===================== Product Identification =====================
MSDS NAME:MIL-P-53022B, TYPE II, PART B, EPOXY POLYAMIDE PRIMER
NIIN:01-309-0328
Status Code:A
MSDS Number: CLFFY
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:630 E 13TH ST
City:ANDOVER
State:KS
ZIP:67002
Country:US
Info Phone Num:216-566-2917
Emergency Phone Num:216-566-2917
Preparer's Name:HENRY SIMMONS
CAGE:1BGY0
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO
Address:630 E 13TH ST
Box:City:ANDOVER
State:KS
ZIP:67002
Country:US
Phone:216-566-2902;216-566-2917
CAGE:1BGY0
============= Composition/Information on Ingredients =============
Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:21.
OSHA PEL:SEE TABLE Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:1-BUTANOL
CAS:71-36-3
RTECS #:EO1400000
= Wt:2.
OSHA PEL:300 MG/M3;100 PPM
ACGIH STEL:C152 MG/M3;C50 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PHENYLMETHANOL
CAS:100-51-6
RTECS #:DN3150000
= Wt:4.
Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
= Wt:12.
OSHA PEL:590 MG/M3;200 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:METHYL N-PROPYL KETONE
CAS:107-87-9
RTECS #:SA7875000
= Wt:19.
OSHA PEL:700 MG/M3;200 PPM
ACGIH TLV:705 MG/M3;200 PPM
ACGIH STEL:881 MG/M3;250 PPM
Name:METHYL ISOBUTYL KETONE
CAS:108-10-1
RTECS #:SA9275000
= Wt:1.
OSHA PEL:410 MG/M3;100 PPM
ACGIH TLV:205 MG/M3;50 PPM
ACGIH STEL:307 MG/M3;75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TRI (DIMETHYLAMINOMETHYL) PHENOL
= Wt:1.
Name:4,4'-ISOPROPYLIDENEDIPHENOL
CAS:80-05-7
RTECS #:SL6300000
= Wt:4.
Name:1-METHOXY-2-PROPYL ACETATE
CAS:108-65-6
RTECS #:AI8925000
= Wt:13.
Name:DIETHYLENETRIAMINE
CAS:111-40-0
RTECS #:IE1225000
= Wt:4.
ACGIH TLV:4.2 MG/M3;1 PPM
Name:EPOXY POLYMER
= Wt:3.
Name:POLYAMIDE
= Wt:4.
Name:POLYAMINE
= Wt:10.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
CHRONIC: METHYL ETHYL KETONE MAY INC REASE THE NERVOUS SYSTEM
EFFECTS OF OTHER SOLVENTS. PROLONGED OVEREXPOSURES TO SOLVENT
INGREDIENTS IN SECTION II MAY CAUSE ADVERSE EFFECTS TO THE LIVER,
URINARY, BLOODS FORMING, CARDIOVASCULAR, NERVO US AND REPRODUCTIVE
SYSTEMS. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED
OVEREXPOSURES TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURES TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXP OSURE.
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN
SUSCEPTIBLE PERSONS.
======================= First Aid Measures =======================
First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREAS
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE-USE . EYES: FLUSH EYES WITH LARGE AMOUNTS OF
WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SWALLOWED: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING.
GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=-6.1C, 21.F
Lower Limits:1.0
Upper Limits:13.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINING BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED CLOSED CONTAINER S TO PREVENT PRESSURE BUILD-UP AND
POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO
HOT SURFACES REQUIRES SPECIA L PRECAUTIONS. DURING EMERGENCY
CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A
HEALTH HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE FLAMMABLE. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAME. DURING USE AND UNTIL ALL VAPORS ARE
GONE: KEEP AREA VENTILATED ? DO NOT SMOKE ? EXTINGUISH ALL FLAMES,
PILOT LIGHTS, AND HEATERS ? TURN OFF STOVES, ELECTRIC TOOLS AND
APPLIANCE, AND ANY OTHER SOURCES OF IGNITION.
Other Precautions:THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS
BEFORE USE. BEFORE OPENING THE PACKAGE, READ AND FOLLOW WARNING ON
ALL COMPONENTS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING
AND INHALING THE C ONTENTS CAN BE HARMFUL OR FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED
ORGANIC/PARTICULATES RESPIRATOR APPROVED BY NIOSH/MSHA FOR
PROTECTION AGAINST MATERIALS II. WH EN SANDING OR ABRADING THE
DRIED FILM. WEAR A DUST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA FOR
DUST WHICH MAY BE GENERATED FROM THIS PRODUCT.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN SECTION II IS MAINTAIN BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE SUPPLIER
FOR PROTECTION.
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Other Protective Equipment:USE OF BARRIER CREAM ON EXPOSED SKIN IS
RECOMMENDED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:=78.9C, 174.F
B.P. Text:174-419F
Vapor Density:>AIR
Spec Gravity:0.90
VOC Pounds/Gallon:693
VOC Grams/Liter:5.78
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:80%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF NITROGEN, POSSIBILITY OF HYDROGEN CYANIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINES UNDER THR RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE EPA
HAZARDOUS WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION
108-88-3 TOLUENE 21% 71-36-3
1-BUTANOL 2% 78-93-3 METHYL ETHYL KETONE 12% 108-10-1 METHYL
ISOBUTYL KETONE 1% 80-05-7 4,4? ISOPROPYLINDENIPHENOL 4%
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS CHEMICALS KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER AND
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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