===================== Product Identification =====================
MSDS NAME:HYDROCHLORIC ACID (LESS THAN 10%), 6388
NIIN:00N093045
Status Code:A
MSDS Number: CJXCH
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:202-463-7616
Resp. Party Other MSDS Num.:H3883
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:HYDROGEN CHLORIDE
CAS:7647-01-0
RTECS #:MW4025000
Minumum % Wt:.7
Maxumum % Wt:8.
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:92.
Maxumum % Wt:99.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HEALTH HAZARDS GIVEN ON THIS DATA
SHEET APPLY TO CONCENTRATED SOLUTIONS OF HYDROCHLORIC ACID. HAZARDS
OF DILUTE SOLUTIONS MAY BE REDUCED, DEPENDING UPON THE
CONCENTRATION. DEGREE OF HAZARD FOR THESE R EDUCED CONCENTRATIONS
IS NOT CURRENTLY ADDRESSED IN THE AVAILABLE LITERATURE. INHALATION:
CORROSIVE! INHALATION OF VAPORS CAN CAUSE COUGHING, CHOKING,
INFLAMMATION OF THE NOSE, THROAT AND UPPER RESPIR ATORY TRACT AND
IN SEVERE CASES, PULMONARY EDEMA, CIRCULATORY FAILURE AND DEATH.
INGESTION; CORROSIVE! SWALLOWING HYDROCHLORIC ACID CAN CAUSE
IMMEDIATE PAIN AND BURNS OF THE MOUTH, THROAT, ESOPHAGUS ( EFFECTS
OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: AND GASTROINTESTINAL TRACT. MAY
CAUSE NAUSEA, VOMITING AND DIARRHEA, AND IN SEVERE CASES, DEATH.
SKIN CONTACT: CORROSIVE! CAN CAUSE REDNESS, PAIN AND SEVERE SKIN
BURNS. CONCENTRTED SOL UTIONS CAUSE DEEP ULCERS AND DISCOLOR SKIN.
EYE CONTACT: CORROSIVE! VAPORS ARE IRRITATING AND MAY CAUSE DAMAGE
TO THE EYES. CONTACT MAY CAUSE SEVERE BURNS AND PERMANENT EYE
DAMAGE. CHRONIC: LONG-TERM EXPOSURE TO CONCENTRATED VAPORS MAY
CAUSE EROSION OF TEETH. LONG TERM EXPOSURES SELDOM OCCUR DUE TO THE
CORROSIVE PROPERTIES OF THE ACID.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:FIRST AID PROCS GIVEN APPLY TO CONC SOLNS. EXPOS TO DILUTE
SOLNS MAY NOT REQ THESE EXTENSIVE FIRST AID PROCS. INHAL:REMOVE TO
FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE OXYG.
GET ME D ATTN IMMED. INGEST:IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE
LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET
MED ATTN IMMED. SKIN: IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LST
15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. GET MED ATTN IMMED.
WASH CLTHG BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYES:IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MIN, LIFTING
LOWER & UP PER LIDS OCCASNLY. GET MED ATTN IMMED.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER OR WATER SPRAY. NEUTRALIZE WITH SODA ASH OR
SLAKED LIME.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . STRUCTURAL FIREFIGHTER'S PROTECTIVE CLOTHING IS
INEFFECTIVE FOR FIRES INVOLING HYDROCHLORIC ACID. STAY AWAY FROM
ENDS OF TANKS. COOL TANKS WITH WATER SPRAY UNTIL WELL AFTER FIRE
IS OUT.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. MAY
REACT WITH METALS OR HEAT TO RELEASE FLAMMABLE HYDROGEN GAS. NOT
CONSIDERED TO BE AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA OF LEAK OR SPILL. WEAR APPROP
PERSONAL PROT EQUIP AS SPECIFIED IN SECTION 8, EXPOS CTLS/PERSONAL
PROT. ISOLATE HAZ AREA. KEEP UNNEC & UNPROT PERS FROM ENTERING.
CNTN & RECOVER LIQ WHEN POSS. NEUT W/ALKALINE MATL (SODA ASH,
LIME), THEN ABSORB W/INERT MATL (EG, VERMICULITE, DRY SAND, EARTH)
& PLACE IN CHEM WASTE CNTNR. DO NOT USE COMBUST MATLS, SUCH AS SAW
DUST. DO NOT FLUSH TO (SUPDAT)
Neutralizing Agent:NEUTRALIZE WITH ALKALINE MATERIAL (SODA ASH, LIME).
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, VENTD STORAGE AREA
W/ACID RESIST FLOORS & GOOD DRAINAGE. PROTECT FROM PHYSICAL DMG.
KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT & INCOMPAT MATLS. DO
NOT WASH OUT CNTNR & USE IT FO R OTHER PURPOSES. WHEN DILUTING,
ALWAYS ADD ACID TO WATER; NEVER ADD WATER TO ACID.
Other Precautions:WHEN OPENING METAL CNTNRS, USE NON-SPARKING TOOLS
BECAUSE OF POSSIBILITY OF HYDROGEN GAS BEING PRESENT. PROTECT FROM
FREEZING. CNTNRS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE
THEY RETAIN PRO DUCT RESIDUES (VAPOR, LIQUID); OBSERVE ALL WARNINGS
& PRECAUTIONS LISTED FOR PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD FULL
FACEPIECE RESP W/ACID GAS CARTRIDGE MAY BE WORN UP TO 50 TIMES
EXPOS LIMIT OR MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY
OR RESP SUPPLIER, WHICHEV ER IS LOWEST. FOR EMERS OR INSTANCES
WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE
POS-PRESS, AIR-SUPPLIED RESP. (TOXICOLOGICAL INFO)
Ventilation:SYSTEM OF LOC OR GEN EXHST IS RECOM TO KEEP EMPLOYEE
EXPOSURES BELOW AIRBORNE EXPOSURE LIMIT. LOC EXHST VENT IS
GENERALLY PREF BECAUSE IT CAN (ECOLOGICAL INFO)
Protective Gloves:RUBBER OR NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . ADDITIONAL PROTECTION INCLUDING IMPERVIOUS BOOTS, APRON
OR COVERALLS, AS NEEDED IN AREAS OF UNUSUAL EXPOSURE TO PREVENT
SKIN CONTACT.
Supplemental Safety and Health
PHYSICAL DATA: VAP DENS: ESNTLY SAME AS WATER. PH: FOR HCL SOLNS: 0.1
(1.0 N), 1.1 (0.1 N), 2.02 (0.01 N). % VOLAT: 100 (AS WATER & ACID)
@ 21C(70F). SPILL PROC: SEWER! US REGS (CERCLA) REQ REPORTING
SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF REPORTABLE
QTYS. TOLL FREE NUMBER FOR US COAST (TOXICOLOGICAL INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:=0.C, 32.F
Vapor Pres:ESSNTLY SAME AS WATER
Vapor Density:SUPDAT
Spec Gravity:CA 1
pH:SUPDAT
Evaporation Rate & Reference:ESSENTIALLY SAME AS WATER
Solubility in Water:INFINITELY SOLUBLE
Appearance and Odor:CLEAR, COLORLESS SOLUTION; PUNGENT, HYDROCHLORIC
ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
A STRONG MINERAL ACID, CONCENTRATED HYDROCHLORIC ACID IS HIGHLY
REACTIVE W/STRONG BASES, METALS, METAL OXIDES, HYDROXIDES, AMINES,
CARBONATES & OTHER ALKALINE MATLS. INCOMPAT W/MATLS SUCH AS
CYANIDES, SULFIDES, SULFITES & F
Stability Condition to Avoid:HEAT, DIRECT SUNLIGHT, INCOMPATIBLES.
STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE.
Hazardous Decomposition Products:WHEN HEATED TO DECOMP, EMITS TOX
HYDROGEN CHLORIDE FUMES & WILL REACT W/WATER OR STEAM TO PRDCE HEAT
& TOX & CORR FUMES. THERMAL OXIDATIVE DECOMP PRDCES TOX CHLORINE
FUMES & EXPLOSIVE HYDROGEN GAS.
=================== Toxicological Information ===================
Toxicological Information:HYDROCHLORIC ACID: INHAL RAT LC50: 3124
PPM/1H; ORAL RABBIT LD50: 900 MG/KG. INVESTIGATED AS TUMORIGEN,
MUTAGEN, REPRO EFFECTOR. CANCER LISTS: HYDROGEN CHLORIDE
(7647-01-0) - NTP CARCIN: KNOWN-NO; ANT IC-NO. IARC CATEGORY: 3.
WATER (7732-18-5) - NTP CARCIN: KNOWN-NO; ANTIC-NO. IARC
CATEGORY-NONE. SUPDAT: GUARD NATL RESPONSE CTR IS 800-424-8802. JT
BAKER NEUTRASORB(TM) OR TEAM(TM) 'LOW NA+' ACID NEU TRALIZERS ARE
RECOM FOR SPILLS OF THIS PROD. RESP PROT: WARNING: AIR PURIFYING
RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: FOR HYDROCHLORIC ACID (CONCENTRATED
SOLNS): WHEN RELEASED INTO SOIL, THIS MATL IS NOT EXPECTED TO
BIODEGRADE. WHEN RELEASED INTO SOIL, THIS MATL MAY LEACH INTO
GROUNDWATER. ENVIRON MENTAL TOXICITY: FOR HYDROCHLORIC ACID
(CONCENTRATED SOLUTIONS): THIS MATL MAY BE TOXIC TO AQUATIC LIFE.
