===================== Product Identification =====================
MSDS NAME:146 6788,WKG SOL,KODAK MEDICAL X-RAY LIQUID FIXER,MX 1764-3
Status Code:A
MSDS Number: CLKCB
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:80.
Maxumum % Wt:85.
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
Minumum % Wt:5.
Maxumum % Wt:10.
Name:SODIUM THIOSULFATE
CAS:7772-98-7
RTECS #:XN6476000
Minumum % Wt:1.
Maxumum % Wt:5.
Name:AMMONIUM SULFITE
CAS:10196-04-0
< Wt:1.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ALUMINUM SULFATE
CAS:10043-01-3
RTECS #:BD1700000
< Wt:1.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM BISULFITE
CAS:7631-90-5
RTECS #:VZ2000000
< Wt:1.
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED LOW HAZARD FOR
USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN
CONTACT WITH STRONG ACIDS OR HEATED, SULFITES LIBERATE SULFUR
DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY
TRACT. ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE
DIFFICULT BREATHING. EYES: CAUSE TRANSIENT IRRITATION. HOWEVER,
IMMEDIATE FLUSHING OF EYES WITH WATER WILL MINI MIZE IRRITATIVE
EFFECT. SKIN: MATERIAL HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
Effects of Overexposure:INHALATION: EXPECTED LOW HAZARD FOR USUAL
INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT
WITH STRONG ACIDS OR HEATED, SULFITES LIBERATE SULFUR DIOXIDE GAS.
SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY TRACT. ASTHMATICS
OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSE TRANSIENT IRRITATION. HOWEVER, IMMEDIATE FLUSHING OF
EYES WITH WATER WILL MINI MIZE IRRITATIVE EFFECT. SKIN: MATERIAL
HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. GET M EDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH
WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO2), DRY
CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP
FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED OR
HALOGENATED SOLVENTS, ORGANIC COMPOUNDS CONTAINING REDUCIBLE
FUNCTIONAL GROUPS, OR AQUEOUS AMMONIA.
Other Precautions:AVOID BREATHING VAPOR AT CONCENTRATIONS GREATER THAN
THE EXPOSURE LIMITS. AVOID CONTACT WITH EYES AND PROLONGED OR
REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HAND LING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT, IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT.IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:>100.C, 212.F
Vapor Pres:68F: 24MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:NOT AVAILABLE
pH:NOT AVAILABLE
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS LIQUID.
Percent Volatiles by Volume:85-90 WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, STRONG ACIDS, BASES,
SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, SULFUR DIOXIDE.
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF
SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:WARNING! MAY BE HARMFUL IF SWALLOWED.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY- FISH LC50 MG/L: >100,
DAPHNID EC50 MG/L: >100, ALGAL IC50 MG/L: >100. ORGANICS READILY
DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE G/L): 55. BOD5 (APPROXIMATE G/L): 45.
POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS EC50 (MG/L):
>100.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 AM AND 5 PM (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: AMMONIUM THIOSULFATE, AMMONIUM SUL FITE, AS A SOURCE OF
AQUEOUS AMMONIA.
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|