===================== Product Identification =====================
MSDS NAME:CADMIUM SULFATE, 1243
NIIN:00N093047
Status Code:A
MSDS Number: CJXBV
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:202-463-7616
Resp. Party Other MSDS Num.:C0140
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:CADMIUM SULFATE
CAS:10124-36-4
RTECS #:EV2700000
Minumum % Wt:99.
Maxumum % Wt:100.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: CADMIUM ABSORPTION IS
MOST EFFECTIVE VIA RESP TRACT. INHAL OF DUST MAY PRDCE IRRIT, HDCH,
METALLIC TASTE &/OR COUGH. SEV EXPOS MAY PRDCE SHORTNESS OF BREATH,
CHEST PAIN, & FLU-LIKE SYMPS W/WEAK, FEVER, HDCH, CHILLS,
SWEATING, NAUS & MUSC PAIN. CAN CAUSE PULM EDEMA, LIVER & KIDNEY
DMG & DEATH. SYMPS FROM INHAL MAY BE DELAYED FOR AS MUCH AS 24 HRS.
INGEST: TOX. INGESTED CADMIUM SALTS M AY CAUSE SEV & SOMETIMES
FATAL POIS. SYMPS CAN INCL SEV NAUS, VOMIT, DIARR, ABDOM PAINS,
CHOKING, DIZZ, & SALIVATION. KIDNEY & LIVER DYSFUNC MAY OCCUR.
ALTHOUGH AS LITTLE AS 10-20 MG OF SOL CADMIUM SA LTS HAVE PRDCED
SEV (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CADMIUM SULFATE: IARC MONOGRAPHS, VOLUME
58, PAGE 119, 1993: GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS,
1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Effects of Overexposure:HLTH HAZ: TOX SYMPS WHEN INGESTED, DEATH
PROBABLY REQUIRES SEVERAL HUNDRED MG BY ORAL ROUTE. SKIN: CAUSES
IRRIT. SYMPS INCL REDNESS, ITCH, & PAIN. EYES: CAUSES IRRIT,
REDNESS, & PAIN. CHRONIC: CHRONIC EXPOS TO CADMIUM, EVEN AT
RELATIVELY LOW CONCS, MAY RSLT IN KIDNEY DMG, ANEMIA, PULM
FIBROSIS, EMPHYSEMA, PERFORATION OF NASAL SEPTUM, LOSS OF SMELL,
MALE REPRO EFTS, & INCREASED RISK OF CANCER OF LU NG & OF PROSTATE.
DECREASE IN BONE DENSITY, RENAL STONES, & OTHER EVIDENCE OF
DISTURBED CALCIUM METABOLISM MAY BE OBSERVED. (SUP DAT)
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS, BLOOD DISORDERS, PROSTATE PROBLEMS, OR
IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE
SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN IMMED. INGEST: INDUCE
VOMIT IMMED AS DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH
TO AN UNC ON PERS. GET MED ATTN IMMED. SKIN: WIPE OFF EXCESS MATL
FROM SKIN THEN IMMED FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT
LEAST 15 MINS. REMOVE CONTAM CLTHG & SHOES. GET MED ATTN IMMED.
WASH CLTHG BEFOR E REUSE. THORO CLEAN SHOES BEFORE REUSE. EYES:
IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINS, LIFTING
LOWER & UPPER EYELIDS OCCAS. GET MED ATTN IMMED. NOTE TO MD: SEE 29
CFR 1910.1027, APPEN DIX A FOR ADDNL TREATMENT INFO.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . IF INVOLVED IN A FIRE,
THIS MATERIAL CAN EMIT VERY TOXIC FUMES OF CADMIUM.
Unusual Fire/Explosion Hazard:THIS MATERIAL IS A NON-COMBUSTIBLE SOLID,
BUT THE DUST CAN BE A MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT OR
FLAME, OR WHEN REACTED WITH OXIDIZING AGENTS, HYDROGEN AZIDE, ZINC,
SELENIUM, OR TELLURIUM. NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. KEEP UNNEC & UNPROT PEOPLE AWAY.
WEAR APPROP PERS PROT EQUIP AS SPECIFIED IN CTL MEASURES SECTION.
SPILLS: PICK UP & PLACE IN SUITABLE CONTR FOR RECLAMATION/DISP,
USING METH THAT DOES NOT G ENERATE DUST. DO NOT FLUSH TO SEWER. US
REGS (CERCLA) REQUIRE REPORTING SPILLS & RELEASES TO SOIL, WATER &
AIR IN EXCESS OF RQ'S. TOLL FREE # FOR US COAST GUARD NATL RESPONSE
CTR IS (800) 424-8802.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. WEAR SPECIAL PROTECTIVE EQUIPMENT (SEE CONTROL MEASURES
SECTION) FOR MAINTENANCE BREAK-IN O R WHERE EXPOSURES MAY EXCEED
ESTABLISHED EXPOSURE LEVELS.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE
ALL WARNINGS & PRECAUTIONS LISTED FOR THE PRODUCT. DO NOT BREATHE
DUST. DO NOT GET IN EYES, ON SKIN/ON CLOTHING. DO NOT ENTER
STORAGE AREAS UNLESS ADEQUATELY VENTILATED. USE ONLY WITH A DEQUATE
VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
HALF-FACE HIGH EFFICIENCY DUST/MIST RESP MAY BE WORN FOR UP TO 10
TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY
AGENCY/RESP SUPPLIER, WHICHEVER I S LOWEST. A NIOSH APPRVD
FULL-FACE PIECE HIGH EFFICIENCY DUST/MIST RESP MAY BE WORN UP TO 50
TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP (OTHER INFO)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (TOX INFO)
Protective Gloves:WEAR IMPERVIOUS PROTECTIVE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS,
LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH HANDS, FACE, FOREARMS & NECK WHEN EXITING
RESTRICTED AREAS. SHOWER, DISPOSE OF OUTER CLTHG, CHANGE TO CLEAN
GARMENTS AT END OF DAY. AVOID CROSS-CONTAM OF STREET CLOTHES.
