===================== Product Identification =====================
MSDS NAME:TETRABUTYLAMMONIUM HYDROXIDE SOLUTION (0.4M - 1M) 04575100
Status Code:A
MSDS Number: CKWPR
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100/703-527-3887
Emergency Phone Num:800-424-9300/703-527-3887
Resp. Party Other MSDS Num.:22862
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:1-BUTANAMINIUM, N,N,N-TRIBUTYL-, HYDROXIDE. (EINECS
#218-147-6)
CAS:2052-49-5
RTECS #:BS5425000
Minumum % Wt:10.
Maxumum % Wt:25.
OSHA PEL:NONE LISTED
OSHA STEL:NONE LISTED
ACGIH TLV:NONE LISTED
ACGIH STEL:NONE LISTED
Name:WATER. (EINECS #231-791-2)
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:75.
Maxumum % Wt:90.
OSHA PEL:NONE LISTED
OSHA STEL:NONE LISTED
ACGIH TLV:NONE LISTED
ACGIH STEL:NONE LISTED
===================== Hazards Identification =====================
LD50 LC50 Mixture:CAS 7732-18-5: ORAL RAT: LD50= >90 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING! MAY CAUSE SEVERE RESPIRATORY
AND DIGESTIVE TRACT IRRITATION WITH POSSIBLE BURNS. MAY CAUSE
SEVERE EYE AND SKIN IRRITATION WITH POSSIBLE BURNS. TARGET ORGANS:
NONE. POTENTIAL HEALTH EFFECTS: E YE: MAY CAUSE EYE IRRITATION AND
POSSIBLE BURNS. SKIN: EXPOSURE MAY CAUSE IRRITATION AND POSSIBLE
BURNS. INGESTION: MAY CAUSE SEVERE GASTROINTESTINAL TRACT
IRRITATION WITH NAUSEA, VOMITING AND POSSIBL E BURNS. INHALATION:
MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT WITH BURNING PAIN IN
THE NOSE AND THROAT, COUGHING, WHEEZING, SHORTNESS OF BREATH AND
PULMONARY EDEMA. CHRONIC: NO INFORMATION FOUND.
Explanation of Carcinogenicity:1-BUTANAMINIUM, N,N,N-TRIBUTYL-,
HYDROXIDE: NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. WATER:
NO LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA.
======================= First Aid Measures =======================
Eyes: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER AND LOWER LIDS. GET MEDICAL AID
IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. SKIN:
GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKIN WITH PLENTY OF
SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS
CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS MILK OR WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. POSSIBLE ASPIRATION
HAZARD. GET MEDICAL AID IMMEDIATELY. INHALATION: GET MEDICAL AID
IMMEDIATELY. REMOVE F ROM EXPOSURE TO (OTHER INFORMATION)
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:NOT AP
Lower Limits:NOT APPLIC
Upper Limits:NOT APPLIC
Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL
FOAM OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN (CONTROL MEASURES) SECTION. ABSORB SPILL WITH INERT
MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL
WASTE CONTAINER. CLEAN UP S PILLS IMMEDIATELY, OBSERVING
PRECAUTIONS IN PROTECTIVE EQUIPMENT SECTION.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE
WITH ADEQUATE VENTILATION. DO NOT GET ON SKIN OR IN EYES. DO NOT
INGEST OR INHALE. DISCARD CONTAMINATE D SHOES. STORAGE: STORE IN
A COOL PLACE IN THE ORIGINAL CONTAINER AND PROTECT (OTHER
PRECAUTIONS)
Other Precautions:N/P. HANDLING AND STORAGE PRECAUTIONS (CONT): FROM
SUNLIGHT. KEEP CONTAINERS TIGHTLY CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN . A RESPIRATORY PROTECTION PROGRAM THAT MEETS
OSHA'S 29 CFR 1910.134 AND ANSI 288.2 REQUIREMENTS OR EUROPEAN
STANDARD EN 149 M UST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT
SKIN EXPOSURE.
Supplemental Safety and Health
GENERAL INFORMATION: USE PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN
(CONTROL MEASURES) SECTION.
================== Physical/Chemical Properties ==================
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:=0.C, 32.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL
Spec Gravity:NOT AVAILABLE
pH:BASIC
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:SOLUBLE IN WATER.
