MATERIAL SAFETY DATA SHEET
DOUBLE THREAT鈩? CP
MSDS Ref. No.: F18-35-9
Date Approved: 06/23/2006
Revision No.: 4
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
DOUBLE THREAT鈩? CP
PRODUCT NAME:
6192
PRODUCT CODE:
Bifenthrin*; Spinosad**
ACTIVE INGREDIENT(S):
*Pyrethroid Insecticide; **Naturalyte
CHEMICAL FAMILY:
*C23H22ClF3O2; **C42H67NO10
MOLECULAR FORMULA:
FMC 54800; (2-methyl[1,1'-biphenyl]-3-yl)methyl 3-(2-chloro-3,3,3-
SYNONYMS:
trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate; IUPAC:
2-methylbiphenyl-3-ylmethyl (Z)-(1RS)-cis-3-(2-chloro-3,3,3-
trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate*;
Spinosyn A: 2-((6-deoxy-2,3,4-tri-O-methyl-alpha-L-
mannopyranosyl)oxy)-13-((5-dimethylamino)tetrahydro-6-methyl-
2H-pyran-2-yl)oxy)-9-ethyl-
2,3,3A,5A,5B,6,9,10,11,12,13,14,16a,16b-tetra-decahydro-14-
methyl-1H-as-indaceno(3,2-d)oxacyclododecin-7,15-dione; Spinosyn
D: 2-((6-deoxy-2,3,4-tri-O-methyl-alpha-L-mannopyranosyl)oxy)-9-
ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-4-14-
eimethyl-1H-as-indaceno(3,2-d)oxacyclododecin-7,15-dione**
*Information for Bifenthrin; ** Information for Spinosad
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (800) 331-3148 (FMC - U.S.A. & Canada)
Agricultural Products Group (716) 735-3765 (FMC - Reverse charges)
1735 Market Street
Philadelphia, PA 19103
(215) 299 6000 (General Information) For leak, fire, spill, or accident emergencies, call:
(800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(703) 527-3887 (CHEMTREC - All Other Countries)
Page 1 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
鈥? *Amber liquid with an aromatic hydrocarbon odor / ** Off-white to tan liquid suspension with low
odor.
鈥? *Moderately combustible. May support combustion if heated above the product's flash point (see
Section 9, "Physical and Chemical Properties" below).
鈥? Thermal decomposition and burning may form toxic by-products.
鈥? For large exposures or fire, wear personal protective equipment.
鈥? Highly toxic to fish and aquatic organisms. Keep out of drains and water courses.
鈥? This product, as a mixture, is expected to have moderate oral toxicity.
POTENTIAL HEALTH EFFECTS: Effects from overexposure result from either
swallowing or coming into contact with the skin. Symptoms of overexposure to Bifenthrin 2 EC includes
tremors, convulsions, incoordination, decreased locomotion and nasal discharge. Contact with bifenthrin
may occasionally produce skin sensations such as rashes, numbing, burning or tingling. These skin
sensations are reversible and usually subside within 12 hours.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
COMMENTS: * Information for Bifenthrin 2 EC; ** Information for Spinosad
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Bifenthrin 82657-04-3 25.1 None R25-20-43-50/53; S1/2-23-
24-37-38-45-29
Spinosad 44.2 None Not classified
Spinosyn A 131929-60-7 None Not classified
Spinosyn D 131929-63-0 None Not classified
Aromatic Hydrocarbons 64742-95-6 <21.22 265-199-0 R10-37-51/53-65-66-67;
S23-24-43A-57-60-62
1,2,4-trimethylbenzene 95-63-6 <12 202-436-9 R10-20-36/37/38-51/53;
S2-26-61
Surfactant Blend <7 None Not classified
Xylene 1330-20-7 <1.1 215-535-7 R10-20/21-38; S2-25
Ethylbenzene 100-41-4 <0.04 202-849-4 R11-20; S2-16-24/25-29
Cumene 98-82-8 <0.5 202-704-5 R10-37-51/53-65; S2-24-
37-61-62
Page 2 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
Chemical Name CAS# Wt.% EC No. EC Class
Propylene Glycol 57-55-6 >1 200-338-0 Not classified
1-butanol 71-36-3 0.6 200-751-6 R10, 22, 37/38, 41, 67; S2-
7/9-13-26-37/39-46
COMMENTS: Spinosad - mixture of Spinosyn A and Spinosyn D
4. FIRST AID MEASURES
EYES: Immediately flush with water for at least 15 minutes, lifting the upper and lower eyelids
intermittently. See a medical doctor immediately.
