===================== Product Identification =====================
MSDS NAME:EPON RESIN 815, SHELL CODE: 43220
NIIN:00-763-3654
Status Code:A
Kit Part:Y
MSDS Number: CLKBZ
=== Responsible Party ===
Company:SHELL OIL COMPANY, PRODUCT SAFETY AND COMPLIANCE
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:1-17
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO320
=== Contractor Identification ===
Company:SHELL OIL COMPANY, PRODUCT SAFETY AND COMPLIANCE
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:713-241-4819
CAGE:TO320
============= Composition/Information on Ingredients =============
Name:EPON RESIN 815
Fraction by Wt: 100%
Name:BISPHENOL A-EPICHLOROHYDRIN RESIN
CAS:25068-38-6
RTECS #:CE6880000
Fraction by Wt: 86.5%
Name:N-BUTYL GLYCIDYL ETHER
CAS:2426-08-6
RTECS #:TX4200000
Fraction by Wt: 13.5%
OSHA PEL:270 MG/M3;50 PPM
ACGIH TLV:133 MG/M3;25 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:EYE: IRRITATING,MAY CAUSE CORNEAL
DAMAGE. SKIN: COMPENENT 2 (N-BUTYL GLYCIDYL ETHER) IS EXTREMELY
IRRITATING TO THE SKIN AND MAY CAUSE SKIN DAMAGE, IS A SKIN
SINSITIZER AND MAY BE TOXIC IF ABSORBED. I NHALATION: COMPONENT 2
MAY PRODUCE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION, MAY ALSO BE A
RESPIRATORY TRACT SENSITIZER. INGESTION: PRODUCT MAY BE SLIGHTLY
TOXIC, BASED ON THE PRESENCE OF COMPONENT 2, PRODUCT MAY CAUSE CNS
DEPRESSION.CHRONIC:WEEK CARCINOGENICITY
Explanation of Carcinogenicity:EIPCHLOROHYDRIN(ECH) HAS BEEN REPORTED
TO PRODUCE CANCER IN LABORATORY ANIMALS AND TO PRODUCE MUTAGENIC
CHANGES IN BACTERIA AND CULTURED HUMAN CELLS. IT HAS BEEN
CLASSIFIED BY THE IARC AS A PROBABLE H UMAN CARCINOGEN (IARC GROUP
2A), IT HAS BEEN CLASSIFIED BY NTP AS AN ANTICIPATED HUMAN
CARCINOGEN.
Effects of Overexposure:IRRITATION AS NOTED . SKIN SENSITIZATION
(ALLERGY) MAY BE EVIDENCED BY RASHES, ESPECIALLY HIVES. RESPRIATORY
TRACT SENSITIZATION (E.G. ALLERGY, ASTHMA) MAY BE EVIDENCED BY
WHEEZING WITH SHORTNESS OF B REATH AND COUGH. EARLY TO MODERATE CNS
DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS, AND
NAUSEA; IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR.
Medical Cond Aggravated by Exposure:PREECISTING EYE, SKIN, AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT. PREEXISTING SKIN OR RESPIRATORY TRACT ALLERGIES MAY
INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:
IMMEDIATELY REMOVE CONTAMINTED CLOTHING OR SHOES, WIPE EXCESS FROM
SKI N AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE
SOAP IF AVIALABLE OR FOLLOW BY WASHING WITH SOAP AND WATER. DO NOT
REUSE CLOTHING. GET MEDICAL ATTENTION. INHALATION: REMOVE VICTIN TO
FRE SH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT.INGESTION:
GIVE 2 GLASSES OF WATER, INDUCE VOMITING. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=73.3C, 164.F
Lower Limits:N/AV
Upper Limits:N/AV
Extinguishing Media:USE WATER FOG, ALCOHOL FOAM, DRY CHEMICAL OR CO2.
Fire Fighting Procedures:CAUTION. COMBUSTIBLE. DO NOT ENTER CONFIED
FIRES SPACE WITHOUT FULL BUNKER GEAR (HEALMET WITH FACE SHIELD,
BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE
PRESSURE NIOSH APPROVED SELF-CON TAINED BREATHING APPARATUS. COOL
FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP
WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO
DIRECT FLAME CONTACT SHO ULD BE COOLED WITH LARGE QUANTITIES OF
WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:CAUTION. COMBUSTIBLE.LARGE SPILLS: ELIMINATE
POTENTIAL SOURCES OF IGNITION.WEAR APPROPRIATE RESPIRATOR AND OTHER
PROTECIVE CLOTHING.SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO.
DIKE AND CONTAIN. REM OVE WITH VACCUM TRUCK OR PUMP TO
STORAGE/SALVAGE VESSELS.SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS
CLAY,SAND,OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING
CONTAINERS AND SEAL TIGHTLY FOR DISPOSAL.
====================== Handling and Storage ======================
Other Precautions:CONTAINERS, EVEN THOSE THAT ARE EMPTIED,CAN CONTAIN
EXPLOSIVE VAPORS. DO NOT CUT,DRILL, GRIND, WELD OR PERFORM SIMILAR
OPRATIONS ON OR NEAR CONTAINERS.DO NOT PRESSUREIZE DRUM CONTAINERS
TO EMPTY THEM. STATIS ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE
HAZARD. GROUND FIXED EQUIPMENT. BOND AND GROUND TRANSFER EQUIPMENT
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING AEROSOLS AND MISTS WHICH MAY BE
FORMED BY VARIOUS METHODS OF APPLICATION. IF EXPOSURE OR DOES
EXCEED OCCUPATIONAL EXPOSURE LIMITS, USE A NIOSH-APPROVED
RESPIRATOR TO PREVENT OVEREXPOSU RE. IN ACCORD WITH 29 CFR 1910.134
USE EITHER A FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR
AIR-PURIFYING RESPIRATOR FOR ORGAINC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD
BE AVAILABLE FOR EMERGENCY USE. PROTECTIVE CLOTHING TO PREVENT SKIN
AND CLOTHING CONTACT.
