ZEP Inc.
Material Safety Data Sheet
P.O. Box 2015
Atlanta, GA 30301
1-877-I-BUY-ZEP (428-9937)
www.zep.com
Section 1. Chemical Product and Company Identification
Product name BIG ORANGE (LIQUID)
Industrial Solvent Degreaser
Product use
0415
Product code
Date of issue Supersedes 03/24/05
12/07/07
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Printing date: 12/07/07
Prepared By
Compliance Services Group
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity
WARNING ! 1 2 0
COMBUSTIBLE. CAUSES EYE IRRITATION.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Dermal contact. Eye contact. Inhalation.
Acute Effects Routes of Entry
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching.
Eyes
May cause skin irritation. May cause skin sensitization. May cause allergic reactions in certain
Skin
individuals. Skin inflammation is characterized by itching, scaling, or reddening.
Inhalation Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory
irritation.
Ingestion May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause
damage.
Prolonged or repeated contact may dry skin and cause irritation. Contains material which may
Chronic effects
cause damage to the following organs: kidneys, lungs, liver.
Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients CAS number % by Weight
D-LIMONENE; orange distillate; citrus terpene; cyclohexene, 1-methyl-4-(1-methylethenyl)-, 5989-27-5 >90
(R)-
NONYLPHENOXYPOLY(ETHYLENEOXY)ETHANOL npe; poly(oxy-1,2-ethanediyl) 9016-45-9 1-5
alpha-(nonylphenyl)-omega-hydroxy
NONYLPHENOXY POLY(ETHYLENEOXY) ETHANOL - npe; poly(oxy-1,2-ethanediyl) 9016-45-9 1-5
alpha-(nonylphenyl)-omega-hydroxy
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at
Skin Contact
least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops.
Move exposed person to fresh air. If irritation persists, get medical attention.
Inhalation
If swallowed, do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head
Ingestion
should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. Get medical attention immediately.
Page: 1/3
Product Name BIG ORANGE (LIQUID)
Material Safety Data Sheet
Product code 0415
National Fire Protection Association (U.S.A.)
Section 5. Fire Fighting Measures
2
Closed cup: 49.4掳C (120.9掳F)
Flash Point 1 0
[Tagliabue.]
Flammable Limits Not determined.
COMBUSTIBLE.
Flammability
Combustible liquid and vapor. Keep away from heat, sparks and flame.
Fire hazard
Use dry chemical, CO2, water spray (fog) or foam. Fire-fighters should wear appropriate
Fire-Fighting
protective equipment. Do not release runoff from fire to sewers or waterways.
Procedures
Section 6. Accidental Release Measures
Eliminate all ignition sources. Put on appropriate personal protective equipment (see section 8). Dilute with
Spill Clean up
water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal
container. Dispose of via a licensed waste disposal contractor.
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame
Handling
or any other ignition source. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists.
Use only with adequate ventilation. Do not ingest. Observe label precautions. Wash thoroughly after handling.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Keep away from heat and direct sunlight. Avoid all possible sources of ignition (spark or flame). Keep container in a
Storage
cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Keep away from food, drink
and animal feeding stuffs. Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Personal Protective Equipment (PPE)
Safety glasses.
Eyes
For prolonged or repeated handling, use gloves. Recommended:
Body
Neoprene gloves. Nitrile gloves. Rubber gloves.
Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering
controls to keep the airborne concentrations of vapors below their respective
occupational exposure limits.
Section 9. Physical and Chemical Properties
Liquid. Color Clear. Orange.
Physical State
Not applicable. Odor Orange. [Strong]
pH
170掳C (338掳F) Vapor Pressure 0.25 kPa (1.9 mm Hg)
Boiling Point
0.85 Vapor Density 4.7 [Air = 1]
Specific Gravity
Emulsifies in water. Evaporation Rate <1 (Water = 1)
Solubility
VOC (Consumer) 789.37 (g/l). 6.59 lbs/gal 92.70%
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Combustible materials should be stored away from extreme heat and away from strong oxidizing
Incompatibility
agents. Incompatible with some strong acids. Reactive with acidic clay (i.e. clay absorbent)
Reactive or incompatible with the following materials: oxidizing materials.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products carbon oxides
Section 11. Toxicological Information
Acute Toxicity
Exposure
Product/ingredient name Result Species Dose
d-Limonene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Nonylphenoxypoly(Ethyleneoxy)Ethano LD50 Dermal Rabbit 2000 mg/kg -
LD50 Oral Rat 3310 mg/kg -
Page: 2/3
Product Name BIG ORANGE (LIQUID)
Material Safety Data Sheet
Product code 0415
Section 12. Ecological Information
No known significant effects or critical hazards.
Environmental Effects
Aquatic Ecotoxicity
Not available.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or
regional authorities for additional information.
Waste Stream Code: D001
Classification: - [Hazardous waste.]
Origin: - [RCRA waste.]
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label
DOT Classification Not applicable. Not a DOT controlled material
(United States).
Not determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
No products were found.
California Prop 65
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to
relay the meanings of this scale.
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