MATERIAL SAFETY DATA SHEET
MustangMAX鈩? Insecticide
MSDS Ref. No.: 52315-07-8-52
Date Approved: 06/11/2007
Revision No.: 11
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
MustangMAX鈩? Insecticide
PRODUCT NAME:
6084; 6209
PRODUCT CODE:
Zeta-cypermethrin (2S)
ACTIVE INGREDIENT(S):
Pyrethroid Pesticide
CHEMICAL FAMILY:
C22H19Cl2NO3 (zeta-cypermethrin 2S)
MOLECULAR FORMULA:
FMC 291799; (S)-Cyano-(3-phenoxyphenyl)methyl (+)cis-3-(2,2-
SYNONYMS:
dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate and (S)-
cyano-(3-phenoxyphenyl)methyl (+)trans-3-(2,2-dichloroethenyl)-
2,2-dimethylcyclopropanecarboxylate
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (800) 331-3148 (FMC - U.S.A. & Canada)
Agricultural Products Group (716) 735-3765 (FMC - Reverse charges)
1735 Market Street
Philadelphia, PA 19103
(215) 299 6000 (General Information) For leak, fire, spill, or accident emergencies, call:
msdsinfo@fmc.com (Email - General Information) (800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(703) 527-3887 (CHEMTREC - All Other Countries)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
鈥? Brown liquid with an aromatic solvent odor.
鈥? Moderately combustible. May support combustion if heated above the product's flash point (see
Section 9, "Physical and Chemical Properties" below).
鈥? Thermal decomposition and burning may form toxic by-products.
鈥? For large exposures or fire, wear personal protective equipment.
鈥? Highly toxic to fish and aquatic organisms. Keep out of drains and water courses.
鈥? Moderately irritating if swallowed and moderately irritating to the skin.
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
POTENTIAL HEALTH EFFECTS: Effects from overexposure result from either
swallowing or inhaling this product. Symptoms of overexposure include tremors, convulsions, increased
sensitivity to touch, and incoordination. Contact with this product may produce skin sensations such as
numbing, burning or tingling. These skin sensations are reversible and usually subside within 12 hours.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Zeta-cypermethrin (2S) 52315-07-8 9.6 257-842-9 Not classified
Aromatic Hydrocarbons 64742-95-6 <32.1 265-199-0 R10-37-51/53-65-66-67;
S23-24-43A-57-60-62
Surfactant Blend <6.5 None Not classified
Naphthalene 91-20-3 <5.2 202-049-5 R22-40-50/53; S2-36/37-
46-60-61
1-butanol 71-36-3 <1 200-751-6 R10-22-37/38-41-67; S2-
7/9-13-26-37/39-46
4. FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, obtain medical
attention.
SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation occurs and
persists, contact a medical doctor.
INGESTION: Do not induce vomiting and do not give liquids of any kind to the person. Never give
anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists,
contact a medical doctor.
NOTES TO MEDICAL DOCTOR: This product has moderate oral, and low dermal and
inhalation toxicity. It is moderately irritating to the skin and mildly irritating to the eyes. Contains aromatic
hydrocarbons that may produce a severe pneumonitis if aspirated during vomiting. Consideration should be
given to gastric lavage with an endotracheal tube in place. Reversible skin sensations (paresthesia) may
occur and ordinary skin salves have been found useful in reducing discomfort. Treatment is otherwise
controlled removal of exposure followed by symptomatic and supportive care.
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-
combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.
To clean and neutralize contaminated area, scrub area with a solution of detergent (e.g. commercial product
such as SuperSoap鈩?, Tide庐, Spic and Span庐, or other high pH detergent) and water. Let solution sit for 5
minutes. Use a stiff brush to scrub affected area. Repeat if necessary to remove visible staining.
Additional decontamination can be made by applying bleach (Clorox庐 or equivalent) to affected area.
