===================== Product Identification =====================
MSDS NAME:SPS 5050, SIFCO SELECTRON PLATING SOLUTION CADMIUM (ACID)
NIIN:01-349-8654
Status Code:A
MSDS Number: CLFGG
=== Responsible Party ===
Company:SIFCO SELECTIVE PLATING DIVISION OF SIFCO INDUSTRIES, INC.
Address:5708 SCHAAF ROAD
City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Info Phone Num:216-524-0099 /FAX: 216-524-6331
Emergency Phone Num:INTL: 703-527-3887(COLLECT)
Chemtrec Ind/Phone:(800)424-9300
CAGE:11924
=== Contractor Identification ===
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-00-M-D346
CAGE:11924
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-00-M-SC50
CAGE:11924
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-00-M-SE33
CAGE:11924
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-01-M-ZD19
CAGE:11924
Company:SIFCO SELECTIVE PLATING DIV OF SIFCO INDUSTRIES INC.
Address:5708 SCHAAF ROAD
Box:City:CLEVELAND
State:OH
ZIP:44131-1394
Country:US
Phone:216-524-0099/ FAX: -6331
Contract Num:SP0450-99-M-ND16
CAGE:11924
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Minumum % Wt:5.
Maxumum % Wt:10.
Other REC Limits:1 MG/M3 (NIOSH)
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3, R DUST
ACGIH STEL:3 MG/M3, R DUST
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CADMIUM SULFATE
CAS:10124-36-4
RTECS #:EV2700000
Minumum % Wt:20.
Maxumum % Wt:30.
Other REC Limits:NIOSH (IDLH)9 MG/M3
OSHA PEL:0.005 MG(CD)/M3
OSHA STEL:0.0025PPM
ACGIH TLV:0.002 MG/M3 R DUST
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:60.
Maxumum % Wt:75.
===================== Hazards Identification =====================
LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS: SKIN, EYES, NASAL
CAVITY, LUNGS, KIDNEYS AND LIVER. EYES: CORROSIVE AND MAY CAUSE
SEVERE DAMAGE. SKIN CONTACT: CORROSIVE, CAUSES BURNS AND POSSIBLE
ALLERGIC REACTION. SUBSTANCE IS POSSI BLY TOXIC VIA SKIN
ULCERATIONS. SKIN ASORPTION: POSSIBLY TOXIC IF ABSORBED THROUGH THE
SKIN. INHALATION: MAY CAUSE SNEEZING, NASAL DISCHARGE, COUGHING,
HEADACHES, DIZZINESS, NAUSEA, FATIGUE OR DIFFICU LTY IN BREATHING.
INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE SEVERE AND PERMANENT
DAMAGE TO MOUTH, THROAT, AND STOMACH. CHRONIC EFFECTS: MAY CAUSE
SEVERE AND DELAYED EFFECTS SUCH AS INFLAMMATION OF LU NGS, CHEMICAL
BRONCHITIS, AND/OR CANCER.
Explanation of Carcinogenicity:CADMIUM SULFATE IS LISTED ON THE LIST
FOR ALL 3 AGENCIES AND ACGIH AS CARCINOGENIC TO HUMAN.
Effects of Overexposure:EYE CONTACT: CORROSION, SEVERE EYE DAMAGE. SKIN
CONTACT: CORROSION, ULCERATIONS. SKIN ABSORPTION:TOXIC EFFECTS.
INHALATION: SNEEZING, NASAL DISCHARGE, COUGHING, HEADACHES,
DIZZINESS, NAUSEA, FATIGUE, BREATHING DIFFICULTY. INGESTION:
PERMANENT DAMAGE TO MOUTH, THROAT, STOMACH. CHRONIC: DAMAGE TO
SKIN, EYES, RESPIRATORY SYSTEM AND TEETH. SEVERE AND DELAYED
INFLAMMATION OF THE LUNGS, CHEMICAL BRONCHI TIS, AND/OR CANCER.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND EYE
CONDITIONS; RESPIRATORY SYSTEM DISORDERS.
======================= First Aid Measures =======================
Eyes: HOLD EYELIDS APART. FLUSH WITH WATER FOR 15 MINUTES.
SKIN: FLUSH WITH WATER FOR 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. DECONTAMINATE CLOTHING AND SHOES.
INHALATION: MOVE TO FRESH AIR. LOOSEN TIGHT CLOTHING, COVER WITH A
BLANKET. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFICULT, GIVE OXYGEN. INGESTION: DO NOT INDUCE
VOMITING. GIVE LARGE QUNATITIE S OF WATER OR MILK WITH 1-2 FRESH
EGGS. GIVE A GLASS OF 1/3 VINEGAR WITH 2/3 WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:WILL NOT BURN.
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ALL. MATERIAL WILL NOT BURN.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS. STRUCTURAL FIRE FIGHTERS'
PROTECTIVE CLOTHING MAY NOT PROVIDE ADEQUATE PROTECTION.
Unusual Fire/Explosion Hazard:CONTACT WITH METALS MAY FORM FLAMMABLE
HYDROGEN GAS. CONTAINERS CAN BUILD UP PRESSURE AND BURST IF EXPOSED
TO HEAT (FIRE). WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE
AREA FOR LATER DISPOSAL.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT WALK THROUGH SPILL. NOTIFY EMERGENCY
COORDINATOR. ELIMINATE ALL SOURCES OF IGNITION. PROVIDE
VENTILATION. DO NOT RELEASE INTO SOIL, SEWERS, OR NATURAL BODIES OF
WATER. WEAR PROPER PERSONAL PROT ECTIVE EQUIPMENT (PPE). CAREFULLY
MOP UP OR VACCUM SPILL AND TRIPLE RINSE WITH WATER INTO PLASTIC
CONTAINER FOR DISPOSAL. RELEASE OF REPORTABLE QUANTITY (RQ)
REQUIRES REPORTING TO PROPER AUTHORITIES.