SKIN: Immediately flush with plenty of water while removing contaminated clothing and/or shoes, and
thoroughly wash with soap and water. See a medical doctor immediately.
INGESTION: Do not induce vomiting and do not give liquids of any kind to the person. Never give
anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, see a
medical doctor. If breathing has stopped, give artificial respiration and see a medical doctor immediately.
NOTES TO MEDICAL DOCTOR: This product, as a mixture, is expected to have
moderate oral, and low dermal and inhalation toxicity. It is expected to be irritating to the eyes and non-
irritating the skin. Aromatic hydrocarbons can produce a severe pneumonitis or fatal pulmonary edema if
aspirated. Consideration should be given to gastric lavage with an endotracheal tube in place. Reversible
skin sensations(paresthesia) may occur and ordinary skin salves have been found useful in reducing
discomfort. Treatment is otherwise controlled removal of exposure followed by symptomatic and
supportive care.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
Page 3 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-
combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.
To clean and neutralize contaminated area, scrub area with a solution of detergent (e.g. commercial product
such as SuperSoap鈩?, Tide庐, Spic and Span庐, or other high pH detergent) and water. Let solution sit for 5
minutes. Use a stiff brush to scrub affected area. Repeat if necessary to remove visible staining.
Additional decontamination can be made by applying bleach (Clorox庐 or equivalent) to affected area.
Absorb wash-liquid as noted above, remove visibly contaminated soil and place into recovery / disposal
container (plastic, open-top steel drum or equivalent). Place all clean-up material in a container, seal and
dispose of in accordance with the method outlined in Section 13 "Disposal Considerations" below.
For further information on spill clean-up, waste disposal, or return of salvaged product, call the FMC
Emergency Hotline number listed in Section 1 "Product and Company Identification" above.
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Bifenthrin 2 EC and Spinosad: Store in a cool, dry, well-
ventilated place. Do not use or store near heat, open flame or hot surfaces. Store in original containers only.
Keep out of reach of children and animals.
Bifenthrin 2 EC: Do not freeze. Do not store below 4掳C (40掳F). If crystals are observed, warm material to
above 15掳C (60掳F) by room heating only. Do not use external source of heat for warming container. Shake
container periodically to re-dissolve crystals. Carefully open containers. After partial use, replace lids and
close tightly. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
Page 4 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
GLOVES: Wear chemical protective gloves made of materials such as nitrile, neoprene or
Viton庐 brand. Thoroughly wash the outside of gloves with soap and water prior to removal.
Inspect regularly for leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
COMMENTS:
Personal protective recommendations for mixing or applying this product are prescribed on the product
label. Information stated above provides useful, additional guidance for individuals whose use or handling
of this product is not guided by the product label.
9. PHYSICAL AND CHEMICAL PROPERTIES
Aromatic hydrocarbon
ODOR:
* Amber liquid / ** Off-white to tan liquid suspension
APPEARANCE:
* 7.91 lb/gal (950 g/L); ** 9.1 lb/gal (1090 g/L)
DENSITY / WEIGHT PER VOLUME:
42 掳C (108 掳F) (CC)Bifenthrin 2 EC
FLASH POINT:
422.88 (bifenthrin)
MOLECULAR WEIGHT:
*Emulsifies; **Dispersible
SOLUBILITY IN WATER:
*0.95 @ 20掳C (water = 1); **1.09 g/mL
SPECIFIC GRAVITY:
COMMENTS:
* Information for Bifenthrin 2 EC; ** Information for Spinosad
10. STABILITY AND REACTIVITY
Excessive heat and fire.
