===================== Product Identification =====================
MSDS NAME:WKG SOL,KODAK COLOR DEVELOPER REPLENISHER, PROCESS E-6 AR
Status Code:A
MSDS Number: CKWPW
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:POTASSIUM HYDROXIDE
CAS:1310-58-3
RTECS #:TT2100000
< Wt:.5
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:90.
Maxumum % Wt:95.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Name:TRIPOTASSIUM PHOSPHATE
CAS:7778-53-2
RTECS #:TC8450000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Ingred
Name:4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIA
MINE SESQUISULFATE MONOHYDRATE
CAS:25646-71-3
RTECS #:PB0431000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:1 MG/M3 TWA; MFR
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: GENERAL: CONTAINS
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MONOHYDRATE. MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL
DATA. INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED
HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SOME ASTHM ATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES BURNS.
MIST IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: MAY BE HARMFUL IF SWA LLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): SOD IUM BISULFITE, A4;
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA):NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUA LS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES BURNS. MIST IRRITATING. SKIN: CAUSES IRRITATION. MAY
CAUSE ALLERGIC SKIN REACTION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTI ON IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DO NOT INDUCE V OMITING. GIVE VICTIM A GLASS OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
Other Precautions:DO NOT GET IN EYES. AVOID CONTACT WITH SKIN. AVOID
BREATHING MIST OR VAPOR. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID)
TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES,
GLOVES, ETC. WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN
REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: HALF-FACE CARTRIDGE
RESPIRATOR WITH HIGH EFFICI ENCY PARTICULATE AEROSOL (HEPA)
CARTRIDGES. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED
TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A
FACE SHIELD.
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR(18 MM HG)
Vapor Density:0.6
Spec Gravity:1.04
pH:12.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS ODORLESS LIQUID.
Percent Volatiles by Volume:90- 95 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:NONE (NONCOMBUSTIBLE)
=================== Toxicological Information ===================
Toxicological Information:DATA FOR
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MONOHYDRATE ACUTE TOXICITY DATA: ORAL LD-50 (MALE
RAT): 400 MG/KG (TARGET ORGAN EFFECTS: KIDNEY). ORAL LD-50
(FEMALE RAT): 246 MG/KG. DERMAL LD-50: > 1000 MG/KG (HIGHEST DOSE
TESTED). SKIN IRRITATION: SLIGHT. REPEATED SKIN APPLICATION:
MODERATE IRRITATION. SKIN SENSITIZATION: MODERATE. SKIN
SENSITIZATI ON (HUMAN): POSITIVE EYE IRRITATION (UNWASHED
EYES): MODERATE EYE IRRITATION (WASHED EYES): SLIGHT
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEGRAD ABLE (>70%): YES (14 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 12. BOD5
(APPROXIMATE G/L): 2. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS
EMPTIED. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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