===================== Product Identification =====================
MSDS NAME:BLEND-A-COLOR TONER BLUE, A60L1
NIIN:01-063-4013
Status Code:A
MSDS Number: CJVJS
=== Responsible Party ===
Company:SHERWIN-WILLIAMS COMPANY
Address:101 PROSPECT AVENUE
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:ETHYLENE GLYCOL. VP: 0.12
CAS:107-21-1
RTECS #:KW2975000
= Wt:25.
OSHA PEL:50 PPM
ACGIH STEL:C127 MG/M3;C50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:OCTYLPHENOXYPOLY (ETHOXY) ETHANOL VP: 0.00
CAS:9036-19-5
RTECS #:MD0907600
= Wt:18.
Name:SILICA, CRYSTALLINE-QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
= Wt:.3
OSHA PEL:see Table Z-3
ACGIH TLV:0.1 MG/M3
Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS
CAS:14807-96-6
RTECS #:WW2710000
= Wt:26.
OSHA PEL:see Table Z-3
ACGIH TLV:2 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ROUTES OF EXPOSURE: EXPOSURE MAY BE BY
INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF
USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION, AND PERSONAL PRO TECTIVE EQUIPMENT. ACUTE: IRRITATION
OFEYES, SKIN AND UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA
VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR
DIZZINESS. SIGNS AND SYMPTOMS OF OVEREXPOS URE: REDNESS AND ITCHING
OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
CHRONIC: CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS LISTED BY
IARC AND NTP. LONG TERM EXPOSURE TO HIGH LEV ELS OF SILICA DUST
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS ON EVALUATION OF CARCIN RISK OF CHEM TO MAN: VOL 68,
PAGE 41, 1997: GROUP 1. NTP 8TH ANNUAL RPT ON CARCIN 1998:
REASONABLY ANTICIPATED TO BE HUMAN CARCIN.
Effects of Overexposure:HLTH HAZ: WHICH CAN OCCUR ONLY WHEN SANDING OR
ABRADING THE DRY FILM, MAY CAUSE LUNG DAMAGE (SILICOSIS) AND
POSSIBLY CANCER. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN.
IT HAS BEEN SHOWN TO CAU SE BIRTH DEFECTS IN RATS AND MICE AT HIGH
DOSES WHEN GIVEN IN DRINKING WATER OR BY GAVAGE. THERE IS NO
EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMAN. PROLONGED
OVEREXPOSURE TO SOLVENT INGREDIE NTS IN SECTION 2 MAY CAUSE ADVERSE
EFFECTS TO THE LIVER AND URINARY SYSTEMS.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE RE-USE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GIVE CONSCIOUS PATIENT
SEVERAL GLASSES OF WATER. IF VOMITING IS NOT SPONTANEOUS, INDUCE
VOMITING BY HAVING THE PATIENT GENTLY TOUCH THE BACK OF HIS THROAT
WITH A FINGER. KEEP AIRWAY CLEAR. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>93.3C, 200.F
Lower Limits:N.A
Upper Limits:N.A
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESSU RE BUILD-UP AND POSSIBLE AUTOIGNITION OREXPLOSION
WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. FLAMMABILITY
CLASSIFICATION: NOT APPLICABLE. HMIS CODE: HEALTH 3 FLAMMABILITY 1
REACTIVITY 0.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY: 3B. KEEP
CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:PREC TO BE TAKEN IN USE: USE ONLY W/ADEQUATE VENT.
AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. THIS
COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECT ION 2) WHICH MAY BE PRESENT AT HAZ LEVELS
ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC
(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENT, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN SECTION 2. WHEN SANDING/ABRADING DRIED FILM,
WEAR DUST/MIST RESP APPROVED BY NIOSH FOR DUST WHICH MAY BE
GENERATED FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE TO MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE
EXPOSURE LIMITS. (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
OTHER PREC: DUSTS ARE LISTED IN SECTION 2, APPLICABLE LIMITS FOR
NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3
(RESPIRABLE FRACTION), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3
(RESPIRABLE FRACTION). VENT: REFER TO OSHA STANDARDS1910.94,
1910.107, 1910.108.
================== Physical/Chemical Properties ==================
Boiling Pt:>100.C, 212.F
B.P. Text:212-388F
Melt/Freeze Pt:M.P/F.P Text:N.A.
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Spec Gravity:1.32
VOC Pounds/Gallon:413
pH:8.3
VOC Grams/Liter:3.44
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:N.A.
Percent Volatiles by Volume:49
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIXIDE, CARBON
MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT IS NOT HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING POLLUTION.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION 107-21-1 ETHYLENE GLYCOL. % BY WT: 25.
Federal Regulatory Information:TSCA CERTIFICIATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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