MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
PRODUCT NAME: FINAL
OTHER NAMES: PACER FINAL
RECOMMENDED USE: Remedial acidic cleaner for CSSD applications.
SUPPLIER NAME: CAMPBELL CLEANTEC (ABN 92 009 657 489)
ADDRESS: 32 PERIVALE STREET, DARRA, QLD, 4076
TELEPHONE: GENERAL ENQUIRIES: + 61 7 3710 3200
CUSTOMER SERVICE: 1800 077 240
FAX: GENERAL ENQUIRIES: + 61 7 3710 3210
CUSTOMER SERVICE: + 61 7 3710 3207
EMERGENCY TELEPHONE NUMBER: AUSTRALIA: 1800 628 724 (ALL HOURS)
INTERNATIONAL: + 61 7 3710 3184 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as hazardous according to the criteria of NOHSC.
HAZARD
Classified as a dangerous good UN 1760 according to the criteria of ADG Code (see section 14).
CLASSIFICATION:
Classified as schedule 5 according to the criteria of SUSDP (see section 15).
HAZARD CATEGORY: C 鈥? Corrosive
RISK PHRASES: R34 - Causes burns.
R41 - Risk of serious damage to eyes.
SAFETY PHRASES: S1/2 鈥? Keep locked up and out of reach of children.
S24/25 鈥? Avoid contact with eyes and skin.
S26 鈥? In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 鈥? Wear suitable protective clothing, gloves and eye/face protection.
S45 鈥? In case of accident or if you feel unwell, seek medical advice immediately (show the label
whenever possible).
The information contained in this MSDS is specific to the product when handled and used neat. This product when diluted may not require the
same control measures as the neat product. Check with your technical representative if in doubt.
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT CAS No. PROPORTION (% w/w)
The ingredients below are considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC, ADG
Code and SUSDP (respectively) at the levels used in the product.
Phosphoric Acid 7664-38-2 30 - 60%
The ingredients below are not considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC,
ADG Code and SUSDP (respectively) at the levels used in the product.
Organic acid 10 鈥? 30%
Nonionic surfactant < 10%
Dye < 10%
Water 30 鈥? 60%
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MATERIAL SAFETY DATA SHEET
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone Australia 131126, New Zealand
INGESTION:
0800 764 766) or a doctor. If swallowed, do NOT induce vomiting.
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing
EYE CONTACT:
until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
SKIN CONTACT:
water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor.
Remove from source of exposure to fresh air. Seek medical assistance if the effects persist.
INHALATION:
** SHOW THIS SAFETY DATA SHEET TO A DOCTOR **
Potable water should be available to rinse eyes or skin. Provide eye baths and safety showers.
FIRST AID FACILITIES:
Treat symptomatically, may aggravate skin and lung disorders (for example, asthma-like conditions)
NOTES TO PHYSICIAN:
5. FIRE FIGHTING METHODS
Water spray, foam, carbon dioxide or dry chemical powder.
SUITABLE EXTINGUISHING MEDIA:
The product is non-combustible but will decompose under fire conditions
HAZARDS FROM COMBUSTION:
releasing toxic and/or irritating smoke, phosphoric acid fumes and oxides of
phosphorus. The packaging material may burn to emit noxious fumes. Contact
with metals may liberate hydrogen gas which is extremely flammable.
Fire fighters should wear self-contained breathing apparatus and acid-resistant
PRECAUTIONS FOR FIRE FIGHTERS AND
chemical splash unit to minimise risk of exposure.
SPECIAL PROTECTIVE EQUIPMENT:
2X
HAZCHEM CODE:
6. ACCIDENTAL RELEASE MEASURES
Spillages are slippery. Ensure adequate ventilation, work up wind or increase ventilation. Keep
EMERGENCY
spectators away 鈥? rope off the area. Avoid accidents, clean up immediately. Wear protective equipment
PROCEDURES:
to prevent skin and eye contamination and inhalation of mists.
Contain the spill and prevent run off into confined areas, drains and waterways.
METHODS AND
Absorb with dry earth, sand or other non-combustible material. Neutralise with lime or soda ash. Use
MATERIALS FOR
clean non-sparking tools to collect and seal in properly labelled drums for disposal in an area approved
CONTAINMENT AND
by local authority by-laws. Wash area down with excess water to remove residual material.
CLEAN UP:
Incineration of disposed material is not recommended, as it is unlikely to adequately burn.
7. HANDLING AND STORAGE
Keep containers closed at all times - check regularly for leaks or spills. Transport and store upright.
PRECAUTIONS FOR
Addition to water releases heat which can result in violent boiling and splattering. Always add slowly
SAFE HANDLING:
and in small amounts. Never add water to acids always add acids to water.
Avoid eye contact and repeated or prolonged skin contact and breathing in mists. Do not eat, drink or
smoke in contaminated areas. Always remove contaminated clothing and wash hands before eating,
drinking, smoking or using the toilet. Wash contaminated clothing and other protective equipment
before storage or re-use.
