===================== Product Identification =====================
MSDS NAME:199 7873,KODAK VERSA, 885 FIXER & REPL. PART A, (SEE SUPPL)
NIIN:01-353-4888
Status Code:A
Kit Part:Y
MSDS Number: CLKCK
=== Responsible Party ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716-722-5151
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
Minumum % Wt:40.
Maxumum % Wt:45.
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:35.
Maxumum % Wt:40.
Name:SODIUM BISULFITE (SARA I I I) (CERCLA)
CAS:7631-90-5
RTECS #:VZ2000000
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM ACETATE
CAS:127-09-3
RTECS #:AJ4300010
Minumum % Wt:1.
Maxumum % Wt:5.
Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:10 PPM
ACGIH TLV:10 PPM
ACGIH STEL:15 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM TETRABORATE, DECAHYDRATE
CAS:1303-96-4
RTECS #:VZ2275000
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:5 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD
FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS
IRRITATING TO RESPIRATORY TRACT. SOME ASTHM ATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: NO SPECIFIC
HAZARD KNOWN. MAY CAUSE IRRITATION. SKIN: MAY BE ABSORBED IN
TOXIC AMOUNTS THROUGH DAMAGED OR ABRADED SKIN. THIS MATERIAL HAS
LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL
IF SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
HAVE ADVERSE REACTIONS.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): IARC: BISULFITES (3)."THE
AGENT IS NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS."
ACGIH: SODIUM BISULFITE: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
(A4). NTP: NONE. OSHA: NONE.
Effects of Overexposure:INHALATION: RESPIRATORY TRACT IRRITATION,
DIFFICULT BREATHING. EYES: TRANSIENT IRRITATION. SKIN: SKIN
SENSITIZATION. INGESTION: WHEEZING, CHEST TIGHTNESS, STOMACH UPSET,
HIVES, FAINTNESS, WEAKNESS, D IARRHEA.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS, DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION IF SYMP TOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL IF SYMPTOMS OCCUR. WASH CONTAMINATED CLOTHING BEFORE REUSE.
INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL
PERSONNEL. CALL A PHYS ICIAN OR POISON CONTROL CENTER IMMEDIATELY.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:FLOOD WITH WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS, CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF
NITROGEN, OXIDES OF SUL FUR.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOUROUGHLY TO REMOVE RESIDUA L CONTAMINATION. COLLECT IN A
NONCOMBUSTIBLE CONTAINER FOR PROMPT DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES (SEE
INCOMPATIBILITY SECTION). DO NOT STORE OR SHIP TOGETHER WITH
COMBUSTIBLE MATERIAL. STORE IN ORIGINAL CONTAINER. AVOID BREATHING
MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. KEEP AWAY FROM COMBUSTIBLE MATERIAL. REMOVE AND WASH
CONTAMINATED CLOTHING PROMPTLY. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS, HIGHLY O XYGENATED OR HALOGENATED SOLVENTS, ORGANIC
COMPOUNDS CONTAINING REDUCIBLE FUNCTIONAL GROUPS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:PROVIDE EYE BATH, WASHING FACILITIES, SAFETY
SHOWER.USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
THIS ENTRY DESCRIBES "PART A" , MSDS SERIAL NUMBER (CLKCK) IN THE
"KODAK VERSAMAT 885 FIXER AND REPLENISHER KIT", A THREE PART KIT.
SEE THIS SAME NSN, MSDS SERIAL NUMBER (CLJZB) FOR REPLENISHER PART
O F KIT AND MSDS SERIAL NUMBER (CLKCX) FOR PART B OF KIT.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:>100.C, 212.F
Vapor Pres:24 MBAR (18 MM HG) @ 68F
Vapor Density:0.6(AIR =1
Spec Gravity:1.33 (WATER=1)
pH:5.3
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, VINEGAR ODOR.
Percent Volatiles by Volume:40-45 WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, BASES, SODIUM HYPOCHLORITE
(BLEACH), COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS. CONTACT WITH
BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:STABLE
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR. AMMONIA, SULFUR DIOXIDE,
CHLORAMINE.
=================== Toxicological Information ===================
Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS SODIUM
TETRABORATE. BASED ON REPEATED-DOSE INGESTION STUDIES IN ANIMALS,
MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS. HOWEVER, THE DOSES
ADMINISTERED WERE MANY TIMES THOSE TO WHICH HUMANS WOULD NORMALLY
BE EXPOSED. HMIS HAZARD RATINGS: HEALTH: 0; FLAMMABILITY: 1;
REACTIVITY: 0; PERSONAL PROTECTION: B. NFPA HAZARD RATINGS: HEALTH:
0; FLAMMABILITY: 1; REACTIVITY (S TABILITY): 0.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE CONPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH, LC50: >100 MG/L;
DAPHNID, EC50: >100 MG/L; ALGAL, IC50: >100 MG/L. ORGANICS READILY
DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE): 323 G/L; BOD5 (APPROXIMATE): 261 G/L.
POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS EC50: >100 MG/L.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED
=================== MSDS Transport Information ===================
Transport Information:TRANSPORTATION PER KODAK FOR THREE PART KIT:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., (ALUMIMUM SULFATE), 8,
UN 3264, I I I. TRANSPORTATION FOR THIS ITEM ALONE : NOT REGULATED
PER DSCR VBA.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE I I I OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: NONE.
State Regulatory Information:MATERIALS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER: NONE. MATERIALS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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