===================== Product Identification =====================
MSDS NAME:ALUMINUM AMMONIUM SULFATE, 3212
NIIN:00N093050
Status Code:A
MSDS Number: CJXBX
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:202-463-7616
Resp. Party Other MSDS Num.:A2760
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID, ALUMINUM AMMONIUM SALT (2:1:1)
CAS:7784-25-0
Minumum % Wt:98.
Maxumum % Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING! HARMFUL IF SWALLOWED OR
INHALED. CAUSES IRRITATION TO SKIN, EYES & RESPIRATORY TRACT.
POTENTIAL HEALTH EFFECTS: THIS MATERIAL HYDROLYZES IN WATER TO FORM
SULFURIC ACID, WHICH IS RESPONSIBLE FOR IRRITATING EFFECTS GIVEN
BELOW. ACUTE: INHAL: CAUSES IRRITATION TO RESPIRATORY TRACT.
SYMPTOMS MAY INCLUDE COUGHING, SHORTNESS OF BREATH. INGESTION:
CAUSES IRRITATION TO THE GASTROINTESTINAL TRACT . SYMPTOMS MAY
INCLUDE NAUSEA, VOMITING AND DIARRHEA. THERE HAVE BEEN TWO CASES OF
FATAL HUMAN POISONINGS FROM INGESTION OF 30 GRAMS OF ALUM. SKIN:
CAUSE IRRITATION TO SKIN. SYMPTOMS INCLUDE REDNESS, ITCHING, &
PAIN. (EFTS OF OVEREXP).
Effects of Overexposure:HLTH HAZ: EYE CONTACT: CAUSES IRRITATION,
REDNESS, AND PAIN. CHRONIC: NO INFORMATION FOUND.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL ATTENTION. INGEST: IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE
LARGE QUA NTITIES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET MED ATTN IMMED. SKIN: WIPE OFF EXCESS
MATERIAL FROM SKIN THEN IMMEDIATELY FLUSH SKIN W/PLENTY OF WATER
FOR AT LEAST 15 MIN. REMOVE CONTAMINATED CLOTHING & SHOES. GET
MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN
SHOES BEFORE REUSE. EYE: IMMED FLUSH W/PLENTY OF H*2O FOR AT LEAST
15 MIN, LIFTING UPPER & LO WER EYELIDS OCCASIONALLY. GET MED ATTN.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. KEEP IN MIND THAT ADDITION OF WATER CAN CAUSE THE
FORMATION OF SULFURIC ACID.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPLOSION: NOT CONSIDERED TO BE AN
EXPLOSION HAZARD SEALED CONTAINERS MAY RUPTURE WHEN HEATED. FIRE:
NOT CONSIDERED TO BE A FIRE HAZARD. MAY RELEASE FLAMMABLE AMMONIA
IF INVOLVED IN A FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILL WITH SODIUM BICARBONATE OR SODA
ASH AND MIX. VENTILATE AREA OF LEAK OR SPILL. KEEP UNNECESSARY AND
UNPROTECTED PEOPLE AWAY FROM AREA OF SPILL. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMEN T AS SPECIFIED IN SECTION 8. SPILLS:
PICK UP AND PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR
DISPOSAL, USING A METHOD THAT DOES NOT GENERATE DUST.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER,
STORED IN COOL, DRY, VENT AREA. PROTECT AGAINST PHYSICAL DAMAGE.
ISOLATE FROM INCOMPATIBLE SUBSTANCES. CONTAINERS OF THIS MATERIAL
MAY BE HAZARDOUS WHEN EMPTY SINCE T HEY RETAIN PRODUCT RESIDUES
(DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECAUTIONS LISTED FOR
PRODUCT.
Other Precautions:RESP PROT: WHICHEVER IS LOWEST. FOR EMERGENCIES OR
INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN, USE NIOSH
APPRVD FULL-FACEPIECE POSITIVE-PRESSURE, AIR SUPPLIED RESPIRATOR.
WARNING: NIOSH APPROV ED AIR-PURIFYING RESPIRATORS DO NOT PROTECT
WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD
HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES EXPOS
LIMIT/MAXIMUM USE CONC SPECIFIED BY APPROP REGULATORY AGENY/RESP
SUPPLIER, WHICHEVER IS LOWEST. NIOSH FULL-FACE PIECE DUST/MIST
RESP MAY BE WORN UP TO 50 TIMES EXPOS LIMIT/MAX USE CONC SPECIFIED
BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (OTHER PREC)
Ventilation:SYS OF LOC &/GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW
AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GENERALLY PREFERRED
BECAUSE IT CAN CONTROL (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS,
LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
VENT: EMISSIONS OF CONTAM AT ITS SOURCE, PREVENTING DISPERSION OF IT
INTO GENERAL WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL
VENT, MANUAL OF REC PRACTICES MOST RECENT EDITIONS FOR DETAILS.
================== Physical/Chemical Properties ==================
Boiling Pt:=280.C, 536.F
B.P. Text:DECOMPOSES
Melt/Freeze Pt:=94.5C, 202.1F
Vapor Pres:OTHER INFO
Vapor Density:OTHER INFO
pH:OTHER INFO
Evaporation Rate & Reference:NO INFORMATION FOUND
Solubility in Water:OTHER INFO
Appearance and Odor:COLORLESS CRYSTALS; ODORLESS.
Percent Volatiles by Volume:OTHER INFO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH ALKALIS MAY RELEASE AMMONIA GAS. CORROSIVE TO METALS IN
THE PRESENCE OF WATER.
Stability Condition to Avoid:MOISTURE AND INCOMPATIBLES.
Hazardous Decomposition Products:TOXIC OXIDES OF NITROGEN, SULFUR
DIOXIDE, AMMONIA, AND SULFUR TRIOXIDE MAY FORM AT ELEVATED
TEMPERATURES. HYDROLYZES TO FORM SULFURIC ACID.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:NO LD50/LC50 INFORMATION FOUND RELATING TO
NORMAL ROUTES OF OCCUPATIONAL EXPOSURE.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APROVED WASTE DISPOSAL FACILITY.
PROCESSING, USE/CONTAMINATION OF THIS PRODUCT MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGULATIONS MAY DIFFER
FROM FED DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & UNUSE D
CONTENTS I/A/W/FED, STATE & LOCAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:FEDERAL, STATE & INTERNATIONAL REGULATIONS -
PART I: INGREDIENT: SULFURIC ACID, ALUMINUM AMMONIUM SALT: (2:1:1)
(7784-25-0): SARA 302: RQ NO; TPQ: NO. SARA 312: LIST NO CHEMICAL
CATG: NO.
Federal Regulatory Information:CHEMICAL INVENTORY STATUS- PART 1:
INGREDIENT: SULFURIC ACID, ALUMINUM AMMONIUM SALT (2:1:1)
(7784-25-0): TSCA; EC; JAPAN; AUSTRALIA: YES. CHEMICAL INVENTORY
STATUS - PART 2: INGREDIENT: SULFUR ACID, ALUMINUM AMMONIUM SALT
(2:1:1) (7784-25-0): CANADA: KOREA: YES, DSL: YES; NDSL: NO; PHIL:
NO. AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON
SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HA S BEEN PREPARED
ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS
REGULATIONS (CPR) AND MS DS CONTAINS ALL OF THE INFORMATION
REQUIRED BY THE CPR.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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