===================== Product Identification =====================
MSDS NAME:ACETONE
NIIN:00-264-8955
Status Code:A
MSDS Number: CLRPG
=== Responsible Party ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:ACC#00140
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ACETONE
CAS:67-64-1
RTECS #:AL3150000
= Wt:99.
OSHA PEL:2400 MG/M3;1000 PPM
ACGIH TLV:500 PPM
ACGIH STEL:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAUSES RESPIRATORY TRACT
IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. MAY CAUSE
LIVER AND KIDNEY DAMAGE. CAUSES EYE AND SKIN IRRITATION. CHRONIC:
DERMATITIS, CHRONIC INHALATION EFFE CTS ARE SIMILAR TO THOSE OF
ACUTE. TARGET ORGANS: KIDNEYS, CENTAL NERVOUS SYSTEM, LIVER,
RESPIRATORY SYSTEM, EYES, SKIN.
Explanation of Carcinogenicity:CAS# 67-64-1: ACGIH: A4 - NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN
Effects of Overexposure:EYE: PRODUCES IRRITAION, CHARACTERIZED BY A
BURNING SENSATION, REDNESS, TEARING, INFLAMMATION, AND POSSIBLE
CORNEAL INJURY. DKIN: EXPOSURE MAY CAUSE IRRITATION CHARACTERIZED
BY REDNESS, DRYNESS, AND I NFLAMMATION. INGESTION: MAY CAUSE
IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION, KIDNEY DAMAGE, AND LIVER DAMAGE. SYMPTOMS MAY INCLUDE:
HEADACHE, EXCITEMENT, FATIGUE, NAUSEA, VOMITIN, STUPOR, AND COMA.
MAY CAUSE LIVER AND KIDNEY DAMAGE. MAY CAUSE CENTRAL NERVOUS SYSTEM
DEPRESSION, CHARACTERIZED BY EXCITEMENT, FOLLOWED BY HEADACHE,
DIZZINESS, DROWSINESS, AND NAUSEA. SEE OTHER INFORMATION).
======================= First Aid Measures =======================
Eyes: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER EYELIDS. GET
MEDICAL AID IMMEDIATLEY. SKIN: FLUSH SKIN WITH PLENTY OF SOAP AND
WATER FOR AT LEAS T 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. WASH
CLOTHING BEFORE REUSE. INGESTION: DONOT INDUCE VOMITING. IF VICTIM
IS CONSCIOUS AN D ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID
IMMEDIATELY. SEE SUPPLEMENTAL DATA.
===================== Fire Fighting Measures =====================
Flash Point:=-20.C, -4.F
Autoignition Temp:=465.C, 869.F
Lower Limits:2.5
Upper Limits:12.8
Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY OR ALCOHOL-RESISTANT FOAM. LARGE FIRES: WATER SPRAY, FOG, OR
ALCOHOL-RESISTANT FOAM. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS IN
PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT), AND FULL
PROTECTIVE GEAR. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
DO NOT USE STRAIGHT STEAMS OF WATER. COOL CONTAINERS WITH FLOODING
QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM AND EXPLOSIVE MIXTURE
WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK.
DURING A FIRE, IRRITATING AND HIGHLY TOXIC GASES MAY BE GENERATED
BY THERMAL DECOMPOSITION OR COMBUSTION.EXTREMELY FLAMMABLE LIQUID
AND VAPOR. VAPORS MAY BE HEAVIER THAN AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DAND OR EARTH),
THEN PLACE IN SUITABLE CONTAINER. AVOID RUNOFF INTO STORM SEWERS
AND DITCHES WHICH LEAD TO WATERWAYS. WEAR APPROPRIATE PROTECTIVE
CLOTHING TO MINIMIZE CONTACT WITH SKIN. REMOVE ALL SOURCES OF
IGNITION. A VAPOR SUPPRESSING FOAM MAY BE USED RO REDUCE VAPORS.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND
FLAME. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY
CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY
FROM INCOMPATIBLE SUBSTANCES. FLAMMABLE S-AREA. WASH THOROUGHLY
AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Other Precautions:USE ONLY IN A WELL-VENTILATED AREA. GROUND AND BOND
CONTAINERS WHEN TRANSFERRING MATERIAL. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND, OR EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS OR OPEN FLAMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUAE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:APPROPRIATE PROTECTIVE GLOVES.
Eye Protection:CHEMICAL GOGGLES.
Other Protective Equipment:FACILITIES STORING OR UTILIZING THIS
MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A SAFETY
SHOWER.
Supplemental Safety and Health
FIRST AID CONT: INHALATION: GET MEDICAL ATTENTION IMMEDIATELY. REMOVE
FROM EXPOSURE TO FRESH AIR IMMEFDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GE
T MEDICAL AID. DO NOT USE MOUTH-TO-MOUTH RESPIRATION. IF BRATHING
HAS CEASED APPLY ARTIFICIAL RESPIRATION USING OXYGEN
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=56.2C, 133.2F
Melt/Freeze Pt:=59.8C, 139.6F
Vapor Pres:180 MM HG
Vapor Density:2.0
Spec Gravity:0.79
pH:7
Evaporation Rate & Reference:7.7 (N-BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID, ACETONE-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS (MINERAL, NON-OXIDIZING, E.G. HYDROCHLORIC ACID, HYDROFLUORIC
ACID, MURIATIC ACID, PHOSPHORIC ACID), ACIDS (MINERAL, OXIDIZING,
ELGL CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID),
ACIDS (ORGANIC, E.G. A
Stability Condition to Avoid:HIGH TEMPERATURES, IGNITION SOURCES,
TEMPERATURES ABOVE 220 C.