Appearance and Odor:LIQUID; CLEAR, COLORLESS; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN, AMMONIA, AMINES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:RTECS#: CAS# 2052-49-5: BS5425000. CAS#
7732-18-5: ZC0110000. LD50/LC50: NOT AVAILABLE. CAS# 7732-18-5:
ORAL, RAT: LD50= >90 ML/KG. CARCINOGENICITY: 1-BUTANAMINIUM,
N,N,N-TRIBUTYL-, HYDROXIDE- NOT LI STED BY ACGIH, IARC, NIOSH, NTP
OR OSHA. WATER: NOT LISTER BY ACGIH, IARC, NIOSH, NTP OR OSHA.
EPIDEMIOLOGY: NO DATA AVAILABLE. TERATOGENICITY: NO DATA
AVAILABLE. REPRODUCTIVE EFFECTS: NO DATA AVAI LABLE.
NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: NO DATA AVAILABLE.
OTHER STUDIES: NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT
AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT W/ FEDERAL,
STATE & LOCAL REGULATIONS. RCRA D-SERIES MAX CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LISTED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED. NOT LISTED AS A MATER IAL
BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
=================== MSDS Transport Information ===================
Transport Information:U.S. D.O.T.-SHIPPING NAME: CAUSTIC ALKALI
LIQUIDS, N.O.S. (TETRABUTYLAMMONIUM HYDROXIDE). HAZARD CLASS: 8.
UN NUMBER: UN1719. PACKING GROUP: II. IMO: NO INFORMATION
AVAILABLE. IATA: NO INFORMATIO N AVAILABLE. RID/ADR: NO
INFORMATION AVAILABLE. CANADIAN TDG: SHIPPING NAME: ALKALINE
CAUSTIC LIQUID NOS (TETRABUTYLAMMONIUM HYDROXIDE). HAZARD CLASS:
8. UN NUMBER: UN1719.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS #2052-49-5: ACUTE,
FLAMMABLE. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION
313. STATE REGS (CONT): DSL/NDSL LIST. THIS PRODUCT HAS A
WHIMIS CLASSIFICATION OF E. NEITHER CAS# LISTED ON CANADA'S
INGREDIENT DISCLOSURE LIST.
Federal Regulatory Information:TSCA: CAS #'S 2052-49-5 & 7732-18-5 IS
LISTED ON TSCA INVENTORY. NONE OF CHEMICALS ARE ON HEALTH & SAFETY
REPORTING LIST. NONE OF CHEMICALS IN PRODUCT ARE UNDER CHEMICAL
TEST RULE. NONE OF CHEMICALS L ISTED UNDER TSCA SECTION 12B. NONE
OF CHEMICALS IN MATERIAL HAVE A SNUR (SIGNIFICANT NEW USE RULE)
UNDER TSCA. CLEAN AIR ACT: MATERIAL DOES NOT CONTAIN ANY HAZARDOUS
AIR POLLUTANTS, CLASS 1 OR CLASS 2 OZONE DEPLETORS. CLEAN WATER
ACT: NONE OF CHEMICALS IN PRODUCT LISTED AS HAZARDOUS SUBSTANCES
UNDE R CWA, PRIORITY POLLUTANTS UNDER CWA OR TOXIC POLLUTANTS UNDER
CWA. OSHA: NONE OF CHEMICALS IN PRODUCT CONSIDERED HIGHLY HAZARDOUS
BY OSHA.
State Regulatory Information:1-BUTANAMINIUM, N,N,N-TRIBUTYL-, HYDROXIDE
OR WATER ARE NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL OR
NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN
THIS PRODUCT ARE LISTED . EUROPEAN / INTERNATIONAL REGULATIONS:
EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVES. HAZARD SYMBOLS:
C. RISK PHRASES: R 34: CAUSES BURNS. SAFETY PHRASES: S 26: IN CASE
OF CONTACT WITH EYES, RI NSE IMMEDIATELY. S 28: AFTER CONTACT WITH
SKIN, WASH IMMED WITH PLENTY OF (TO BE SPECIFIED BY MFR). WGK
(WATER DANGER/PROTECTION): CAS #'S 2052-49-5 & 7732-18-5: NO INFO.
AVAILABLE. CANADA: BOTH CAS #'S LISTED ON CANADA'S (SARA TITLE III)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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