MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
PRODUCT NAME: SUPER SOLV
OTHER NAMES: PACER SUPER SOLV
Solvent cleaner.
RECOMMENDED USE:
CAMPBELL CLEANTEC (ABN 92 009 657 489)
SUPPLIER NAME:
32 PERIVALE STREET, DARRA, QLD, 4076
ADDRESS:
GENERAL ENQUIRIES: + 61 7 3710 3200
TELEPHONE:
CUSTOMER SERVICE: 1800 077 240
GENERAL ENQUIRIES: + 61 7 3710 3210
FAX:
CUSTOMER SERVICE: + 61 7 3710 3207
AUSTRALIA:
EMERGENCY TELEPHONE NUMBER:
1800 628 724 (ALL HOURS)
INTERNATIONAL: + 61 7 3710 3184 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as hazardous according to the criteria of NOHSC.
HAZARD
Classified as a dangerous good UN 1993 according to the criteria of ADG Code (see section 14).
CLASSIFICATION:
Classified as schedule 6 according to the criteria of SUSDP (see section 15).
F 鈥? Flammable; Xn 鈥? Harmful; Xi 鈥? Irritant; N 鈥? Dangerous for the environment
HAZARD CATEGORY:
R10 鈥? Flammable
RISK PHRASES:
R20/21/22 鈥? Harmful by inhalation, in contact with skin and if swallowed
R36/37/38 鈥? Irritating to eyes, respiratory system and skin.
R43 鈥? May cause sensitisation by skin contact.
R51 鈥? Toxic to aquatic organisms.
R65 鈥? Harmful: may cause lung damage if swallowed.
S2 鈥? Keep out of reach of children.
SAFETY PHRASES:
S9 鈥? Keep container in well-ventilated place.
S16 鈥? Keep away from sources of ignition 鈥? No smoking.
S23 鈥? Do not breathe vapours.
S24/25 鈥? Avoid contact with eyes and skin.
S26 鈥? In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29 鈥? Do not empty into drains.
S33 鈥? Take precautionary measures against static discharges.
S36/37/39 鈥? Wear suitable protective clothing, gloves and eye/face protection.
S61 鈥? Avoid release to the environment. Refer to special instructions / Material Safety Data Sheet.
S62 鈥? If swallowed, do not induce vomiting: seek medical advice immediately and show container or
label.
The information contained in this MSDS is specific to the product when handled and used neat. This product when diluted may not require the
same control measures as the neat product. Check with your technical representative if in doubt.
Product Name: Page:
SUPER SOLV 1 of 6
MATERIAL SAFETY DATA SHEET
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT CAS No. PROPORTION (% w/w)
The ingredients below are considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC, ADG
Code and SUSDP (respectively) at the levels used in the product.
Ethylene glycol monobutyl ether 111-76-2 30 鈥? 60%
Distillates (petroleum) hydrotreated
64742-47-8 30 鈥? 60%
light
d-Limonene 5989-27-5 10 鈥? <30%
The ingredients below are not considered either hazardous, dangerous goods or poison scheduled according to the criteria of NOHSC,
ADG Code and SUSDP (respectively) at the levels used in the product.
Non-ionic surfactant <10%
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone Australia 131126, New Zealand
INGESTION:
0800 764 766) or a doctor. If swallowed, do NOT induce vomiting.
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing
EYE CONTACT:
until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
SKIN CONTACT:
water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor.
Remove from source of exposure to fresh air. Seek medical assistance if the effects persist.
INHALATION:
** SHOW THIS SAFETY DATA SHEET TO A DOCTOR **
Potable water should be available to rinse eyes or skin. Provide eye baths and safety showers.
FIRST AID FACILITIES:
Treat symptomatically.
NOTES TO PHYSICIAN:
5. FIRE FIGHTING METHODS
Foam, carbon dioxide or dry chemical powder.
SUITABLE EXTINGUISHING MEDIA:
Flammable liquid. Explosive air-vapour mixture may form. Explosive when mixed
HAZARDS FROM COMBUSTION:
with oxidising agents. Vapour is heavier than air, can spread along the ground and
distant ignition is possible. Avoid all ignition sources. Keep away from heat, naked
flames or sparks and oxidising agents. Flameproof equipment is necessary in all
areas where this chemical is being used. Nearby equipment must be earthed.
Heating can cause expansion or decomposition of the material, which can lead to
the containers exploding. If safe to do so, remove containers from the path of fire.
On burning will emit toxic fumes such as carbon monoxide and carbon dioxide.
Fire fighters should wear self-contained breathing apparatus to minimise risk of
PRECAUTIONS FOR FIRE FIGHTERS AND
exposure to vapour or products of combustion.
