE THEREOF WHICH
MATLS ARE EXPECTED TO COME IN CONT W/D RY FOOD PRODS. WHMIS:
W/EXCEPTION OF 16 SECTION FORMAT, THIS MSDS CONFORMS TO CURRENT
WHMIS STDS. CONT NEHC FOR MORE COMPLETE INFO .
Federal Regulatory Information:TSCA #: 10043-35-3. RCRA (40 CFR 261):
NOT LISTED UNDER ANY SECTION. CLEAN WATER ACT (CWA): BORIC ACID IS
NOT REGULATED BY ANY WATER QUALITY CRITERIA UNDER SECTION 304, IS
NOT LISTED AS PRIORITY POLLU TANT UNDER SECTION 307, & IS NOT
LISTED AS HAZ SUBSTANCE UNDER SECTION 311. SAFE DRINKING WATER ACT
(SDWA): NOT REGULATED UNDER SDWA, 42 USC 300G-1, 40 CFR 141 ET SEQ.
CONSULT STATE & LOC REGS FOR POS S WATER QUALITY ADVISORIES
INVOLVING BORON. OCCUP EXPOS LIMS: BORIC ACID IS LISTED/REGULATED
BY OSHA , CAL OSHA/ACGIH AS "PARTICULATE NOT OTHERWISE
CLASSIFIED"/"NUISANCE DUST". CONEG MODEL LEGISLATION: MEETS ALL
CONEG REQS (SARA REGS)
State Regulatory Information:CALIFORNIA OSHA: PEL 10 MG/M3. CA
PROPOSITION 65: NOT LISTED AS CARCIN/REPRO TOXIN. --TOX INFO:
INHAL: HUMAN EPIDEMIOLOGICAL STUDIES SHOW NO INCR IN PULM DISEASE
IN OCCUP POPULATIONS W/CHRONIC EXPOS T O BORIC ACID & SODIUM BORATE
DUST. INGEST: LOW ACUTE ORAL TOXICITY: LD50 FOR SPRAGUE-DAWLEY RATS
IS 3,500 TO 4,100 MG/KG OF BODY WT. REPRO: A HUMAN STUDY OF OCCUP
EXPOSED BORATE WORKER POPULATION SHOW ED NO ADVERSE REPRO EFTS.
ANIMAL STUDIES INDICATE THAT BORIC ACID REDUCES/INHIBITS SPERM
PRODUCTION, CAUSES TESTICULAR ATROPHY &, WHEN GIVEN TO PREGNANT
ANIMALS DURING GESTATION MAY CAUSE DEVEL CHANGES. CONT NEHC FOR
MORE INFO .
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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