Store in the original container, in a cool dry well-ventilated area out of sunlight and away from heat,
CONDITIONS FOR
incompatible materials and foodstuffs.
SAFE STORAGE:
Keep containers closed when not in use to ensure contamination does not occur- check regularly for
leaks. Do not combine part drums of the same product, as this may be a source of contamination. Do
not mix with other chemicals.
This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with
the relevant regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No value assigned for this specific material by NOHSC, however as published by NOHSC:
NATIONAL EXPOSURE
3 3
T.W.A. for Phosphoric Acid = 1 mg/m S.T.E.L. for Phosphoric Acid = 3 mg/m
STANDARDS:
No biological limit allocated.
BIOLOGICAL LIMIT VALUES:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards.
ENGINEERING CONTROLS:
If inhalation risk exists then use with local exhaust ventilation or while wearing air supplied
respirator. Keep containers closed when not in use.
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MATERIAL SAFETY DATA SHEET
Protective equipment must be worn at all times. Risk assessments should always be conducted to identify the
PERSONAL
hazards and in turn determine the appropriate personal protective equipment for the hazard.
PROTECTIVE
Protective gloves: elbow-length laminate film, unsupported nitrile, neoprene, neoprene/natural rubber blend or
EQUIPMENT:
PVC impervious gloves. Always check with the glove manufacturer or your personal protective equipment
supplier regarding the correct type of glove to use. Consult AS/NZS 2161 for further information.
Eye protection: safety glasses/goggles with side shield protection and/or full-face shield. Consult AS/NZS
1336 and AS/NZS 1337 for further information.
Clothing and footwear: waterproof apron, coveralls, trousers, long sleeved shirt, closed in shoes and/or safety
footwear. Consult AS/NZS 2210 and AS/NZS 2919 for further information.
Respiratory Protection: Avoid breathing mist, sprays or vapours. Where ventilation is not adequate,
respiratory protection may be required. Any air-purifying respirator with an acid gas filters or any chemical
cartridge respirator with an acid gas cartridge(s) providing protection against the compound of concerns
meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Clear, orange, mobile liquid.
APPEARANCE:
Slight surfactant odour.
ODOUR:
<2
PH (NEAT):
S.G. 1.25
SPECIFIC GRAVITY OR DENSITY:
No information available.
VAPOUR PRESSURE:
Approx. 56% w/w.
PERCENT VOLATILES:
No information available.
BOILING POINT / RANGE:
No information available.
FREEZING / MELTING POINT:
The product is water based and is fully soluble in water.
SOLUBILITY:
No known fire hazard.
FLASH POINT:
No information available.
FLAMMABILITY LIMITS:
No information available.
IGNITION TEMPERATURE:
2 years from manufacturing date (when stored as directed).
SHELF LIFE:
None.
OTHER:
10. STABILITY AND REACTIVITY
Stable under normal conditions of use. The shelf life is 2 years.
CHEMICAL STABILITY:
Do not combine part drums of the same product, as this may be a source of
CONDITIONS TO AVOID:
contamination.
Alkalis, organic materials, aluminium and alloys, cast iron, brasses tin or zinc
INCOMPATIBLE MATERIALS:
coated metals, strong oxidising and reducing agents, sulphides, phosphides,
cyanides, acetylides, fluorides and carbides.
Oxides of phosphorus. The packaging material may burn to emit noxious fumes.
HAZARDOUS DECOMPOSITION PRODUCTS:
Reacts violently with alkalis with evolution of heat. Reacts exothermically on
HAZARDOUS REACTIONS:
dilution with water. Reacts with strong oxidising and reducing agents, most
metals, sulphides, phosphides, cyanides, acetylides, fluorides and carbides,
releasing flammable or toxic gases. On heating may produce phosphorus oxides
(POx). Corrosive to many metals with the liberation of extremely flammable
hydrogen gas.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE EFFECTS
Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and chemical burns to the
INGESTION:
mouths, lips and gastrointestinal tract.
Corrosive to eyes and may injure the cornea. Contamination of eyes can result in permanent injury.
EYE CONTACT:
Symptoms include stinging, tearing, redness and swelling of eyes.
Corrosive to skin - may cause skin burns. May not produce an immediate burning sensation upon
SKIN CONTACT:
contact, delaying the awareness that contact has occurred. Symptoms may include redness,
burning, and swelling of skin, burns, and other skin damage.
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MATERIAL SAFETY DATA SHEET
Breathing in mists or aerosols may produce severe respiratory irritation and burns to the nose,
INHALATION:
throat, and respiratory tract.
No information available.
LONG TERM EFFECTS:
No toxicity data for this specific product, however toxicity data for the hazardous ingredient is listed
ACUTE TOXICITY /
below.