SPECIAL PROTECTIVE EQUIPMENT:
3[Y]
HAZCHEM CODE:
6. ACCIDENTAL RELEASE MEASURES
Shut off leak if safe to do so. Eliminate all sources of ignition (no smoking, flares, sparks or flame). All
EMERGENCY
equipment used must be earthed. Spillages are slippery. Ensure adequate ventilation, work up wind or
PROCEDURES:
increase ventilation. Keep spectators away 鈥? rope off the area or evacuate the area. Avoid accidents,
clean up immediately. Wear protective equipment to prevent skin and eye contamination and inhalation
of mists or vapour.
Do not smoke during the clean up procedure. Contain the spill and prevent run off into confined areas,
METHODS AND
drains and waterways.
MATERIALS FOR
Absorb with dry earth, sand or other non-combustible material. Use clean, non-sparking tools to collect
CONTAINMENT AND
and seal in properly labelled drums for disposal in an area approved by local authority by-laws. Keep
CLEAN UP:
away from heat, naked flame or sparks.
Wash area down with excess water to remove residual material. Do not flush to drain.
DO NOT incinerate: the by-products may be hazardous.
Product Name: Page:
SUPER SOLV 2 of 6
MATERIAL SAFETY DATA SHEET
7. HANDLING AND STORAGE
Keep containers closed at all times - check regularly for leaks or spills. Earth and bond all transfer
PRECAUTIONS FOR
equipment including tanks and drums. Transport and store upright.
SAFE HANDLING:
Avoid eye contact and repeated or prolonged skin contact and breathing in mists. Do not eat, drink or
smoke in contaminated areas. Always remove contaminated clothing and wash hands before eating,
drinking, smoking or using the toilet. Wash contaminated clothing and other protective equipment before
storage or re-use.
Store in the original container, in a cool, dry, well-ventilated area out of sunlight and away from heat and
CONDITIONS FOR
foodstuffs. Explosive air-vapour mixture may form. Keep material away from sparks, flames and other
SAFE STORAGE:
ignition sources. Keep away from oxidising agents, may form explosive mixtures.
Keep containers closed when not in use to ensure contamination does not occur- check regularly for
leaks. Do not combine part drums of the same product, as this may be a source of contamination. Do
not mix with other chemicals.
This material is a Scheduled Poison S6 and must be stored, maintained and used in accordance with
the relevant regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No value assigned for this specific material by NOHSC, however the exposure standard for
NATIONAL EXPOSURE
ETHYLENE GLYCOL MONOBUTYL ETHER as published by NOHSC:
STANDARDS:
ES-TWA for Ethylene glycol monobutyl ether = 20 ppm (96.9 mg/m3)
ES-STEL for Ethylene glycol monobutyl ether = 50 ppm (242 mg/m3)
Overseas occupational exposure standards for D-LIMONENE are listed below::
Norway (OEL) T.W.A. for d-Limonene = 140 mg/m3 (25 ppm)
Sweden T.W.A. for d-Limonene = 150 mg/m3 (25 ppm)
Sweden S.T.E.L. for d-Limonene = 300 mg/m3 (50 ppm)
AIHA T.W.A. for d-Limonene = 165.6 mg/m3 (30 ppm)
No biological limit allocated.
BIOLOGICAL LIMIT VALUES:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards.
ENGINEERING CONTROLS:
If inhalation risk exists then use with local exhaust ventilation or while wearing a suitable
respirator. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter
confined spaces where vapour may have collected. Keep containers closed when not in use.
Protective equipment must be worn at all times. Risk assessments should always be conducted
PERSONAL PROTECTIVE
to identify the hazards and in turn determine the appropriate personal protective equipment for
EQUIPMENT:
the hazard.
Protective gloves: elbow-length laminate film or unsupported nitrile impervious gloves. Always
check with the glove manufacturer or your personal protective equipment supplier regarding the
correct type of glove to use. Consult AS/NZS 2161 for further information.
Eye protection: safety glasses/goggles with side shield protection and/or full-face shield.
Consult AS/NZS 1336 and AS/NZS 1337 for further information.
Clothing and footwear: waterproof apron, coveralls, trousers, long sleeved shirt, closed in
shoes and/or safety footwear. Consult AS/NZS 2210 and AS/NZS 2919 for further information.
Respiratory Protection: Avoid breathing mist, sprays or vapours. Where ventilation is not
adequate, respiratory protection may be required. Any air-purifying respirator with an organic
gases and vapour filter or any chemical cartridge respirator with an organic vapour cartridge(s)
providing protection against the compounds of concern meeting the requirements of AS/NZS
1715 and AS/NZS 1716.