CONDITIONS TO AVOID:
Bifenthrin 2 EC: Stable Spinosad: Thermally
STABILITY:
stable at typical use temperatures. Some
Page 5 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
components of this product can decompose at
elevated temperatures.
Will not occur
POLYMERIZATION:
Carbon monoxide, carbon dioxide, hydrogen
HAZARDOUS DECOMPOSITION PRODUCTS:
chloride and hydrogen fluoride.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: No data available for the mixture.
Bifenthrin 2 EC: Minimally irritating
Spinosad: Slightly irritating
SKIN EFFECTS: No data available for the mixture.
Bifenthrin 2 EC: Non-irritating (rabbit)
Spinosad: Non-irritating (rabbit)
DERMAL LD50: No data available for the mixture.
Bifenthrin 2 EC: > 2,000 mg/kg (rabbit)
Spinosad: > 5,000 mg/kg (rabbit)
ORAL LD50: No data available for the mixture.
Bifenthrin 2 EC: 262 mg/kg (rat)
Spinosad: > 5,000 mg/kg (rat, mouse)
INHALATION LC50: No data available for the mixture.
Bifenthrin 2 EC: 1.86 mg/l (4 h) (rat)
SENSITIZATION: Bifenthrin 2 EC: Produced skin sensitization (allergic reaction) in laboratory
animals and may produce similar symptoms in humans.
ACUTE EFFECTS FROM OVEREXPOSURE: This product, as a mixture, is
expected to have moderate oral, and low dermal and inhalation toxicity. It is expected to be irritating to the
eyes and non-irritating the skin.
A single prolonged dermal exposure to Spinosad is not likely to result in the material being absorbed
through the skin in harmful amounts. Swallowing amounts larger than normal handling may cause injury. A
single exposure to the concentrate mist is not likely to cause adverse effects.
Inhalation of aromatic hydrocarbon vapors may cause dizziness, disturbances in vision, drowsiness,
respiratory irritation, and eye, skin and mucous membrane irritation. Vomiting after ingestion of this
product may cause aspiration of aromatic hydrocarbons into the lungs, which may result in fatal pulmonary
edema. Exposure to butanol vapors may produce headaches, drowsiness and irritation of the nose and
throat. Excessive exposures to butanol liquid or vapors may result in contact dermatitis and irritation of the
mucous membranes. In humans, ingestion of large amounts of propylene glycol has resulted in symptoms
of reversible central nervous system depression including stupor, rapid breathing and heartbeat, profuse
sweating and seizures.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the product
as a mixture.
Page 6 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
No data available for Bifenthrin 2 EC. Information is based on the active ingredient. In studies with
laboratory animals, bifenthrin did not cause reproductive toxicity or teratogenicity. Tremors were
associated with repeated exposure of laboratory animals to bifenthrin. In lifetime feeding studies conducted
with rodents, a slight increase in the incidence of urinary bladder tumors at the highest dose in male mice
was considered to be an equivocal response, not evidence of a clear compound related effect. An overall
absence of genotoxicity has been demonstrated in mutagenicity tests with bifenthrin.
