===================== Product Identification =====================
MSDS NAME:SC-431
NIIN:01-415-0559
Status Code:A
MSDS Number: CLCGW
=== Responsible Party ===
Company:NALCO CHEMICAL COMPANY
Address:ONE NALCO CENTER
City:NAPERVILLE
State:IL
ZIP:60563-1198
Country:US
Info Phone Num:(312) 981-9500
Emergency Phone Num:(800) 462-5378 (800) I-M-ALERT
CAGE:89524
=== Contractor Identification ===
Company:ONDEO NALCO COMPANY
Address:ONDEO NALCO CENTER
Box:City:NAPERVILLE
State:IL
ZIP:60563-1198
Country:US
Phone:(630) 305-1000
Contract Num:SP0450-01-M-ZA42
CAGE:89524
============= Composition/Information on Ingredients =============
Name:HYDROTREATED HEAVY NAPHTHA
CAS:64742-48-9
Minumum % Wt:60.
Maxumum % Wt:100.
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): >10,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HUMAN HEALTH HAZARDS-ACUTE: EYE-CAN
CAUSE MILD IRRITATION. SKIN-CAN CAUSE MODERATE IRRITATION.
INGESTION-NOT A LIKELY ROUTE OF EXPOSURE. MAY CAUSE NAUSEA AND
VOMITING. CAN CAUSE CHEMICAL PNEUMONIA IF ASPIRATED INTO LUNGS
FOLLOWING INGESTION. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
INHALATION-REPEATED OR PROLONGED EXPOSURE MAY IRRITATE THE
RESPIRATORY TRACT. HUMAN HEALTH HAZARDS-CHRONIC: NO AD VERSE
EFFECTS EXPECTED OTHER THAN THOSE MENTIONED.
Explanation of Carcinogenicity:NONE OF THE SUBSTANCES IN THIS PRODUCT
ARE LISTED AS CARCINOGENS BY THE INTERNATIONAL AGENCY FOR RESEARCH
ON CANCER (IARC), THE NATIONAL TOXICOLOGY PROGRAM (NTP) OR THE
AMERICAN CONFERENCE ON GOVERNME NTAL INDUSTRIAL HYGIENISTS (ACGIH).
Effects of Overexposure:ACUTE: INHALATION OF HIGH CONCENTRATIONS OF
ORGANIC SOLVENTS CAN CAUSE NAUSEA, DIZZINESS, VOMITING, STUPOR OR
UNCONSCIOUSNESS. CHRONIC: FREQUENT OR PROLONGED CONTACT WITH
PRODUCT MAY DEFAT AND DRY THE SKIN, LEADING TO DISCOMFORT AND
DERMATITIS.
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS CONDITION.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYE WITH WATER FOR AT LEAST 15 MINUTES
WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:
IMMEDIATELY WASH WITH PLENTY OF SOAP & WATER. IF SYMPTOMS DEVELOP,
SEEK MEDICAL A DVICE. INGESTION: DO NOT INDUCE VOMITING: CONTAINS
PETROLEUM DISTILLATES AND/OR AROMATIC SOLVENTS. IF CONSCIOUS,
WASHOUT MOUTH AND GIVE WATER TO DRINK. GET MEDICAL ATTENTION.
INHALATION: REMOVE TO FRE SH AIR, TREAT SYMPTOMATICALLY. IF
SYMPTOMS DEVELOP, SEEK MEDICAL ADVICE. NOTE TO PHYSICIAN: BASED ON
THE INDIVIDUAL REACTION OF THE PATIENT, THE PHYSICIAN'S JUDGEMENT
SHOULD BE USED TO CONTROL SYMPTOM S & CLINICAL CONDITION.
===================== Fire Fighting Measures =====================
Flash Point:=40.C, 104.F
Autoignition Temp:=292.8C, 559.F
Lower Limits:1.2V%
Upper Limits:9.6V%
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY POWDER, OTHER
EXTINGUISHING AGENT SUITABLE FOR CLASS B FIRES. FOR LARGE FIRES,
USE WATER SPRAY OR FOG, THOROUGHLY DRENCHING THE BURNING MATERIAL.