Product Name: Page:
SUPER SOLV 3 of 6
MATERIAL SAFETY DATA SHEET
9. PHYSICAL AND CHEMICAL PROPERTIES:
Clear, colourless liquid.
APPEARANCE:
Icinol odour.
ODOUR:
Not relevant.
PH (NEAT):
0.83
SPECIFIC GRAVITY OR DENSITY:
No information available.
VAPOUR PRESSURE:
Approx. 99% w/w
PERCENT VOLATILES:
No information available.
BOILING POINT / RANGE:
No information available.
FREEZING / MELTING POINT:
No information available.
SOLUBILITY:
56 掳C
FLASH POINT:
No information available.
FLAMMABILITY LIMITS:
No information available.
IGNITION TEMPERATURE:
2 years from manufacturing date (when stored as directed).
SHELF LIFE:
None.
OTHER:
10. STABILITY AND REACTIVITY
Stable under normal conditions of use. The shelf life is 2 years.
CHEMICAL STABILITY:
Do not combine part drums of the same product, as this may be a source of
CONDITIONS TO AVOID:
contamination. Keep material away from excessive heat, sparks, flames and
other ignition sources. Keep away from oxidising agents.
Oxidising agents, mineral acids, strong alkalis, halogenated compounds and
INCOMPATIBLE MATERIALS:
peroxides. Natural rubber, butyl rubber, neoprene, EPDM, polystyrene and
painted surfaces. Aluminium, copper, and their alloys.
Carbon oxides, soot, smoke and other organic compounds. The packaging
HAZARDOUS DECOMPOSITION PRODUCTS:
material may burn to emit noxious fumes.
Explosive air-vapour mixture may form. Explosive when mixed with oxidising
HAZARDOUS REACTIONS:
substances. Contact with aluminium or its alloys may result in alcoholate
formation and subsequent evolution of hydrogen.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE EFFECTS
Swallowing can result in irritation to the gastro-intestinal tract, nausea, vomiting, diarrhoea,
INGESTION:
abdominal pain, headache, dizziness, central nervous system depression and loss of
consciousness. Aspiration into lungs when swallowed or vomited may cause chemical pneumonitis.
A severe eye irritant and may cause redness and swelling. Vapour can also irritate the eye.
EYE CONTACT:
Harmful in contact with skin. Moderate skin irritant and may defat the skin with continual use causing
SKIN CONTACT:
severe irritation. Symptoms may include redness, and swelling of skin. Can be absorbed through the
skin. May cause sensitisation by skin contact.
Vapours, mists and sprays are capable of causing irritation to the mucous membranes and
INHALATION:
respiratory tract, headache and nausea. High concentrations may result in dizziness and vomiting,
central nervous system depression, which can lead to loss of coordination, impaired judgment and, if
exposure is prolonged, unconsciousness.
No information available for the product.
LONG TERM EFFECTS:
No toxicity data for this specific product, however toxicity data for the hazardous ingredients is listed
ACUTE TOXICITY /
below.
CHRONIC TOXICITY:
TOXICITY DATA FOR D-LIMONENE
Dermal LD50 (rabbit) > 5000 mg/kg Oral LD50 (rat, male) 4.4 g/kg
Oral LD50 (rat, female) 5.1 g/kg Oral LD50 (mouse, male) 5.6 mg/kg
Oral LD50 (mouse, female) 6.6 mg/kg
TOXICITY DATA FOR ETHYLENE GLYCOL MONOBUTYL ETHER:
Oral LD50 (rat) 530 - 3000 mg/kg Oral LD50 (guinea pig) 950 - 1414 mg/kg
Dermal LD50 (rabbit) 100 鈥? 610 mg/kg Dermal LD50 (guinea pig) 1200 - >2000 mg/kg
Inhalation LC50 (rat) 450-490 ppm/4H
Product Name: Page:
SUPER SOLV 4 of 6
MATERIAL SAFETY DATA SHEET
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways. Expected to be toxic to fish and invertebrates.
ECOTOXICITY:
ECOTOXICITY DATA FOR D-LIMONENE:
LC50 Rainbow Trout 80 鈥? 88.7 mg/L/96 hr
LC50 Fathead minnow 0.702 mg/L/96 hr
EC50 Daphnia Magna 0.421mg/L/48 hr
ECOTOXICITY DATA FOR ETHYLENE GLYCOL MONOBUTYL ETHER:
24hr LC50 (goldfish): 1650 mg/L
7 day LC50 (guppy): 983 ppm
The product is considered to be readily biodegradable.