LC50 SHRIMP: 100-300 PPM/48-HR/SALT WATER; LC100 TROUT: 10
MG/1/24-HR; TLM MOSQUITO FISH: 282 P PM/96-HR. VENT: EMISSIONS OF
CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN
WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION,
A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR
DETAILS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZ WASTE & SENT TO A RCRA APPRVD
WASTE FACILITY. PROCESSING, USE OR CONTAM OF THIS PROD MAY CHANGE
THE WASTE MANAGEMENT OPTIONS . STATE & LOCAL DISPOSAL REGS MAY
DIFFER FROM FED DISPOSAL REGS. DISPOSE OF CNTNR & UNUSED CONTENTS
I/A/W FED, STATE & LOCAL REQS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, DOT) - PROPER SHIPPING NAME:
HYDROCHLORIC ACID. HAZ CLASS: 8. UN/NA: UN1789. PACKING GROUP: II.
INFO REPORTED FOR PRO/SIZE: 200L. INTERNATL (WATER, IMO) = PROPER
SHIPPING NAME: HYDROCH LORIC ACID. HAZ CLASS: 8. UN/NA: UN1789.
PACKING GROUP: II. INFO REPORTED FOR PROD/SIZE: 200L. AIRBORNE
EXPOSURE LIMS: FOR HYDROCHLORIC ACID: OSHA PEL: 5 PPM (CEILING) -
ACGIH TLV: 5 PPM (STEL/CEILING ). OTHER INFO: LG QTYS OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. IN ALL CASES GET MED
ATTN IMMED. PROD USE: LAB REAGENT. REVISION INFO: MIXTURE. NEW 16
SECTION MSDS FORMAT, ALL SECTIONS HAVE BEEN (STATE REG INFO)
===================== Regulatory Information =====================
SARA Title III Information:FEDERAL, STATE & INTERNATIONAL REGS - PART
1: HYDROGEN CHLORIDE (7647-01-0) - SARA 302 RQ: 5000; TPQ: 500.
SARA 313 LIST-YES; CHEMICAL CATG-NO. WATER (7732-18-5) - SARA 302
RQ: NO; TPQ: NO. SARA 313 L IST: NO; CHEM CATG-NO. SARA 311/312:
AUCTE:YES; CHRONIC:YES; FIRE:NO, PRESSURE:NO; REACTIVITY:NO
(MIXTURE/LIQUID).
Federal Regulatory Information:HYDROGEN CHLORIDE & WATER: CHEM
INVENTORY STATUS - PART 1: TSCA-YES, EC-YES, JAPAN-YES,
AUSTRALIA-YES. CHEM INVENTORY STATUS -PART 2: KOREA-YES, CANADA
DSL-YES, CANADA NDSL-NO, PHIL-YES. FEDERAL, STAT E & INTERNATIONAL
REGS - PART 2: HYDROGEN CHLORIDE: CERCLA-5000, RCRA 261.33-NO, TSCA
8(D)-NO. WATER: CERCLA-NO, RCRA 261.33-NO, TSCA 8(D)-NO. CHEMICAL
WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: YE S. AUSTRALIAN
HAZCHEM CODE: NO INFO FOUND. POISON SCHEDULE: NO INFO FOUND. WHMIS:
THIS MSDS HAS BEEN PREPARED ACCRD TO HAZ CRITERIA OF CONTROLLED
PRODS REGS (CPR) & MSDS CNTNS ALL INFO REQD BY THE CPR.
State Regulatory Information:N/P. TRANSPORT INFO: REVISED. PREPARED BY:
STRATEGIC SERVICES DIVISION 314-539-1600 (USA). PROD
IDENTIFICATION: SYNONYMS: MURIATIC ACID SOLUTION; 10:1 DILUTE
HYDROCHLORIC ACID; HYDROCHLORIC ACID VOLUM ETRIC SOLNS (0.2-2.0N).
MW: 36.46. CHEMFORMULA: HCL IN WATER. JT BAKER SAF-T-DATA RATINGS:
HEALTH: 3-SEVERE (POISON). FLAMMABILITY RATING: 0-NONE. REACTIVITY:
2-MODERATE. CONTACT: 3-SEVERE (CORROSIVE) . LAB PROT EQUIP: GOGGS &
SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES. STORAGE COLOR
CODE: WH ITE (CORROSIVE).
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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