===================== Product Identification =====================
MSDS NAME:GLYCEROL, 5092
Status Code:A
MSDS Number: CJVFT
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151; 800-424-9300
Resp. Party Other MSDS Num.:G4774
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:GLYCEROL; (GLYCERIN MIST)
CAS:56-81-5
RTECS #:MA8050000
Minumum % Wt:90.
Maxumum % Wt:100.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) 12,600 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: DUE TO THE LOW VAPOR
PRESSURE, INHALATION OF VAPORS AT ROOM TEMPERATURES IS UNLIKELY.
INHALATION OF MIST MAY CAUSE IRRITATION OF RESPIRATORY TRACT.
INGESTION: LOW TOXICITY. MAY CAUSE NAUSE A, HEADACHE, DIARRHEA.
SKIN CONTACT: MAY CAUSE IRRITATION. EYE CONTACT: MAY CAUSE
IRRITATION. CHRONIC EXPOSURE: MAY CAUSE KIDNEY INJURY.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR
ANY BREATHING DIFFICULTY. INGESTION: INDUCE VOMITING IMMEDIATELY AS
DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSC IOUS PERSON. GET MEDICAL ATTENTION. SKINCONTACT:
IMMEDIATELY FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION IF
IRRITATION DEVELOPS. EYE CONTACT: IMMEDIATELY FLUSH EYES W/PLENTY
OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS
OCCASIONALLY. GET MEDIC AL ATTENTION IF IRRITATION PERSISTS.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=198.9C, 390.F
Autoignition Temp:=370.C, 698.F
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. WATER SPRAY MAY BE USED TO EXTING SURROUNDING
FIRE & COOL EXPOS CNTNRS. WATER SPRAY WILL ALSO REDUCE FUME &
IRRITANT GASES.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME. ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE
WITHIN FLAMMABLE LIMITS NOTED ABOVE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN EXPOSURE
CONTROLS/PERSONAL PROTECTION. CONTAIN & RECOVER LIQUID WHEN
POSSIBLE. COLLECT LIQUID IN AN APPR OPRIATE CONTAINER OR ABSORB
WITH AN INERT MATERIAL (EG VERMICULITE, DRY SAND, EARTH), & PLACE
IN A CHEMICAL WASTE CONTAINER. DO NOT USE COMBUSTIBLE MATERIALS,
SUCH AS SAW DUST. DO NOT FLUSH TO SEWER!
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE
ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD
HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES THE EXPOS
LIMIT OR MAX USE CONC SPECIFIED BY THE APPROP REGULATORY AGENCY OR
RESP SUPPLIER, WHIC HEVER IS LOWEST. A NIOSH APPRVD FULL-FACE PIECE
DUST/MIST RESP MAY BE WORN UP TO 50 TIMES THE EXPOS LIMIT OR THE
MAX USE CONCENTRATION SPECIFIED BY THE (SUPDAT)
Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOM TO KEEP
EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOCAL EXHAUST VENT
GENERALLY PREF BECAUSE (TRANSPORT INFO)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR CLEAN BODY-COVERING CLOTHING.
Supplemental Safety and Health
RESP PROT: APPROP REGULATORY AGENCY OR RESP SUPPLIER, WHICHEVER IS
LOWEST. FOR EMERS OR INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN,
USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR SUPPLIED RESP.
WARN ING: AIR-PURIFYING RESPS DO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMOSPHERES.
================== Physical/Chemical Properties ==================
Boiling Pt:=290.C, 554.F
Melt/Freeze Pt:=18.C, 64.4F
Vapor Pres:0.0025 @ 50C(122F)
Vapor Density:3.17 AIR=1
Spec Gravity:1.26 @ 20C/4C
pH:NEUT TO LITMUS
Evaporation Rate & Reference:NO INFO FOUND
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAN OILY LIQUID; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. CAN REACT VIOLENTLY WITH ACETIC ANHYDRIDE, CALCIUM
OXYCHLORIDE, CHROMIUM OXIDES AND ALKALI METAL HYDRIDES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. AVOID HEAT, FLAMES, IGNITION SOURCES AND
INCOMPATIBLES.
Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED
IF INVOLVED IN A FIRE. GLYCERIN DECOMPOSES UPON HEATING ABOVE 290C,
FORMING CORROSIVE GAS (ACROLEIN).