Absorb wash-liquid as noted above, remove visibly contaminated soil and place into recovery / disposal
container (plastic, open-top steel drum or equivalent). Place all clean-up material in a container, seal and
dispose of in accordance with the method outlined in Section 13 "Disposal Considerations" below.
For further information on spill clean-up, waste disposal, or return of salvaged product, call the FMC
Emergency Hotline number listed in Section 1 "Product and Company Identification" above.
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Keep out of reach
of children and animals. Do not store below -6.6掳C (20掳F). If solids are observed, warm above 4.4掳C (40掳F)
and roll or shake containers to re-dissolve. Do not use or store near heat, open flame or hot surfaces. Store
in original containers only. Carefully open containers. After partial use, replace lids and close tightly. Do
not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name ACGIH OSHA Supplier
Aromatic 18 ppm
Hydrocarbons
Naphthalene 10 ppm (TWA) 10 ppm (TWA)
50 mg/m3 (TWA)
15 ppm (STEL)
15 ppm (STEL)
1-butanol 20 ppm (TWA) (ceiling) 100 ppm (TWA) (ceiling)
50 ppm (PEL) (ceiling)
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
GLOVES: Wear chemical protective gloves made of materials such as nitrile, neoprene or
Viton庐 brand. Thoroughly wash the outside of gloves with soap and water prior to removal.
Inspect regularly for leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
COMMENTS:
Personal protective recommendations for mixing or applying this product are prescribed on the product
label. Information stated above provides useful, additional guidance for individuals whose use or handling
of this product is not guided by the product label.
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
9. PHYSICAL AND CHEMICAL PROPERTIES
Aromatic solvent
ODOR:
Brown liquid
APPEARANCE:
8.3 lb/gal. (1000 g/L)
DENSITY / WEIGHT PER VOLUME:
> 98 掳C (> 208 掳F) (TCC)
FLASH POINT:
416.3 (zeta-cypermethrin)
MOLECULAR WEIGHT:
3.9
pH:
Emulsifies
SOLUBILITY IN WATER:
1.0 g/mL @ 20掳C
SPECIFIC GRAVITY:
10. STABILITY AND REACTIVITY
Excessive heat and fire.
CONDITIONS TO AVOID:
Stable
STABILITY:
Will not occur
POLYMERIZATION:
Carbon monoxide, carbon dioxide, hydrogen
HAZARDOUS DECOMPOSITION PRODUCTS:
cyanide, chlorine and hydrogen chloride.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Mildly irritating (rabbit)
SKIN EFFECTS: Moderately irritating (rabbit)
DERMAL LD50: > 5,000 mg/kg (rat)
ORAL LD50: 157 mg/kg (rat)
INHALATION LC50: 3.3 mg/l (4 h) (rat)
SENSITIZATION: This product is not a skin sensitizer.
ACUTE EFFECTS FROM OVEREXPOSURE: This product has moderate oral, and
low dermal and inhalation toxicity. It is moderately irritating to the skin and mildly irritating to the eyes.
Signs of toxicity in laboratory animals included tremors, tonic - clonic convulsions, loss of muscle control,
rales, bloody oral discharge, hypersensitivity to touch and ataxia. Experience to date indicates that contact
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
with this product may produce skin sensations such as numbing, burning or tingling. These sensations are
reversible and usually subside within 12 hours. Inhalation of aromatic hydrocarbon vapors may cause
dizziness, disturbances in vision, drowsiness, respiratory irritation, and eye, skin and mucous membrane
irritation. Vomiting after ingestion of this product may cause aspiration of aromatic hydrocarbons into the
lungs, which may result in fatal pulmonary edema. Exposure to butanol vapors may produce headaches,
drowsiness and irritation of the nose and throat. Excessive exposures to butanol liquid or vapors may result
in contact dermatitis and irritation of the mucous membranes. Naphthalene, if ingested, may cause red
blood cell hemolysis, especially in individuals with glucose-6-phosphate dehydrogenase deficiency.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
formulation. In studies with laboratory animals, zeta-cypermethrin did not cause reproductive effects or
teratogenicity in laboratory animals. An overall absence of genotoxicity has been demonstrated in tests of
mutagenicity, DNA damage and chromosome aberrations. Chronic exposure to aromatic hydrocarbons may
cause headaches, dizziness, loss of sensations or feelings (such as numbness), and liver and kidney damage.