Fire Fighting Procedures:IN CASE OF FIRE, WEAR A FULL FACE
POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
SUIT. WATER MIST MAY BE USED TO COOL CLOSED CONTAINERS. DO NOT USE
WATER UNLESS FLOODING AMOUNTS A RE AVAILABLE.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID; MAY FORM COMBUSTIBLE
MIXTURES AT OR ABOVE THE FLASH POINT. EMPTY PRODUCT CONTAINERS MAY
CONTAIN PRODUCT RESIDUE. DO NOT PRESSURIZE, CUT, HEAT, WELD, OR
EXPOSE CONTAINERS TO FLAME O R OTHER SOURCES OF IGNITION. MAY
EVOLVE OXIDES OF CARBON (COX) UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILLS-SOAK UP SPILL WITH ABSORBENT
MATERIAL. PLACE RESIDUES IN A SUITABLE, COVERED, PROPERLY LABELED
CONTAINER. WASH AFFECTED AREA. LARGE SPILL-CONTAIN LIQUID USING
ABSORBENT MATERIAL, BY DIGGI NG TRENCHES OR BY DIKING. RECLAIM INTO
RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR PROPER DISPOSAL. CLEAN
CONTAMINATED SURFACES WITH WATER OR AQUEOUS CLEANING AGENTS. "SEE
OTHER INFORMATION"
====================== Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. KEEP
THE CONTAINERS CLOSED WHEN NOT IN USE. DO NOT USE IN LOCATIONS
WHERE VAPOR IS LIKELY TO TRAVEL TO WELDING FLAMES OR ARCS OR TO
OTHER HOT SURFACES. VAPORS ARE MUCH H EAVIER THAN AIR, THIS CAN
RESULT IN UNEVEN DISTRIBUTION. DO NOT TAKE INTERNALLY.
Other Precautions:WASTE- HAZARDOUS WASTE MUST BE TRANSPORTED BY A
LICENSED HAZARDOUS WASTE TRANSPORTER & DISPOSED OF OR TREATED IN A
PROPERLY LABELED HAZARDOUS WASTE
TREATMENT/STORAGE/DISPOSAL/RECYCLING FACILITY. CONSU LT LOCAL,
STATE & FEDERAL REGS FOR SPECIFIC REQUIREMENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF SIGNIFICANT MISTS, VAPORS OR AEROSOLS ARE
GENERATED AN APPROVED RESPIRATOR IS RECOMMENDED. AN ORGANIC VAPOR
CARTRIDGE WITH DUST/MIST PREFILTER OR SUPPLIED AIR MAY BE USED. IN
EVENT OF EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS A
POSITIVE PRESSURE, FULL-FACEPIECE SCBA SHOULD BE USED. INSTITUTE A
COMPLETE RESPIRATORY PROTECTION PROGRAM.
Ventilation:USE GENERAL VENTILATION WITH LOCAL EXHAUST VENTILATION.
Protective Gloves:NITRILE GLOVES, VITON GLOVES, POLYVINYL ALCOHOL
GLOVES.
Eye Protection:WEAR CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:WEAR IMPERVIOUS APRON AND BOOTS. KEEP AN EYE
WASH FOUNTAIN AVAILABLE. KEEP A SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:IF CLOTHING IS CONTAMINATED, REMOVE CLOTHING
AND THOROUGHLY WASH THE AFFECTED AREA. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
Supplemental Safety and Health
HANDLING- DO NOT BREATHE VAPORS/GASES/DUST. HAVE EMERGENCY EQUIPMENT
READILY AVAILABLE. STORE-STORE AWAY FROM HEAT & IGNITION SOURCES.
STORE SEPERATELY FROM OXIDIZERS. STORE CONTAINERS TIGHTLY CLOSED.
USE PROPER GROUNDING PROCEDURES. HAVE APPROPIATE FIRE EXTINGUISHERS
NEARBY.
================== Physical/Chemical Properties ==================
HCC:F4
Melt/Freeze Pt:<-60.C, -76.F
Vapor Density:4.94
Spec Gravity:0.75@61F/16C
Viscosity:1.3 CST
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID; MILD, HYDROCARBON ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZERS (E.G. CHLORINE, PEROXIDES, CHROMATES,
NITRIC ACID, PERCHLORATE, CONCENTRATED OXYGEN, PERMANGANATE) MAY
GENERATE HEAT, FIRES, EXPLOSIONS AND/OR TOXIC VAPORS.
Stability Condition to Avoid:HEAT AND SOURCES OF IGNITION INCLUDING
STATIC DISCHARGES.
Hazardous Decomposition Products:UNDER FIRE CONDITIONS: OXIDES OF
CARBON.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:THE FOLLOWING RESULTS ARE FOR THE PRODUCT:
ACUTE ORLA TOXICITY: SPECIES LD50 >10,000 MG/KG, TESTED
SUBSTANCE-PRODUCT. RATING: NON-HAZARDOUS. ACUTE DERMAL TOXICITY:
SPECIES LD50 >3,160 MG/KG, TEST SUBS TANCE-PRODUCT. RATING:
NON-HAZARDOUS. SENSITIZATION: THIS PRODUCT IS NOT EXPECTED TO BE A
SENSITIZER. HUMAN HAZARD CHARACTERIZATION: BASED ON OUR HAZARD
CHARACTERIZATION, THE POTENTIAL HUMAN HAZARD IS : MODERATE.
