MATERIAL SAFETY DATA SHEET
RANMAN鈩? FUNGICIDE
MSDS Ref. No.: 120116-88-3-1
Date Approved: 05/15/2006
Revision No.: 2
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
RANMAN鈩? FUNGICIDE
PRODUCT NAME:
6267
PRODUCT CODE:
Cyazofamid
ACTIVE INGREDIENT(S):
Cyanoimidazole
CHEMICAL FAMILY:
C13H13C1N4O2S
MOLECULAR FORMULA:
CAS: 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1H-
SYNONYMS:
imidazole-1-sulfonamide; IUPAC: 4-chloro-2-cyano-N,N-dimethyl-
5-p-tolylimidazole-1-sulfonamide
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
ISHIHARA SANGYO KAISHA, LTD (800) 331-3148 (FMC - U.S.A. & Canada)
3 - 15, Edobori 1-Chome (716) 735-3765 (FMC - Reverse charges)
Nishi-ku, Osaka 550-0002
Japan (888) 484-7546 (ISK - 24-hour Emergency)
(440) 357-0640 (General Information - ISK
Biosciences Corp. Concord, OH)
For leak, fire, spill, or accident emergencies, call:
DISTRIBUTED BY: (800) 424-9300 (CHEMTREC - U.S.A. & Canada)
FMC CORPORATION (703) 527-3887 (CHEMTREC - All Other Countries)
Agricultural Products Group
1735 Market Street
Philadelphia, PA 19103
(215) 299-6000 (General Information)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
鈥? Light-tan to beige liquid, with a slight musty latex paint odor.
鈥? Slightly combustible. May support combustion at elevated temperatures.
鈥? Thermal decomposition and burning may form toxic by-products.
鈥? For large exposures or fire, wear personal protective equipment.
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
POTENTIAL HEALTH EFFECTS: No significant hazard expected unless large quantities
are ingested. Repeated or prolonged inhalation exposure may cause lung irritation.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Cyazofamid 120116-88-3 34.5 None Not classified
4. FIRST AID MEASURES
EYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious
person. If any discomfort persists, obtain medical attention.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain
medical attention.
NOTES TO MEDICAL DOCTOR: This product has low oral, dermal and inhalation
toxicity. It is non-irritating to the skin and eyes, and is non-sensitizing to the skin. Treatment is otherwise
controlled removal of exposure followed by symptomatic and supportive care.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: SMALL FIRES: Use water spray, dry chemical, foam or carbon
dioxide. LARGE FIRES: Use water spray, dry chemicals, foam or carbon dioxide. DO NOT use water jet.
FIRE / EXPLOSION HAZARDS: Slightly combustible. This material may support
combustion at elevated temperatures.
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-
combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.
To clean and neutralize spill area, tools and equipment, wash with a solution of soap and water and add the
solution to the drums of waste already collected. Dispose of drummed waste according to the method
outlined in Section 13, "Disposal Considerations".
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or
store near heat, open flame or hot surfaces. Store in original containers only. Keep out of reach of children
and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
GLOVES: Wear chemical resistant, waterproof gloves. Thoroughly wash the outside of
gloves with soap and water prior to removal. Inspect regularly for leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Slight musty latex paint
ODOR:
Light-tan to beige liquid
APPEARANCE:
503 掳C (937 掳F) (using 100 ul)
AUTOIGNITION TEMPERATURE:
-5 掳C (23 掳F)
FREEZING POINT:
152.7潞C (based on active ingredient)
MELTING POINT:
324.9 (cyazofamid)
MOLECULAR WEIGHT:
6.2 (1% dilution in water)
pH:
0.107 mg/L at pH 7 @ 20潞C (based on active ingredient)
SOLUBILITY IN WATER:
1.154 g/mL (Water = 1)
SPECIFIC GRAVITY:
0.0000001 torr at 25潞C (0.0000133 Pascal) (based on
VAPOR PRESSURE:
active ingredient)
10. STABILITY AND REACTIVITY
Excessive heat and fire.