Naphthalene causes cataracts in humans, rats, rabbits and mice. In 2-year inhalation studies conducted by
the National Toxicology Program (NTP), there was no evidence of carcinogenic activity of naphthalene in
male mice, there was some evidence of carcinogenic activity in female mice and there was clear evidence
of carcinogenic activity in male and female rats. Inhalation studies conducted by the International Agency
for Research on Cancer (IARC) have found that there is inadequate evidence of carcinogenicity in humans,
therefore, IARC has classified naphthalene as a Group 2B (possibly carcinogenic to humans); however,
IARC has found that there is sufficient evidence of carcinogenicity in experimental animals. Disturbances
in hearing and balance have been reported in workers exposed to butanol vapors.
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
Naphthalene Listed Listed Not listed (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
The physical and environmental properties, as well as the environmental toxicology of zeta-cypermethrin,
are similar to cypermethrin. Unless otherwise indicated, the data presented below pertains to cypermethrin.
ENVIRONMENTAL DATA: Cypermethrin is rapidly degraded in soil with a half-life of 2 to
4 weeks. It is readily hydrolyzed under basic conditions (pH = 9), but under acidic and neutral conditions,
hydrolysis half-life can be 20 to 29 days. Cypermethrin has a high affinity for organic matter and a Log
Pow of 5.0; yet because of the ease with which the material undergoes degradation, it has a very low
potential for bioconcentration (BCF = 17) and is not mobile in soil.
ECOTOXICOLOGICAL INFORMATION: Zeta-cypermethrin is considered highly
toxic to fish and aquatic arthropods and has LC50 values which range from 0.002 碌g/L to 2.37 碌g/L. These
values are comparable to cypermethrin. Care should be taken to avoid contamination of the aquatic
environment. Cypermethrin is slightly toxic to birds, and oral LD50 values are greater than 10,248 mg/kg.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic
PROPER SHIPPING NAME:
Zeta-cypermethrin (2S)
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 3352
UN/NA NUMBER:
III
PACKING GROUP:
6.1
LABEL(S):
6.1
PLACARD(S):
Pyrethroid pesticide, liquid, toxic (zeta-
MARKING(S):
cypermethrin 2S), UN3352
Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic
PROPER SHIPPING NAME:
Zeta-cypermethrin (2S)
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 3352
UN/NA NUMBER:
III
PACKING GROUP:
Zeta-cypermethrin (2S)
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
3352
MARKING(S):
Naphthalene
REPORTABLE QUANTITY (RQ):
Naphthalene is in an "RQ" quantity when
ADDITIONAL INFORMATION:
this material meets or exceeds 1,923 pounds
(231.7 gallons) per bulk package.
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic
PROPER SHIPPING NAME:
Zeta-cypermethrin (2S)
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 3352
UN/NA NUMBER:
III
PACKING GROUP:
Zeta-cypermethrin (2S)
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
Pyrethroid pesticide, liquid, toxic (zeta-
MARKING(S):
cypermethrin 2S), UN3352, Marine
Pollutant
EmS Number: F-A, S-A
ADDITIONAL INFORMATION:
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic
PROPER SHIPPING NAME:
Zeta-cypermethrin (2S)
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
T6
CLASSIFICATION CODE:
UN3352
UN/NA NUMBER:
III
PACKING GROUP:
60
HAZARD IDENTIFICATION NUMBER:
Zeta-cypermethrin (2S)
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
UN3352 + Marine Pollutant
MARKING(S):
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic
PROPER SHIPPING NAME:
Zeta-cypermethrin (2S)
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN3352
UN/NA NUMBER:
III
PACKING GROUP:
6.1
LABEL(S):
Y611 / 2L
LIMITED QUANTITY:
611 / 60L
LIMITED QUANTITY: PASSENGER / CARGO:
618 / 220L
LIMITED QUANTITY: CARGO:
Country of origin or destination regulations
ADDITIONAL INFORMATION:
may require the addition of "Marine
Pollutant" to the marks and shipping paper
description.