Supplemental Safety and Health
FIRST AID CONT: GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING GET
MEDICAL ATTENTION. INGESTION: DO NOT GIVE LIQUIIDS IF VICTIM IS
UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES
OF WATER AND INDUCE VOMITING BY GIVING 30CC (2 TABLESPOONS) OF
IPECAC. SEE OTHER INFORMATION
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:1
Vapor Density:4.5
Spec Gravity:1.13
Evaporation Rate & Reference:NA (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT YELLOW LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. CAN REACT VIGOROUSLY WITH STRONG LEWIS OR
MINERAL ACIDS AND STRONG MINERAL AND ORGANIC BASES/ESPECIALLY
PRIMARY AND SECONDARY ALIPHATIC AMINES. REACTION WITH SOME CURING
AGENTS MAY PRODUCE CONSIDERA
Stability Condition to Avoid:AVOID HEAT AND FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES AND ACIDS
MAY BE FORMED DURING COMBUSTION.
Conditions to Avoid Polymerization:WILL NOT OCCUR
=================== Toxicological Information ===================
Toxicological Information:ACUTE TOXICITY DATA:EPON RESIN 815: ACUTE
ORAL LD50=9.0 G/KG (RAT), ACUTE DERMAL LD50= NO DATA AVIALABLE,
ACUTE INHALATION LC50= NO DATA AVAILABLE. BISPHENO
A/EPICHLOROHYDRIN RESIN:ACUTE ORAL LD50=11. 4 G/KG (RAT), ACUTE
DERMAL LD50= >20 ML/KG(RABBIT), ACUTE INHALATION LC50= NO DATA
AVAILABLE. BISPHENO A/EPICHLOROHYDRIN RESIN:ACUTE ORAL LD50=15.6
G/KG (MOUSE). N-BUTYL GLYCIDYL ETHER:ACUTE ORAL LD50 =1.53 G/KG
(MOUSE), ACUTE DERMAL LD50= 788 ML/KG(RABBIT), ACUTE INHALATION
LC50>3500 PPM/4H (MOUSE). N-BUTYL GLYCIDYL ETHER:ACUTE ORAL
LD50=2.26 G/KG (RAT), ACUTE INHALATION LC50=1030 PPM/8H (RAT).
===================== Ecological Information =====================
Ecological:KEEP OUT OF SURFACE WATERS, SEWERS, AND WATER WAY ENTERING
OR LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO
THE GENERAL PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR. EPA
ENVIR ONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER
EPA-CERCLA ('SUPERFUND") RELEASE TO AIR,LAND OR WATER WHICH EXCEED
THE REPORTABLE QUANTITY MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 80 0-424-8802.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
COMBUSTABILE LIQUID, III. DOT PROPER SHIPPING NAME: RESIN SOLUTION.
OTHER REQUIREMENTS: UN 1866, GUIDE 26,. NOT REGULATED BY D.O.T. IF
IN A CONTAINER OF 11 9 GALLON CAPACITY OR LESS
===================== Regulatory Information =====================
SARA Title III Information:EHS RQ(*1).EHS TPQ (*2). SEC-313 (*3). 313
CATEGORY (*4). 311/312 CATEGORY (*5).*1= REPORTABLE QUANTITY OF
EXTREMELY HAZARDOUS SUBSTANCE, SEC 302. *2= THRESHOLD PLANNING
QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302. *3= TOXIC
CHEMICAL, SEC 313. *4= CATEGORY AS REQUIRED BY SEC 313 (40 CFR
372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM. *5=
CATEGORY ( FOR AGGREGATE REPORTING REQUIREMENT S UNDER SARA 311,
312. HEALTH: H-1= IMMEDIATE (ACUTE) HEALTH HAZARD.H-2=DELAYED
(CHRONIC) HEALTH HAZARD. PHYSICAL: P-3= FIRE HAZARD.P-4=SUDDEN
RELEASE OF PRESSURE HAZARD.P-5=REACTIVE HAZARD.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT IS LISTED
ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. PROTECTION OF
STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
AMENDMENTS OF 1990): PER 40 C FR PART 82, THIS PRODUCT DOES NOT
CONTAIN NOR WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS
II OZONE DEPLETING SUBSTANCE. IN ACCORDANCE WITH SARA TITLE III,
SECTION 313, THE ATTACHED ENVIRONM ENTAL DATA SHEET (EDS) SHOULD
ALWAYS BE COPIED AND SENT WITH THE MSDS.RCRA INFORMATION: KEEP IN
AN A PPROPRIATE DISPOSAL FACILITY IN COMPLIANCE W/LOCAL
REGULATIONS.
State Regulatory Information:THE FOLLOWING CHEMICALS ARE SPECIFICALLY
LISTD BY INDIVIDUAL STATE,FOR DETAILS ON YOUR REGULATORY
REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR
STATE.STATE LISTED COMPONRNT: BUTYL GLY CIDYL ETHER (2426-08-6)
13.5% STATE CODE,FL,IL,MA,ME,MN,PA,RI,NJ. EPICHLOROHYDRIN
(106-89-8) 2-3 PPM :MA,CA65C. PHENY GLYCIDYL ETHER (122-60-1)
5PPM,CA65C. DIGLYCIDYL ETHER (2238-07-5) <200 PPM;MA.CAL IFORNIA
PROPOSITION 65 FOOTNOTE: CA65C=THE CHEMICAL IDENTIFIED WITH THIS
CODE IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.CA65R=THE
CHEMICAL IDENTIFIED IN THIS CODE IS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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