Hazardous Decomposition Products:CARBON MONOCIDE, IRRITATING AND TOXIC
FUMES AND GASES, CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:CAS# 67-64-1. LD50/LC50: DERMAL, GUINEA PIG:
LD50 = >9400 MICROLITER/KG; DRAIZE TEST, RABBIT, EYE: 20 MG SEVERE;
DRAIZE TEST, RABBIT, EYE: 20 MG/24H MODERATE; DRAIZE TEST, RABBIT,
SKIN: 500 MG/24H MIL D; INHALATION, MOUSE: LC50 = 44 GM/M3/4H;
INHALATION, RAT: LC50 = 50100 MG/M3/8H; ORAL, MOUSE: LD50 = 3
GM/KG; ORAL, RABBIT: LD50 = 5340 MG/KG;ORAL, RAT: LD50 = 5800
MG/KG; REPRODUCTIVE EFFECTS: TDLO( ORAL, RAT) = 273
GM/KG;REPRODUCTIVE - PATERNAL EFFECTS - SPERMATOGENESIS (INCL.
GENETIC MATERIAL, SPERM MORPHOLOGY, MOTILITY, AND COUNT).
NEUROTOXICITY: NO INFO AVILABLE. MUTAGENICITY:SEX CHROMOSOME L OSS
AND NONDISJUNCTION= 47600 PPM;
===================== Ecological Information =====================
Ecological:ECOTOXICITY: RAINBOW TROUT LC50=5540 MG/L/96H SUNFISH (TAP
WATER), DEATH AT 14250 PPM/24H MOSQUITO FISH (TURBID WATER)
TLM=13000 PPM/48HCAS# 67-64-1:LC50 (96HR.) RAINBOW TROUT = 5540
MG/L; STATIC COND ITIONS, 11-13 DEGREES CLC50 (96HR) FATHEAD MINNOW
= 7280-8120 MG/L; FLOW-THROUGH CONDITIONSLC50 (96HR) BLUEGILL =8300
MG/L. IF RELEASED ON SOIL, ACETONE WILL BOTH VOLATILIZE AND LEACH
INTO GROUND,& RE ADILY BIODEGRADES. IF RELEASED INTO WATER, ACETONE
WILL PROBABLY BIODEGRADE. ABSORPTION TO SEDIMENT SHOULD NOT BE
SIGNIFICANT. IN THE ATMOSPHERE , ACETONE WILL BE LOST BY PHOTOLYSIS
& BY REACTION WITH HYDOXYL RADICALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:CHEMICAL WASTE GENERATORS MUST DETERMINE WHETHER
A DISCARDED CHEMICAL IS CLASSIFIED AS A HAZARDOUS WASTE. US EPA
GUIDELINES FOR THE CLASSIFICATION DETERMINATION ARE LISTED IN 40
CFR PARTS 261.3. ADDIT IONALLLY, WASTE GENERATORS MUST CONSULT
STATE AND LOCAL HAZARDOUS WASTE REGULATION TO ENSURE COMPLET E AND
ACCURATE CLASSIFICATION.
=================== MSDS Transport Information ===================
Transport Information:US DOT: SHIPPING NAME: ACETONE, HAZARD CLASS: 3,
UN NUMBER:UN 1090, PACKING GROUP:II,
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ) CAS# 67-64-1: FINAL RQ =
5000 POUNDS (2270 KG). SEC 302 (TPQ): NONE. SARA CODES CAS #
67-64-1: ACUTE, CHRONIC, FLAMMABLE, SUDDEN RELEASE OF PRESSURE.
311: NO CHEMICALS ARE REPORTABLE UNSEC 313. CLEAN AIR ACT:THIS
MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS. THIS
MATERIAL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS. THIS
MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLE TORS. CLEAN WATER
ACT: NOT LISTED AS HAZARDOUS SUBSTANCE, PRIORITY POLUTANTS & TOXIC
POLLUTANT UNDER CWA.
Federal Regulatory Information:TSCA: CAS# 67-64-1 IS LISTED ON THE TSCA
INVENTORY. OSHA: NONE OF THE CHEMICALS IN THIS PRODUCT ARE
CONSIDERED HIGHLY HAZARDOUS BY OSHA.
State Regulatory Information:CAS# 67-64-1 CAN BE FOUND ON THE FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF THE CHEMICA LS IN THIS PRODUCT ARE LISTED.
CANADA: CAS 67-64-1 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS
PRODUCT HAS A WHMIS CLASSIFICATION OF B2, D2B., AND IS ALSO LISTED
ON CADADA'S INGREDIENT DISCLOSURE LIST.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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