===================== Product Identification =====================
MSDS NAME:EUCK001A MIL-C-46168D TYPE II C-37030 BLACK PART A
NIIN:01-131-6254
Status Code:A
MSDS Number: CLFFB
=== Responsible Party ===
Company:SPRAYLAT CORP
Address:1701 E 122ND ST
City:CHICAGO
State:IL
ZIP:60633
Country:US
Info Phone Num:773-646-5900
Emergency Phone Num:773-646-5900
Preparer's Name:JIM SCHMIDT
Chemtrec Ind/Phone:(800)424-9300
CAGE:0ULT0
=== Contractor Identification ===
Company:SPRAYLAT CORP
Address:1701 E 122ND ST
Box:City:CHICAGO
State:IL
ZIP:60633
Country:US
Phone:773-646-5900
CAGE:0ULT0
============= Composition/Information on Ingredients =============
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
= Wt:2.92
OSHA PEL:3.50 MG/M3
ACGIH TLV:3.50 MG/M3
Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
< Wt:10.
OSHA PEL:15 MG/M3(TOTAL DUST)
ACGIH TLV:10 MG/M3(TOTAL DUST)
Name:METHYL ETHYL KETONE (VAPOR PRESSURE: 70.00. LEL: 1.8).
CAS:78-93-3
RTECS #:EL6475000
< Wt:10.
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
ACGIH STEL:300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TALC
CAS:14807-96-6
RTECS #:WW2710000
< Wt:50.
OSHA PEL:2.00 MG/M3
ACGIH TLV:2.00 MG/M3
Name:AMORPHOUS SILICA
CAS:67762-90-7
< Wt:10.
OSHA PEL:6.00 MG/M3;RESP DUST
ACGIH TLV:5.00 MG/M3;RESP DUST
Name:PGME ACETATE (VAPOR PRESSURE: 3.80. LEL: 1.5).
CAS:108-65-6
RTECS #:AI8925000
< Wt:50.
OSHA PEL:NO EST.
ACGIH TLV:NO EST.
Name:CRYSTALINE SILICA (RESPIRABLE)
CAS:14808-60-7
RTECS #:VV7330000
= Wt:.36
OSHA PEL:.10MG/M3;RESP DUST
ACGIH TLV:.10 MG/M3;RESP DUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT TESTED AS A MIXTURE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXCESSIVE OVEREXPOSURE:
METHY ETHYL KETONE: PROLONGED OVEREXPOSURE TO VAPORS MAY CAUSE
BLOOD DISORDERS OR DAMAGE TO BLOOD FORMING ORGANS. CHRONIC
OVEREXPOSURE OR INGESTION MAY CAUSE KIDNEY & LIVER INJURY.
PROLONGED OVEREXPOSURE MAY CAUSE HEADACHE, NAUSEA, VOMIT, DIZZINESS
OR LOSS OF CONSCIOUSNESS. IRRITATING TO MUCOUS MEMBRANES. INGESTION
WILL CAUSE IRRITATION OF GASTROINTESTINAL TRACT & MAY CAUSE
EFFECTS RESEMBLING THOSE FROM INHALATION OF VAPOR. SEVERELY
IRRITATING TO EYES. EXPOSURE MAY CAUSE EXTENSIVE CORNEAL INJURY.
MAY CAUSE IRRIT, DRYING, CRACKING, DERMATITIS ON PROLONGED EXP
OSURE TO SKIN. (SIGNS OF OVEREXPOSURE)
Explanation of Carcinogenicity:CRYSTALLINE SILICA: IARC GROUP 1, VOL
68, PAGE 41, 1997. NTP KNOWN HUMAN CARCINOGEN, NINTH REPORT ON
CARCINOGENS. CARBON BLACK: IARC GROUP 2B. VOL 65, PAGE 149, 1996.
Effects of Overexposure:HEALTH HAZARDS (CONT'D): CRYSTALLINE SILICA
(RESPIRABLE): MAY CAUSE SHORTNESS OF BREATH. PROLONGED OVEREXPOSURE
BY INHALATION MAY CAUSE DELAYED LUNG INJURY/DISEASES (SILICOSIS).
CAN CAUSE SEVERE & PER MANENT DMG TO LUNGS (PULMONARY FIBROSIS).
MAY CAUSE NOSE, THROAT & UPPER RESPIRATORY TRACT IRRITATION. SPRAY
MIST/VAPORS OF SPRAY PAINTS MAY CAUSE IRRITATION TO EYES,
NOSE,THROAT, UPPER RESPIRATORY TR ACT, MUCOUS MEMBRANES & SKIN. MAY
CAUSE ALLERGIC RESPIRATORY REACTION. EFFECTS MAY BE PERMANENT. THIS
MATERIAL CONTAINS SUSPECT OR POTENTIAL CARCINOGEN. AMORPHOUS
SILICA: MAY CAUSE SHORTNESS OF BREATH . PULMONARY EDEMA MAY (STATE
REGULATORY)
======================= First Aid Measures =======================
Eyes: FLUSH WITH LUKE WARM WATER FOR 15 MINS. SEEK PHYSICIAN
IMMEDIATELY. SKIN: FLUSH WASH WITH COPIOUS AMOUNTS OF LUKE WARM
WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. CONTACT A PHYSICIAN
IMMEDIATE LY. INHALATION: REMOVE EXPOSED INDIVIDUAL TO FRESH AIR.