Neutralizing Agent:SODA ASH AND/OR CRUSHED LIMESTONE.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN
UPRIGHT POSITION. STORE AT 60-90F AWAY FROM INCOMPATIBLE MATERIALS
AND PHYSICAL HAZARDS. DO NOT REMOVE OR DEFACE CONTAINER LABELS. USE
"BUDDY SYSTEM" WHEN WORKING WITH CHEMICALS. DO NOT GET INTO EYES,
ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR, MIST OR GAS.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH AFTER HANDLING.
TRIPLE RINSE CONTAINERS BEFORE DISCARDING PUT NOTHING ELSE IN
CONTAINER. RELEASE OF A REPORTABLE QUANTITY(RQ) REQUIRES
NOTIFICATION OF PROPER AUT HORITIES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS ARE NOT FEASIBLE, THE
RESPIRATORY PROTECTION PROGRAM MUST COMPLY WITH OSHA'S 29 CFR
1910.134, 30 CFR 11 AND ANSI Z88.2 REQUIREMENTS.
Ventilation:LOCAL EXHAUST VENTILATION REQUIRED TO MEET THE PERMISSIBLE
EXPOSURE LIMITS (PEL) DURING THE USE OF THIS PRODUCT.
Protective Gloves:NITRILE, NEOPRENE, VINYL, LATEX GLOVES.
Eye Protection:FACE SHIELD AND SAFETY GLASSES W/SIDE SHIELDS OR
SPLASH-PROOF CHEMICAL GOGGLES.
Other Protective Equipment:IMPERVIOUS BOOTS, APRON, PROTECTIVE CLOTHING
AS REQUIRED BY JOB CONDITIONS. EYE WASH STATION AND SAFETY SHOWER.
WASHING FACILITIES NEAR WORK AREA.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
DO NOT WEAR CONTACT LENSES.
================== Physical/Chemical Properties ==================
HCC:C1
NRC/State Lic Num:NONE
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:<0.C, 32.F
Spec Gravity:1.315 - 1.335
pH:0-1
Evaporation Rate & Reference:<1 (ETHYL ETHER =1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID. NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTIVE METALS, STRONG BASES, OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER NORMAL AMBIENT CONDITIONS.
Hazardous Decomposition Products:SULFUR OXIDES AND CADMIUM.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:NOT AVAILABLE.
===================== Ecological Information =====================
Ecological:NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS. SHIP TO APPROVED TREATMENT/DISPOSAL FACILITY. EPA
WASTE ID NUMBER: D002, D006; CONTAMINATION MAY AFFECT DISPOSAL
REQUIREMENTS. THE RESPONS IBILITY FOR PROPER WASTE DISPOSAL IS WITH
THE GENERATOR OF THE WASTE.
=================== MSDS Transport Information ===================
Transport Information:CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAINS
SULFURIC ACID AND CADMIUM SULFATE), HAZARD CLASS 8, UN 2922,
PACKAGING GROUP I I. LABEL REQUIREMENTS: 8-CORROSIVE, TOXIC, MARINE
POLLUTANT. UNIT CONTAINER POL YETHYLENE BOTTLE. PACKAGING-MEETS
PERFORMANCE ORIENTED PACKAGIG REQUIREMENTS. REPORTABLE QUANTITY
(RQ): >28 LITERS. ERG GUIDE # 154.
===================== Regulatory Information =====================
SARA Title III Information:CADMIUM SULFATE (CAS# 10124-36-4), 30% &
SULFURIC (CAS# 7664-93-9), 10%. CERCLA AND EPCRA: THRESHOLD
PLANNING QUANTITY: >4,455 LITERS, (RELEASE) REPORTABLE QUANTITY:
>28 LITERS. EXTREMELY HAZARDOUS S UBSTANCE: SULFURIC ACID.
Federal Regulatory Information:TSCA: ALL INGREDIENTS OF THIS PRODUCT
ARE LISTED UNDER TSCA. ODS: THIS PRODUCT DOES NOT CONTAIN OZONE
DEPLETING SUBSTANCE. THIS PRODUCT DOES NOT CONTAIN ANY
POLYCHLORINATED BYPHENYLS. CERCLA AND EPCR A: THRESHOLD PLANNING
QUANTITY: >4,455 LITERS, (RELEASE) REPORTABLE QUANTITY: >28 LITERS.
EXTREMELY HAZARDOUS SUBSTANCE: SULFURIC ACID. OSHA CADMIUM
STANDARD (29 CFR 1910.1027): WARNING SIGNS SHALL B E DISPLAYED IN
ALL REGULATED AREA & APPROACHES WITH THE FOLLOWING INFORMATION:
DANGER, CADMIUM, CANC ER HAZARD, CAN CAUSE LUNG & KIDNEY DISEASE,
AUTHORIZED PERSONNEL ONLY, RESPIRATORS REQUIRED IN THIS AREA.
State Regulatory Information:WARNING! THIS PRODUCT CONTAINS DETECTABLE
AMOUNTS OF CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR REPRODUCTIVE TOXICITY.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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