In studies with laboratory animals, Spinosad has been shown to cause vacuolation of cells in various tissues
and changes in blood and serum biochemistry. Dose levels producing these effects were many times higher
than any dose levels expected from exposure due to use. In studies with laboratory animals, Spinosad was
not carcinogenic, mutagenic or teratogenic. Effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Chronic exposure to aromatic hydrocarbons may cause headaches, dizziness, loss of sensations or feelings,
and liver and kidney damage. Inhalation of xylene vapors at high doses has also resulted in an increase
incidence of malformations and decreases in fetal weight in laboratory animals. Damage from xylene may
be potentiated by alcohol. Disturbances in hearing and balance have been reported in workers exposed to
butanol vapors. Repeated overexposure to propylene glycol can produce central nervous system depression,
hemolysis and minimal kidney damage. Under the conditions of 2-year inhalation studies, conducted by the
National Toxicology Program (NTP), there was clear evidence of carcinogenic activity of ethylbenzene in
male rats based on increased incidences of renal tubule neoplasms. The incidences of testicular adenoma
were also increased. There was some evidence of carcinogenic activity in female rats based on increased
incidences of renal tubule adenomas. There was some evidence of carcinogenic activity in male mice based
on increased incidences of alveolar/bronchiolar neoplasm. There was some evidence of carcinogenic
activity in female mice based on increased incidences of hepatocellular neoplasms. Studies conducted by
the International Agency for Research on Cancer (IARC) showed that there is inadequate evidence in
humans for the carcinogenicity of ethylbenzene and that there is sufficient evidence in experimental
animals; therefore, the overall evaluation shows that ethylbenzene is possibly carcinogenic to humans
(Group 2B). Chronic exposure to trimethylbenzenes may cause CNS changes, asthmatic bronchitis and
blood dyscrasias.
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
Ethylbenzene Listed Listed Not listed (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: Bifenthrin 2 EC:
No data available. Information is based on the active ingredient. Bifenthrin has moderate stability in the soil
under aerobic conditions (half-life range from 65 - 125 days depending on soil type) and is stable at a wide
range of pH values. Bifenthrin has a high Log Pow (6.6), a high affinity for organic matter, is not mobile in
soil and therefore has little potential for movement into ground water. There is, however some potential for
bioconcentration (bioconcentration factor <2,000).
Spinosad:
No data available. Information is based on the active ingredient(s). Bioconcentration potential is low (BCF
<100 or Log Pow <3).
Spinosyn A:
Bioconcentration factor in fish is 19. Photolysis half-life in soil is 8.68 days; the photolysis half-life in pH
7 buffer is 0.96 days. Under aerobic soil conditions the half-life is 9.4 and 17.3 days.
Spinosyn D:
Page 7 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
Bioconcentration factor in fish is 33. Photolysis half-life in soil is 9.44 days; the photolysis half-life in pH
7 buffer is 0.84 days.
ECOTOXICOLOGICAL INFORMATION: Bifenthrin 2 EC:
No data available. Information is based on the active ingredient. Bifenthrin is highly toxic to fish and
aquatic arthropods and LC50 values range from 0.0012 mg/l to 17.8 mg/L. In general, the aquatic arthropods
are the most sensitive species. Care should be taken to avoid contamination of the aquatic environment.
Bifenthrin had no effect on mollusks at its limit of water solubility. Bifenthrin is only slightly toxic to both
waterfowl and upland game birds (LD50 values range from 1800 mg/kg to >2150 mg/kg).
Spinosad:
Material is slightly toxic to aquatic organisms on an acute basis (LC50 / EC50 between 10 and 100 mg/L in
most sensitive species).
Acute immobilization EC50 in water flea (daphnia magna) is 16.9 mg/L
Acute LC50 in water flea (Daphnia magna) is >90.9 mg/L
Acute LC50 in zebra fish (Brachydanio rerio) is > 120 mg/L
Acute LC50 in common carp (Cyprinus Carpio) is > 100 mg/L
The LC50 in earthworm (Eisenia foetida) is > 2000 mg/kg
Growth inhibition EC50 in diatom (Navicula sp.) is 0.667 mg/L
Growth inhibition EC50 in green alga (Selenastrum capricornutum) is > 100 mg/L
Acute contact LC50 in honeybee (Apis mellifera) is 0.12 碌g/bee
Acute oral LD50 in honeybee (Apis mellifera) is 0.11 碌g/bee
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
Page 8 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic,
PROPER SHIPPING NAME:
flammable
Bifenthrin, Aromatic hydrocarbons
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
3
HAZARD CLASS, SUBSIDIARY:
UN 3351
UN/NA NUMBER:
III
PACKING GROUP:
6.1, 3
LABEL(S):
6.1
PLACARD(S):
Pyrethroid pesticide, liquid, toxic,
MARKING(S):
flammable (bifenthrin, aromatic
hydrocarbons), UN3351
Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic,
PROPER SHIPPING NAME:
flammable
Bifenthrin, Aromatic hydrocarbons
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
3
HAZARD CLASS, SUBSIDIARY:
UN 3351
UN/NA NUMBER:
III
PACKING GROUP:
Bifenthrin
MARINE POLLUTANT:
6.1, 3
LABEL(S):
6.1
PLACARD(S):
3351
MARKING(S):
xylene
REPORTABLE QUANTITY (RQ):
Xylene is in an "RQ" quantity when this
ADDITIONAL INFORMATION:
material meets or exceeds 9090.9 pounds
(1,149.3 gallons) per bulk package.