RESTORE BREATHING IF REQUIRED. CONTACT PHYSICIAN IMMEDIATELY.
INGESTION: RINSE MOUTH IMMEDIATELY. GIVE EXPOSED INDIVIDUAL 6 TO 8
OUNCES OF LIQUI D. (NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS
PERSON). DO NOT INDUCE VOMITING UNLESS ADVISED BY PHYSICIAN.
CONTACT A PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:=-5.C, 23.F
Autoignition Temp:Autoignition Temp Text:N/DET.
Lower Limits:1.5
Upper Limits:10.2
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICALS OR ALCOHOL FOAM.
A WATER STREAM CAN SCATTER FLAMES. A SPRAY OF WATER MAY BE USED TO
COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO
NOT ENTER CONFINED SPACE WITHOUT HELMET, FACE SHIELD, BUNKER COAT,
GLOVES, RUBBER BOOTS, AND A POSITIVE PRESSURE NIOSH-APPROVED
SELF-CONTAINED BREATHING AP PARATU. FIGHT FIRE FROM A SAFE DISTANCE
OR A PROTECTED LOCATION. FLAMMABILITY CLASSIFICATION: CLASS 1B.
Unusual Fire/Explosion Hazard:THIS LIQUID AND VAPORS ARE A DANGEROUS
FIRE HAZARD AND MODERATE EXPLOSION HAZARD WHEN EXPOSED TO HEAT,
FLAME OR ANY SOURCE OF IGNITION. VAPORS MAY BE HEAVIER THAN AIR AND
MAY TRAVEL ALONG THE GROUND T O DISTANT IGNITION SOURCE AND FLASH
BACK. KEEP WELDING OR CUTTING EQUIPMENT AWAY FROM PRODUCT.
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND AND AWAY FROM SPILL UNLESS WEARING
APPROPRIATE PROTECT EQUIPMENT. STOP AND/OR CONTAIN DISCHARGE IF IT
MAY BE DONE SAFELY. KEEP ALL SOURCES OF IGNITION AWAY. VENTILATE
AREA OF SPILL. USE NO N-SPARKING TOOLS FOR CLEANUP. COVER WITH
INERT MATERIAL TO REDUCE FUMES. KEEP OUT OF DRAINS, SEWERS,
WATERWAYS. CONTACT FIRE AUTHORITIES. NOTIFY LOCAL HEALTH AND
POLLUTION CONTROL (WASTE DISP METH)
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP PRODUCT CONTAINER COOL, DRY &
AWAY FROM SOURCES OF IGNITION. USE & STORE PRODUCT WITH ADEQUATE
VENTILATION. DO NOT SMOKE IN STORAGE AREAS. KEEP CONTAINERS TIGHTLY
CLOSED WHEN NOT IN USE. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS & OPEN FLAMES. SPRINKLER FIRE PROTECTION IS (OTHER PREC)
Other Precautions:HANDLING/STORAGE (CONT'D): IS DESIRABLE IN AREAS OF
STORAGE, HANDLING, USE. PERSONNEL SHOULD AVOID INHALATION OF
VAPORS/MIST. PERSONAL CONTACT W/PRODUCT SHOULD BE AVOIDED. SHOULD
CONTACT BE MADE, REMO VE SATURATED CLOTHING & FLUSH AFFECTED SKIN
AREAS W/WATER. CONTAINERS OF MATERIAL MAY BE HAZARDOUS W HEN (SUPP
SAFETY)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR AN APPROPRIATE, PROPERLY FITTED RESPIRATOR
(NIOSH APPROVED) DURING AND AFTER APPLICATION UNLESS AIR MONITORING
DEMONSTRATES VAPOR/MIST LEVELS ARE BELOW APPLICABLE LIMITS. USE
DUST MASK OR NIOSH-A PPROVED RESPIRATOR IF THE CONCENTRATION IS
HIGH. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR
USE.
Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR/DUST/MIST
CONCENTRATION. IF EXPOSURE EXCEEDS TLV, USE A NIOSH-APPROVED
RESPIRATOR TO PREVENT OVEREXPOSURE.
Protective Gloves:RESISTANT GLOVES SUCH AS NATURAL RUBBER, NEOPRENE,
BUNA N OR NITRILE.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES . USE SAFETY EYE
(OTHER PROT EQUIP)
Other Protective Equipment:ANSI DESIGNED EYEWASH STATIONS & SAFETY
SHOWERS SHOULD BE READILY AVAILABLE IN USE & HANDLING AREA. AN
APRON SHOULD BE WORN TO AVOID SKIN CONTACT. EYE PROT: WEAR
W/PERFORATED SIDESHIELDS/GOGGLES (MFR).