Marks: Pyrethroid pesticide, liquid, toxic
(zeta-cypermethrin (2S)), UN3352
Marine Pollutant: Zeta-cypermethrin (2S)
OTHER INFORMATION:
HARMONIZED SYSTEM
Import to the U.S.A.: 3808.91.2500
Export from the U.S.A.: 3808.91.0000
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed, Fire
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements:
Naphthalene
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Listed
Chemical Name RQ
Naphthalene 100 lb
1-butanol 5,000 lb
FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
U.S. EPA Signal Word: WARNING
INTERNATIONAL LISTINGS
Australian Hazard Code: 3XE
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Aromatic Hydrocarbons, (Index #649-356-00-4):
EC Symbols: Xn (Harmful)
T (Toxic)
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
EC Risk Phrases: R10 (Flammable)
R37 (Irritating to respiratory system.)
R51/53 (Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
R65 (Harmful: may cause lung damage if swallowed.)
R66 (Repeated exposure may cause skin dryness or cracking.)
R67 (Vapors may cause drowsiness and dizziness.)
EC Safety Phrases: S23 (Do not breathe gas, fumes, vapor, or spray)
S24 (Avoid contact with skin.)
S43A (In case of fire use sand, earth, chemical powder or foam.)
S57 (Use appropriate container to avoid environmental
contamination.)
S60 (This material and its container must be disposed of as
hazardous waste)
S62 (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.)
Notes For Preparation:
Nota H applies to the product or one or more of its components. Annex 1
Nota P of Annex 1 applies to the product or one or more of its components.
Naphthalene, (Index #601-052-00-2):
EC Symbols: Xn (Harmful)
N (Dangerous for the environment)
EC Risk Phrases: R22 (Harmful if swallowed.)
R40 (Possible risks of irreversible effects.)
R50 (Very toxic to aquatic organisms.)
R53 (May cause long-term adverse effects in the aquatic
environment.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S36/37 (Wear suitable protective clothing and gloves.)
S46 (If swallowed, seek medical advice immediately and show this
container or label.)
S60 (This material and its container must be disposed of as
hazardous waste)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
1-butanol, (Index #603-004-00-6):
EC Symbols: Xi (Irritant)
Xn (Harmful)
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MustangMAX鈩? Insecticide (52315-07-8-52) Date: 06/11/2007
EC Risk Phrases: R10 (Flammable)
R22 (Harmful if swallowed.)
R37/38 (Irritating to respiratory system and to skin.)
R41 (Risk of serious damage to eyes.)
R67 (Vapors may cause drowsiness and dizziness.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S7/9 (Keep container tightly closed and in a well-ventilated place.)
S13 (Keep away from food, drink and animal feeding stuffs.)
S26 (In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice)
S37/39 (Wear suitable gloves and eye/face protection.)
S46 (If swallowed, seek medical advice immediately and show this
container or label.)
16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #10, dated August 02, 2005.
Changes in information are as follows:
Section 1 (Product and Company Identification)
Section 14 (Transport Information)
Section 16 (Other Information)
MustangMAX and FMC - FMC Trademarks
Viton - E.I. du Pont de Nemours & Co. Trademark
SuperSoap - Trademark of Weba Technologies, Inc.; Tide - Trademark of Proctor and Gamble; Spic and
Span: Trademark of The Spic and Span Company; Clorox - Trademark of The Clorox Company
漏 2007 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. Use of this product is regulated
by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a
manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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