===================== Ecological Information =====================
Ecological:ECOTOXICOLOGICAL EFFECTS: SPECIES: FATHEAD MINNOW. EXPOSURE:
96 HOURS. LC50: 5,000 MG/L. TESTED SUBSTANCE: PRODUCT. RATING:
ESSENTIALLY NON-TOXIC. ENVIRONMENTAL HAZARD AND EXPOSURE
CHARACTERIZATION: B ASED ON OUR HAZARD CHARACTERIZATION, THE
POTENTIAL ENVIRONMENTAL HAZARD IS: MODERATE. IF RELEASED INTO THE
ENVIRONMENT, SEE CERCLA/SUPERFUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT COULD MEET
THE CRITERIA OF A HAZARDOUS WASTE AS DEFINED BY THE RCRA 40 CFR
261. BEFORE DISPOSAL, IT SHOULD BE DETERMINED IF THE WASTE MEETS
THE CRITERIA. HAZARDOUS WASTE: D001, D018. "SEE OTHER PRECAUTIONS"
=================== MSDS Transport Information ===================
Transport Information:LAND: PROPER SHIPPING NAME: PETROLEUM
DISTILLATES, N.O.S. TECHNICAL NAME(S): PETROLEUM HYDROCARBONS.
UN/ID NO: 1268. HAZARD CLASS-PRIMARY: 3. PACKING GROUP: III. FLASH
POINT: 40C/104F. AIR (ICAO/IATA) : PROPER SHIPPING NAME: PETROLEUM
DISTILLATES, N.O.S. TECHNICAL NAME(S): PETROLEUM HYDROCARBONS.
UN/ID NO: 1268. HAZARD CLASS-PRIMARY: 3. PACKING GROUP: III. IATA
CARGO PACKING INSTRUCTIONS: 310. IAT A CARGO AIRCRAFT LIMIT: 220L
(MAX NET QUANTITY/PACKAGE). MARINE IMDG/IMO). PROPER SHIPPING
NAME: PETROLEUM DISTILLATES, N.O.S. TECHNICAL NAME(S): PETROLEUM
HYDROCARBONS. UN/ID NO: 1268. HAZARD CLASS- PRIMARY: 3. PACKING
GROUP: III.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA/SUPERFUND, 40 CFR 117, 302:
NOTIFICATION OF SPILL OF THIS PRODUCT IS NOT REQUIRED.
SARA/SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 (TITLE
III)-SECTION 302, 311, 312, & 313: SECTION 302- EXTREMELY HAZARDOUS
SUBSTANCES(40 CFR 355): THIS PRODUCT DOES NOT CONTAIN SUBSTANCES
LISTED IN APPENDIX A & B AS AN EXTREMELY HAZARDOUS SUBSTANCES.
SECTION 311 & 312: (X) IMMEDIATE (ACUTE) HEALTH HAZA RD, (X) FIRE
HAZARD. UNDER SARA 311 & 312: 500 LBS OR TPQ, WHICH EVER IS LOWER,
FOR EXTREMELY HAZADOUS SUBSTANCES & 10,000 LBS FOR ALL OTHER
HAZARDOUS CHEMICALS. THIS PRODUCT DOES NOT CONTAIN SUBSTAN CES ON
THE LIST OF TOXIC CHEMICALS.
Federal Regulatory Information:HYDROTREATED HEAVY NAPTHA: COMBUSTIBLE.
TSCA: THIS CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON THE TSCA 8(B)
INVENTORY (40 CFR 710). FEDERAL WATER POLLUTION CONTROL ACT, CLEAN
WATER ACT, 40 CFR 401.15/ FORMERLY SEC. 307, 40 CFR/FORMERLY SEC.
311: NONE OF THE SUBSTANCES ARE SPECIFICALLY LISTED IN THE
REGULATION. CLEAN AIR ACT, SEC. 111: NONE OF THE SUBSTANCES ARE
SPECIFICALLY LISTED IN THE REGULATION .
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
DOES NOT CONTAIN SUBSTANCES WHICH REQUIRE WARNING UNDER CALIFORNIA
PROPOSITION 65. MICHIGAN CRITICAL MATERIALS: NONE OF THE SUBSTANCES
ARE SPECIFICALLY LISTED I N THE REGULATION. STATE RIGHT TO KNOW
LAWS: NONE OF THE SUBSTANCES ARE SPECIFICALLY LISTED IN THE
REGULATION.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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