===================== Product Identification =====================
MSDS NAME:186 6243,CONCENTRATE,KODAK REVERSAL BLEACH AND REPLENISHER
NIIN:00-926-5310
Status Code:A
MSDS Number: CKWQJ
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:75.
Maxumum % Wt:80.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Name:SULFAMIC ACID
CAS:5329-14-6
RTECS #:WO5950000
Minumum % Wt:15.
Maxumum % Wt:20.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:POTASSIUM DICHROMATE
CAS:7778-50-9
RTECS #:NX7680000
= Wt:5.
Other REC Limits:NOT PROVIDED
OSHA PEL:SEE TABLE Z-2
ACGIH TLV:0.05 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: CONTAINS:
POTASSIUM DICHROMATE, SUSPECT CANCER HAZARD. MAY CAUSE CANCER. CAN
CAUSE KIDNEY DAMAGE. CONTAINS: SULFURIC ACID, INTERNATIONAL AGENCY
FOR RESEARCH ON CANCER (IARC) HAS D ETERMINED THAT OCCUPATIONAL
EXPOSURE TOSTRONG INORGANIC MISTS OR VAPORS CONTAINING SULFURIC
ACID IS CARCINOGENIC TO HUMANS. INHALATION: EXPECTED TO BE LOW
HAZARD FOR RECOMMENDED HANDLING. MIST OR DRI ED RESIDUE MAY BE
HARMFUL IF INHALED. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. MAY
CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTRO INTESTINAL
TRACT IF SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): GROUP 1 -
CONFIRMED HUMAN CARCINOGEN AS POTASSIUM DICHROMATE AND STRONG
INORGANIC MISTS OR VAPORS CONTAINING SULFURI C ACID - AMERICAN
CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): (A1) -
CONFIRMED HUMAN CARCINOGEN. NTP: YES. OSHA: NONE.
Effects of Overexposure:EYES: CAUSES BURNS. SKIN: CAUSES BURNS. MAY
CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION:
MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IMMEDIATELY. WASH
CONTAMINATED CLOTHING BEF ORE REUSE. DESTROY OR THOROUGHLY CLEAN
CONTAMINATED SHOES. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM
A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL A PHYSICIAN OR P OISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:DRIED PRODUCT RESIDUE IS IMPACT
SENSITIVE.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID
PROLONGED OR REPEATED BREATHING OF MIST. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A
FACE SHIELD.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED.
================== Physical/Chemical Properties ==================
HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.14
pH:< 1.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:RED BROWN LIQUID. ODOR: ODORLESS.
Percent Volatiles by Volume:75- 80 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, BASES
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:AMMONIA. CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR.
=================== Toxicological Information ===================
Toxicological Information:EFFECTS OF EXPOSURE: CONTAINS: POTASSIUM
DICHROMATE, SUSPECT CANCER HAZARD. MAY CAUSE CANCER. CAN CAUSE
KIDNEY DAMAGE. CONTAINS: SULFURIC ACID, INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC) HAS D ETERMINED THAT OCCUPATIONAL
EXPOSURE TOSTRONG INORGANIC MISTS OR VAPORS CONTAINING SULFURIC
ACID IS CARCINOGENIC TO HUMANS. INHALATION: EXPECTED TO BE LOW
HAZARD FOR RECOMMENDED HANDLING. MIST OR DRI ED RESIDUE MAY BE
HARMFUL IF INHALED. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. MAY
CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTRO INTESTINAL
TRACT IF SWALLOWED.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10.
DAPHNID EC50 MG/L: 10-100. ALGAL IC50 MG/L: NOT AVAILABLE.
ORGANICS READ ILY DEGRADABLE (>70%): NOT APPLICABLE. POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): NOT AVAILABLE.
BOD5 (APPROXIMATE G/L): 2. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC 50 (MG/L): >100. WHEN DILUTED WITH A LARGE
AMOUNT OF WATER, THIS MATERIAL RELEASED DIRECTLY OR INDIRECTLY INTO
THE ENVIRONMENT IS NOT EXPECTED TO HAVE A SIGNIFICANT IMPACT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. CONTRACT WITH A LICENSED CHEMICAL
DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNING S EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:THE INFORMATION GIVEN BELOW IS PROVIDED TO ASSIST
IN DOCUMENTATION. IT MAY SUPPLEMENT THE INFORMATION ON THE PACKAGE.
UNITED NATIONS UN NUMBER:
PA CKING GROUP: CONCENTRATE: 3265 III PROPER
SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (SULFAMIC
ACID 15-20%).: AIR - INTERNATIONAL CIVIL AVIATION ORGANIZATION
(ICAO): (IMDG) I MDG CLASS: 8 USA DEPARTMENT OF
TRANSPORTATION (DOT) HAZARDOUS MATERIALS CLASSIFICATION: DOT
(USA) STATUS: R DOT HAZARD CLASS: 8
DOT PACKING GROUP: III
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: POTASSIUM DICHROMATE.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: POTASSIUM DICHROMATE - MATERIAL(S)
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE
EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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