(ECOLOGICAL INFORMATION)
Supplemental Safety and Health
HLTH HAZ: CADMIUM APPEARS ON THE NAVY OCCUP CHEM REPRO HAZS LIST. SEEK
CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ
LIST INFO & SAFE HNDLG & EXPOS INFO . WASTE DISP METH: ST ATE & LOC
DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF CONTR & UNUSED
CONTENTS I/A/W FED, STATE & LOC REQS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:SEE TRANSPORT INFO
Spec Gravity:3.08
Solubility in Water:FREELY SOLUBLE
Appearance and Odor:COLORLESS CRYSTALS; ODORLESS.
Percent Volatiles by Volume:0 @ 21C(70F)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, METALS, HYDROGEN AZIDE, ZINC, SELENIUM AND TELLURIUM.
Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES, DUSTING AND
INCOMPATIBLES.
Hazardous Decomposition Products:OXIDES OF SULFUR AND THE CONTAINED
METAL.
=================== Toxicological Information ===================
Toxicological Information:TOXICOLOGICAL DATA: HYDRATE: INVESTIGATED AS
A TUMORIGEN, MUTAGEN, REPRODUCTIVE EFFECTOR. ANHYDROUS: ORAL RAT
LD50: 280 MG/KG. INVESTIGATED AS A TUMORIGEN, MUTAGEN, REPRODUCTIVE
EFFECTOR. REPRODUCTIVE TOXICITY: IN LABORATORY ANIMALS, THIS
COMPOUND HAS CAUSED BOTH BIRTH DEFECTS AND DAMAGE TO THE
REPRODUCTIVE SYSTEM. VENTILATION: CONTAMINANT AT ITS SOURCE,
PREVENTING DISPERSION OF IT INTO THE GENERA L WORK AREA. PLEASE
REFER TO THE ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF
RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS.
===================== Ecological Information =====================
Ecological:ENVIRON FATE: DATA FOR ANHYDROUS MATL UNLESS OTHERWISE
NOTED. MATL HAS AN EXPERIMENTALLY-DETERMINED BIOCONCENTRATION
FACTOR (BCF) OF >100. MATL IS EXPECTED TO SIGNIFICANTLY
BIOACCUMULATE. ENVIRON TOX: THIS MATL IS EXPECTED TO BE VERY TOX
TO AQUATIC LIFE. HYGIENE PRACT: WASH HANDS BEFORE EATING & DO NOT
EAT, DRINK/SMOKE IN WORKPLACE. EATING, DRINKING, & SMKG SHOULD NOT
BE PERMITTED IN AREAS WHERE S OLIDS/LIQS CONTAINING CADMIUM CMPDS
ARE HANDLED, PROCESSED/STORED. SEE OSHA SUBSTANCE-SPECIFIC STD FOR
MORE INFO ON PERS PROT EQUIP, ENGINEERING & WORK PRACT CTLS, MED
SURVEILLANCE, RECORD KEEPING, & REPORTING REQS (29 CFR 1910.1027).
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. ALTHOUGH NOT A
LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT ONE/MORE CHARACTS OF
HAZ WASTE & REQUIR E APPROP ANALYSIS TO DETERMINE SPECIFIC DISP
REQS. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WA STE
MANAGEMENT OPTIONS. (SUP DAT)
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, D.O.T.), INTERNATIONAL (WATER,
I.M.O.), INTERNATIONAL (AIR, I.C.A.O.): PROPER SHIPPING NAME:
CADMIUM COMPOUNDS; HAZARD CLASS: 6.1; UN/NA: UN2570; PACKING GROUP:
III; INFORMATION REPORT ED FOR PRODUCT/SIZE: 100 LBS. MELTING
POINT: LOSES WATER ABOVE 40C FORMING MONOHYDRATE BY 80C.
===================== Regulatory Information =====================
SARA Title III Information:CADMIUM SULFATE (CAS # 10124-36-4): NOT
LISTED IN SARA 302 RQ/TPQ; NOT LISTED IN SARA 313 LIST. SARA 313
CHEMICAL CATEGORY: CADMIUM COMPOUND. SARA 311/312: ACUTE: YES;
CHRONIC: YES; FIRE: NO; PRESSURE : NO; REACTIVITY: NO (PURE/SOLID).
Federal Regulatory Information:CADMIUM SULFATE (CAS # 10124-36-4):
LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL, THE
PHILIPPINES; NOT LISTED IN CANADA NDSL, CERCLA, RCRA 261.33, TSCA 8
(D), CHEMICAL WEAPONS CONVENTION, T SCA 12 (B), CDTA. AUSTRALIAN
HAZCHEM CODE: 2X. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS:
THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE
CONTROLLED PRODUCTS REGULATIONS (CPR) A ND THE MSDS CONTAINS ALL OF
THE INFORMATION REQUIRED BY THE CPR.
State Regulatory Information:PROPOSITION 65: THIS PRODUCT CONTAINS A
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|