CONDITIONS TO AVOID:
Stable
STABILITY:
Will not occur
POLYMERIZATION:
The active ingredient degrades with iron,
INCOMPATIBLE MATERIALS:
aluminum, iron acetate or aluminum acetate at
54潞C.
Under fire conditions, product may decompose to
HAZARDOUS DECOMPOSITION PRODUCTS:
emit hazardous vapors and gases, which may
irritate the respiratory tract.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Non-irritating (species unknown)
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
SKIN EFFECTS: Non-irritating (rabbit)
DERMAL LD50: > 2,000 mg/kg (rat)
ORAL LD50: > 5,000 mg/kg (rat)
INHALATION LC50: > 5.9 mg/l (4 h) (species unknown)
SENSITIZATION: (Skin) Non-sensitizing (species unknown)
ACUTE EFFECTS FROM OVEREXPOSURE: This product has low oral, dermal
and inhalation toxicity. It is non-irritating to the skin and eyes, and is non-sensitizing to the skin. No
significant hazards are expected unless large quantities are ingested. Repeated or prolonged inhalation
exposure may cause lung irritation. No other data are available at this time.
CHRONIC EFFECTS FROM OVEREXPOSURE: This product was negative in the
Ames mutagenicity assay. This product is classified as "not likely to be carcinogenic to humans" based on
rat and mouse studies. Appropriate precautions should be taken to minimize exposure. No other data are
available at this time.
CARCINOGENICITY:
Not listed
NTP:
Not listed
IARC:
Not listed
OSHA:
(ACGIH) Not listed
OTHER:
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available for the formulation.
Cyazofamid has a rapid degradation rate in soil (half-life ranges from 3.7 - 6.4 days depending on soil type)
and water (approximately 11.9 days depending on pH), therefore it should not persist in the environment.
Photolysis half-life is approximately 30 minutes. Cyazofamid has limited mobility in soil due to its strong
affinity for adsorption to organic matter (Koc ranges from 815/657 to 1524/1062 depending on soil type).
Therefore, there is little potential for movement into ground water.
ECOTOXICOLOGICAL INFORMATION: No data available for the formulation.
Cyazofamid is practically non-toxic to birds (LD50 > 2000 mg/kg, species not specified) and honey bees
(LD50 > 100 g/bee). Due to its limited solubility, the LC50 to freshwater fish and Daphnia magna is >0.1
ppm and >1.3 ppm, respectively. Cyazofamid is highly toxic to estuarine fish (LC50 > 0.167 ppm, species
not specified), and very highly toxic to mysid shrimp (LC50 = 0.089 ppm) and mollusks (EC50 = 0.015
ppm).
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple-rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
This material is not a hazardous material as
ADDITIONAL INFORMATION:
defined by US Department of
Transportation at 49 CFR Parts 100 through
185.
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
This material is not a dangerous good as
ADDITIONAL INFORMATION:
defined by the International Maritime
Dangerous Goods Code.
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
This material is not a dangerous good as
ADDITIONAL INFORMATION:
defined in ICAO and the International Air
Transport Association Dangerous Goods
Regulations.
15. REGULATORY INFORMATION
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
There are no ingredients in this product, which are subject to Section 313 reporting
requirements.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Not listed
FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
U.S. EPA Signal Word: CAUTION
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Not a controlled product under the Canadian Workplace Hazardous Materials Information System
(WHMIS).
INTERNATIONAL LISTINGS
Australian Hazard Code: 3XE
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
EC Symbols: (Not classified as hazardous)
EC Risk Phrases: (Not classified as hazardous)
EC Safety Phrases: (Not classified as hazardous)
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RANMAN鈩? FUNGICIDE (120116-88-3-1) Date: 05/15/2006
16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #1, dated June 22, 2005.
Changes in information are as follows:
Section 9 (Physical and Chemical Properties)
Section 16 (Other Information)
FMC Logo - FMC Corporation Trademark
Ranman - ISK Biosciences Corporation Trademark
漏 2006 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. Use of this product is regulated
by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a
manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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