CHRONIC TOXICITY:
TOXICITY DATA FOR PHOSPHORIC ACID: Oral LD50 (rat) 1530 mg/kg
3
Dermal LD50 (rabbit) 2740 mg/kg Inhalation LC50 (rat) > 850 mg/m /1h
Skin Irritation - Standard Draize Test (Rabbit) 595 mg/24H (Severe)
Eye Irritation - Standard Draize Test (Rabbit) 119 mg (Severe)
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways. The product is highly acidic. If large spills occurred a
ECOTOXICITY:
water pH drop could be responsible for an environmental effect on aquatic organisms.
Low concentrations of phosphate may act as a plant nutrient or precipitate heavy
metals.
This product is considered to be readily biodegradable to AS 4351.
PERSISTENCE AND DEGRADABILITY:
No information available.
MOBILITY:
None.
OTHER:
13. DISPOSAL CONSIDERATIONS
Empty containers should be forwarded to an approved agent for recycling. Avoid
DISPOSAL METHODS:
unauthorised discharge to sewer.
The product is suitable for disposal by landfill through an approved agent. Incineration of
SPECIAL PRECAUTIONS FOR
the product is not recommended, as it is unlikely to adequately burn.
LANDFILL OR INCINERATION:
14. TRANSPORT INFORMATION
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods
ROAD AND RAIL TRANSPORT:
Code (ADG Code) for transport by Road and Rail.
1760
UN NUMBER:
CORROSIVE LIQUID, N.O.S. (CONTAINS PHOSPHORIC ACID)
UN PROPER SHIPPING NAME:
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
2X
HAZCHEM CODE:
Guide 37
INITIAL EMERGENCY RESPONSE GUIDE:
Not to be loaded with explosives (class 1), dangerous when wet substances
SEGREGATION DANGEROUS GOODS:
(class 4.3), oxidising agents (class 5.1), organic peroxides (class 5.2), radioactive
substances (class 7), corrosives (strong alkalis of class 8), foodstuffs and
foodstuff empties, however exemptions may apply.
Classified as Dangerous Goods by the criteria of the International Maritime
MARINE TRANSPORT:
Dangerous Goods Code (IMDG Code) for transport by sea.
1760
UN NUMBER:
CORROSIVE LIQUID, N.O.S. (CONTAINS PHOSPHORIC ACID)
UN PROPER SHIPPING NAME:
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
Category A. Clear of living quarters.
STOWAGE AND SEGREGATION:
Classified as Dangerous Goods by the criteria of the International Air Transport
AIR TRANSPORT:
Association (IATA) for transport by air.
1760
UN NUMBER:
CORROSIVE LIQUID, N.O.S. (CONTAINS PHOSPHORIC ACID)
UN PROPER SHIPPING NAME:
8
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
8L
ERG CODE:
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MATERIAL SAFETY DATA SHEET
15. REGULATORY INFORMATION
POISONS SCHEDULE (AUST.): 5
Not relevant.
APVMA STATUS:
Not relevant.
TGA STATUS:
All the constituents of this product are listed.
AICS STATUS:
Not relevant.
AQIS STATUS:
None.
OTHER:
16. OTHER INFORMATION
This product is a medium to strong acid. Use good industrial hygiene.
GENERAL INFORMATION:
002
MSDS ISSUE NUMBER:
22 February 2006
MSDS ISSUE DATE:
In any event, the review and, if necessary, the re-issue of a MSDS shall be no longer than 5 years after the last date of issue.
Electronic versions of the MSDS鈥檚 in a PDF format are also available on our Website at www.cleantec.com.au/product.asp
REASON(S) FOR ISSUE: Update to conform to requirements of NOHSC:2011(2003); 16-header format.
THIS ISSUE NUMBER REPLACES ALL PREVIOUS ISSUES.
LITERARY REFERENCE:
SOURCES FOR DATA:
LEGEND:
AICS Australian Inventory of Chemical Substances
APVMA Australian Pesticides and Veterinary Medicines Authority
AQIS Australian Quarantine and Inspection Service
AS Australian Standard (as issued by Standards Australia)
ERP Code Emergency Response Drill Code as found in the ICAO (International Civil Aviation Organisation) Doc 9481
MSDS Material Safety Data Sheet
NOHSC National Occupational Health and Safety Commission
STEL Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a
working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the
STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There
should be at least 60 minutes between successive exposures at the STEL.
TGA Therapeutic Goods Administration
TLV Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental
Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical
agents to which it is believed that nearly all workers may be repeatedly exposed day after day without
adverse effect.
TWA Time Weighted Average - The average airborne concentration of a particular substance when calculated
over a normal eight-hour working day, for a five-day working week.
This MSDS has been prepared from current technical data and summarises at the date of issue our best knowledge of the health and safety
information of the product, and in particular how to safely handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also
available upon request.
This MSDS may only be reproduced in full. Summaries or excerpts from this MSDS may not contain all the relevant information and thus are
not permitted.
End of MSDS
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