PERSISTENCE AND DEGRADABILITY:
No information available.
MOBILITY:
None.
OTHER:
13. DISPOSAL CONSIDERATIONS
Dispose of material under the requirements of state environmental authority. Advise of
DISPOSAL METHODS:
flammable nature. Do not contaminate stream, rivers or watercourses. Inform local
authority if liquid enters drains, sewers, streams, etc. Empty containers should be forwarded
to an approved agent for recycling.
Dispose of material through a licensed waste contractor. Incinerate under controlled
SPECIAL PRECAUTIONS FOR
conditions if permitted by local authorities.
LANDFILL OR INCINERATION:
14. TRANSPORT INFORMATION
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods
ROAD AND RAIL TRANSPORT:
Code (ADG Code) for transport by Road and Rail.
1993
UN NUMBER:
FLAMMABLE LIQUID, N.O.S. (CONTAINS d-LIMONENE)
UN PROPER SHIPPING NAME:
3
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
3[Y]
HAZCHEM CODE:
Guide 14
INITIAL EMERGENCY RESPONSE GUIDE:
Not to be loaded with explosives (class 1), toxic gas (class 2.3), spontaneously
SEGREGATION DANGEROUS GOODS:
combustible (class 4.2), oxidising agents (class 5.1), organic peroxides (class 5.2),
radioactive substances (class 7), foodstuffs and foodstuff empties, however
exemptions may apply.
Classified as Dangerous Goods by the criteria of the International Maritime
MARINE TRANSPORT:
Dangerous Goods Code (IMDG Code) for transport by sea.
1993
UN NUMBER:
FLAMMABLE LIQUID, N.O.S. (CONTAINS d-LIMONENE)
UN PROPER SHIPPING NAME:
3
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
Category A
STOWAGE AND SEGREGATION:
Classified as Dangerous Goods by the criteria of the International Air Transport
AIR TRANSPORT:
Association (IATA) for transport by air.
1993
UN NUMBER:
FLAMMABLE LIQUID, N.O.S. (CONTAINS d-LIMONENE)
UN PROPER SHIPPING NAME:
3
CLASS AND SUBSIDIARY RISK(S):
III
PACKAGING GROUP:
3L
ERG CODE:
Product Name: Page:
SUPER SOLV 5 of 6
MATERIAL SAFETY DATA SHEET
15. REGULATORY INFORMATION
POISONS SCHEDULE (AUST.): 6
Not relevant.
APVMA STATUS:
Not relevant.
TGA STATUS:
All the constituents of this product are listed.
AICS STATUS:
Not relevant.
AQIS STATUS:
Not relevant.
OTHER:
16. OTHER INFORMATION
This product is a flammable liquid. Use good industrial hygiene.
GENERAL INFORMATION:
002
MSDS ISSUE NUMBER:
29 AUGUST 2006
MSDS ISSUE DATE:
In any event, the review and, if necessary, the re-issue of a MSDS shall be no longer than 5 years after the last date of issue.
Electronic versions of the MSDS鈥檚 in a PDF format are also available on our Website at www.cleantec.com.au/product.asp
REASON(S) FOR ISSUE: Update to conform to requirements of NOHSC:2011(2003); 16-header format.
THIS ISSUE NUMBER REPLACES ALL PREVIOUS ISSUES.
LITERARY REFERENCE:
SOURCES FOR DATA:
LEGEND:
AICS Australian Inventory of Chemical Substances
AIHA American Industrial Hygiene Association
APVMA Australian Pesticides and Veterinary Medicines Authority
AQIS Australian Quarantine and Inspection Service
AS Australian Standard (as issued by Standards Australia)
ERP Code Emergency Response Drill Code as found in the ICAO (International Civil Aviation Organisation) Doc 9481
MSDS Material Safety Data Sheet
NOHSC National Occupational Health and Safety Commission
OEL Occupational Exposure Limit
STEL Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a
working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the
STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There
should be at least 60 minutes between successive exposures at the STEL.
TGA Therapeutic Goods Administration
TLV Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental
Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents
to which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect.
TWA Time Weighted Average - The average airborne concentration of a particular substance when calculated over
a normal eight-hour working day, for a five-day working week.
This MSDS has been prepared from current technical data and summarises at the date of issue our best knowledge of the health and safety
information of the product, and in particular how to safely handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also
available upon request.
This MSDS may only be reproduced in full. Summaries or excerpts from this MSDS may not contain all the relevant information and thus are
not permitted.
End of MSDS
Product Name: Page:
SUPER SOLV 6 of 6
|