Page 9 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic,
PROPER SHIPPING NAME:
flammable
Bifenthrin, Aromatic hydrocarbons
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
3
HAZARD CLASS, SUBSIDIARY:
UN 3351
UN/NA NUMBER:
III
PACKING GROUP:
Bifenthrin
MARINE POLLUTANT:
6.1, 3
LABEL(S):
6.1 3
PLACARD(S):
Pyrethroid pesticide, liquid, toxic,
MARKING(S):
flammable (bifenthrin, aromatic
hydrocarbons), UN3351, Marine Pollutant
EmS Number: F-E, S-D
ADDITIONAL INFORMATION:
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic,
PROPER SHIPPING NAME:
flammable
Bifenthrin, Aromatic hydrocarbons
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
3
HAZARD CLASS, SUBSIDIARY:
TF2
CLASSIFICATION CODE:
UN3351
UN/NA NUMBER:
III
PACKING GROUP:
63
HAZARD IDENTIFICATION NUMBER:
Bifenthrin
MARINE POLLUTANT:
6.1, 3
LABEL(S):
6.1 3
PLACARD(S):
UN3351 + Marine Pollutant
MARKING(S):
Page 10 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Non-Bulk
PACKAGING TYPE:
Pyrethroid pesticide, liquid, toxic,
PROPER SHIPPING NAME:
flammable
Bifenthrin, Aromatic hydrocarbons
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
3
SUBSIDIARY RISK:
UN3351
UN/NA NUMBER:
III
PACKING GROUP:
6.1, 3
LABEL(S):
Y611 / 2L
LIMITED QUANTITY:
611 / 60L
LIMITED QUANTITY: PASSENGER / CARGO:
618 / 220L
LIMITED QUANTITY: CARGO:
Marks: Pyrethroid pesticide, liquid, toxic,
ADDITIONAL INFORMATION:
flammable (bifenthrin, aromatic
hydrocarbons), UN3351
OTHER INFORMATION:
HARMONIZED SYSTEM
Import to the U.S.A.: 3808.10.2500
Export from the U.S.A.: 3808.10.0000
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed, Fire
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
Page 11 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements:
1,2,4-trimethylbenzene, Bifenthrin, Xylene (mixed isomers), Cumene, Ethylbenzene
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Listed
Chemical Name RQ
Xylene 100 lb
Ethylbenzene 1,000 lb
Cumene 5,000 lb
1-butanol 5,000 lb
FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
U.S. EPA Signal Word: WARNING
INTERNATIONAL LISTINGS
Australian Hazard Code: 3XE
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Bifenthrin:
EC Symbols: T (Toxic)
Xn (Harmful)
N (Dangerous for the environment)
EC Risk Phrases: R25 (Toxic if swallowed.)
R20 (Harmful by inhalation.)
R43 (May cause sensitization by skin contact.)
R50/53 (Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S1/2 (Keep locked up and out of reach of children.)
S23 (Do not breathe gas, fumes, vapor, or spray)
S24 (Avoid contact with skin.)
S37 (Wear suitable gloves.)
S38 (In case of insufficient ventilation, wear suitable respiratory
equipment.)
S45 (In case of accident or if you feel unwell, seek medical advice
immediately - show the label where possible.)