=================== Toxicological Information ===================
Toxicological Information:LD50: (ORAL, RAT) 12,600 MG/KG. INVESTIGATED
AS A MUTAGEN, REPRODUCTIVE EFFECTOR. CANCER LISTS: GLYCERIN MIST
(56-81-5): NTP CARCINOGEN - KNOWN: NO, ANTICIPATED: NO. IARC
CATEGORY: NONE.
===================== Ecological Information =====================
Ecological:WHEN RELEASED INTO SOIL, THIS MATERIAL IS EXPECTED TO
READILY BIODEGRADE. WHEN RELEASED INTO SOIL, THIS MATERIAL IS NOT
EXPECTED TO EVAPORATE SIGNIFICANTLY. WHEN RELEASED INTO WATER, THIS
MATERIAL IS EXPECTED TO READILY BIODEGRADE. THIS MATERIAL IS NOT
EXPECTED TO SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED INTO AIR,
THIS MATERIAL MY BE MODERATELY DEGRADED BY REACTION WITH
PHOTOCHEMICALLY PRODUCED HYDROXYL RADICALS. WHEN RELEASED INTO THE
AIR, THIS MATERIAL MAY BE REMOVED FROM THE ATMOSPHERE TO A MODERATE
EXTENT BY WET DEPOSITION. ENVIRONMENTAL TOXICITY: THIS MATERIAL IS
NOT EXPECTED TO BE TOXI C TO AQUATIC LIFE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE
DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT
MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGS
MAY DIFFER FROM FEDERAL DISPOSAL REGS. DISPOSE OF CONTAINER & U
NUSED CONTENTS I/A/W FEDERAL, STATE & LOCAL REQS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED. VENT: IT CAN CONTROL EMISSIONS OF
CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO THE
GENERAL WORK AREA. PLEASE REFER TO THE ACGIH DOCUMENT, INDUSTRIAL
VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST
RECENTEDITION, FOR DETAILS. EXPOS CONTROLS/PERSONAL PROT: AIRBORNE
EXPOS LIMITS: FOR GLYCERINE MIST: -OSHA PERMISSIBLE EXPOSURE LIMIT
(PEL): TOTAL DUST: 15 MG/M3 (TWA); RESPIRABLE FRACTION: 5 MG/M3
(TWA). -ACGIH THRESHOLD LIMIT VALUE (TLV): 10 MG/M3.
===================== Regulatory Information =====================
SARA Title III Information:GLYCERIN MIST (56-81-5): FEDERAL, STATE &
INTERNATIONAL REGULATIONS - PART 1: SARA 302 - RQ-NO, TPQ-NO. SARA
313 - LIST-NO, CHEMICAL CATG-NO. SARA 311/312: ACUTE:YES,
CHRONIC:YES, FIRE:NO, PRESSURE:NO , REACTIVITY:NO (PURE/LIQUID)
Federal Regulatory Information:GLYCERIN MIST (56-81-5): CHEMICAL
INVENTORY STATUS - PART 1: TSCA-YES. EC-YES. JAPAN-YES.
AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2: KOREA:YES.
CANADA - DSL-YES, NDSL-YES. PHIL-YES. FEDERAL, S TATE &
INTERNATIONAL REGULATIONS - PART 2: CERCLA-NO. RCRA 261.33-NO. TSCA
8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO.
AUSTRALIAN HAZCHEM CODE: NO INFO FOUND. POISON SCHEDULE: NO INFO
FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD
CRITERIAL OF THE CONTROLLE D PRODUCTS REGULATIONS (CPR) & THE MSDS
CONTAINS ALL OF THE INFO REQUIRED BY THE CPR.
State Regulatory Information:N/P. OTHER INFO: STRATEGIC SERVICES
DIVISION; PHONE NUMBER: (314) 539-1600 (USA). JT BAKER SAF-T-DATA
RATINGS (PROVIDED HERE FOR YOUR CONVENIENCE): HEALTH RATING:
1-SLIGHT, FLAMMABILITY RATING: 1-SLIG HT, REACTIVITY RATING:
0-NONE, CONTACT RATING: 1-SLIGHT. LAB PROTECTIVE EQUIP: GOGGLES;
LAB COAT. STORAGE COLOR CODE: ORANGE (GENERAL STORAGE).
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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