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND USING
WASHROOM. REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND DO NOT REUSE
UNTIL IT HAS BEEN PROPERLY LAUNDERED.
Supplemental Safety and Health
OTHER PRECAUTIONS (CONT'D): WHEN EMPTIED. SINCE EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, &/OR SOLID), ALL HAZARD
PRECAUTIONS GIVEN MUST BE OBSERVED. DO NOT FLAME CUT OR WELD EMPTY
DR UMS. DO NOT BREATHE SPRAY MIST/VAPOR (IF PRESENT) OF ANY SPRAY
PAINT. AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.
================== Physical/Chemical Properties ==================
Boiling Pt:=79.4C, 175.F
B.P. Text:175.0-284.0 F
Melt/Freeze Pt:M.P/F.P Text:NOT ESTIMATED.
Vapor Pres:SEE OTHER INFO
Vapor Density:> AIR
VOC Grams/Liter:4.73
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:NOT AVAILABLE.
Appearance and Odor:LIQUID. ODOR: MODERATE KETONE.
Percent Volatiles by Volume:60.00
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASED ON INGREDIENT(S): PGME ACETATE, CARBON BLACK, METHYL ETHYL
KETONE, TALC: THIS PRODUCT IS INCOMPATIBLE WITH STRONG OXIDIZERS;
MAY CAUSE FIRE OR EXPLOSION ON CONTACT. BASED ON CRYSTALLINE
SILICA: AVOID HYDROFLORIC ACID.
Stability Condition to Avoid:AVOID EXPOSURE TO SPARKS, OPEN FLAME, HOT
SURFACES, AND ALL SOURCES OF HEAT AND IGNITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION: IN THE PRESENCE
OF AIR MAY FORM OXIDES OF CARBON AND VARIOUS HYDROCARBONS.
=================== Toxicological Information ===================
Toxicological Information:THIS PRODUCT CONTAINS ONE OR MORE REPORTED
CARCINOGENS OR SUSPECTED CARCINOGENS WHICH ARE NOTED NTP, IARC
AND/OR OSHA IN THE CARCINOGEN SECTION. THIS PRODUCT CONTAINS
PIGMENTS WHICH MAY BECOME A DUS T NUISANCE WHEN REMOVED BY ABRASIVE
BLASTING, SANDING, OR GRINDING. PHYSICAL DATA (CONT'D): VAPOR
PRESSURE: PGME ACETATE - 3.80. METHYL ETHYL KETONE - 70.00. WEIGHT
PER GALLON: 11.5. ODOR THRESHOLD: N OT AVAILABLE. % VOLATILE BY
WEIGHT: 40.99. COEFFICIENT OF WATER/OIL DISTRIBUTION: NOT
AVAILABLE. NOTE 1: THE VOC CONTENT IS DETERMINED BY USING A PERCENT
SOLIDS BASIS, LESS WATER & EXEMPT SOLVENTS, (E COLOGICAL INFO)
===================== Ecological Information =====================
Ecological:N/P. TOXICOLOGICAL (CONT'D): FOR ADHESIVES, COATINGS & INKS
& THE CALCULATIONS OF EPA REFERENCE METHOD 24 OR EQUIVALENT ASTM
METHOD APPROVED IN THE EXECUTIVE OFFICE. NOTE 2: IF THIS PRODUCT
CONTAINS A CETONE, THE FOLLOWING APPLIES: THE FEDERAL EPA HAS
DELISTED ACETONE AS A VOC. THEREFORE, ALTHOUGH THIS PROD CONTAINS
ACETON, THE VOC LISTED DOES NOT INCLUDE ACETONE IN THE VOC
CALCULATION. INDIVIDUAL STATES MAY HAVE OTHER REGULATIONS. CHECK
WITH YOUR STATE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE
LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS. SPILL/RELEASE
PROCEDURES (CONT'D): AGENCIES. CALL SPILL RESPONSE TEAMS IF LARGE
SPILL. DO NOT FLUSH TO SEWER, WATERSHED OR WATERWAY.
=================== MSDS Transport Information ===================
Transport Information:DOT: FLAMMABLE LIQUID.
===================== Regulatory Information =====================
SARA Title III Information:THE FOLLOWING INGREDIENT(S) ARE SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING
AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372: METHYL
ETHYL KETONE.
Federal Regulatory Information:ALL THE COMPONENTS IN THIS PRODUCT ARE
LISTED IN THE TOXIC SUBSTANCE CONTROL ACT (TSCA) INDEX.
State Regulatory Information:N/P. SIGNS/SYMPTOMS OVEREXPOSURE (CONT'D):
DEVELOP WITH INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL.
PGME ACETATE: IRRITATING TO THE MUCOUS MEMBRANES. CARBON BLACK:
THIS PRODUCT MAY BE HARMFUL IF IT IS SWALLOWED. THIS PRODUCT MAY
CAUSE IRRITATION, DRYING, CRACKING OR DERMATITIS ON PROLONGED
EXPOSURE TO SKIN. NOTICE: REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENT RATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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