S29 (Do not empty into drains.)
Notes For Preparation:
CLASSIFICATION: Mandatory labeling (self-classification) of hazardous substances: applicable
Aromatic Hydrocarbons, (Index #649-356-00-4):
Page 12 of 15
DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
EC Symbols: Xn (Harmful)
T (Toxic)
EC Risk Phrases: R10 (Flammable)
R37 (Irritating to respiratory system.)
R51/53 (Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
R65 (Harmful: may cause lung damage if swallowed.)
R66 (Repeated exposure may cause skin dryness or cracking.)
R67 (Vapors may cause drowsiness and dizziness.)
EC Safety Phrases: S23 (Do not breathe gas, fumes, vapor, or spray)
S24 (Avoid contact with skin.)
S43A (In case of fire use sand, earth, chemical powder or foam.)
S57 (Use appropriate container to avoid environmental
contamination.)
S60 (This material and its container must be disposed of as
hazardous waste)
S62 (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.)
Notes For Preparation:
Nota H applies to the product or one or more of its components. Annex 1
Nota P of Annex 1 applies to the product or one or more of its components.
1,2,4-trimethylbenzene, (Index #601-043-00-3):
EC Symbols: Xn (Harmful)
Xi (Irritant)
N (Dangerous for the environment)
EC Risk Phrases: R10 (Flammable)
R20 (Harmful by inhalation.)
R36/37/38 (Irritating to eyes, respiratory system and skin.)
R51/53 (Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S26 (In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
Xylene, (Index #601-022-00-9):
EC Symbols: Xn (Harmful)
Xi (Irritant)
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DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
EC Risk Phrases: R10 (Flammable)
R20 (Harmful by inhalation.)
R21 (Harmful in contact with skin.)
R38 (Irritating to skin)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S25 (Avoid contact with eyes.)
Ethylbenzene, (Index #601-023-00-4):
EC Symbols: F (Highly Flammable)
Xn (Harmful)
EC Risk Phrases: R11 (Highly flammable)
R20 (Harmful by inhalation.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S16 (Keep away from sources of ignition - No Smoking.)
S24/25 (Avoid contact with skin and eyes.)
S29 (Do not empty into drains.)
Cumene, (Index #601-024-00-X):
EC Symbols: Xn (Harmful)
Xi (Irritant)
N (Dangerous for the environment)
EC Risk Phrases: R10 (Flammable)
R37 (Irritating to respiratory system.)
R51/53 (Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
R65 (Harmful: may cause lung damage if swallowed.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S24 (Avoid contact with skin.)
S37 (Wear suitable gloves.)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
S62 (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.)
1-butanol, (Index #603-004-00-6):
EC Symbols: Xn (Harmful)
Xi (Irritant)
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DOUBLE THREAT鈩? CP (F18-35-9) Date: 06/23/2006
EC Risk Phrases: R10 (Flammable)
R22 (Harmful if swallowed.)
R37/38 (Irritating to respiratory system and to skin.)
R41 (Risk of serious damage to eyes.)
R67 (Vapors may cause drowsiness and dizziness.)
EC Safety Phrases: S2 (Keep out of the reach of children.)
S7/9 (Keep container tightly closed and in a well-ventilated place.)
S13 (Keep away from food, drink and animal feeding stuffs.)
S26 (In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice)
S37/39 (Wear suitable gloves and eye/face protection.)
S46 (If swallowed, seek medical advice immediately and show this
container or label.)
16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #3, dated July 08, 2005.
Changes in information are as follows:
Section 12 (Ecological Information)
Section 16 (Other Information)
Double Threat and FMC Logo - FMC Trademarks
Spinosad - Product of Dow AgroSciences
Viton - E.I. du Pont de Nemours & Co. Trademark
SuperSoap - Trademark of Weba Technologies, Inc.; Tide - Trademark of Proctor and Gamble; Spic and
Span: Trademark of The Spic and Span Company; Clorox - Trademark of The Clorox Company
漏 2006 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. Use of this product is regulated
by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a
manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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