The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: FH/C/2007/BRRM-732PQG Issue Date: May, 2007
Supersedes: FH/C/2006/BRRM-6SVR4T Issue Date: August, 2006
SECTION I - PRODUCT IDENTIFICATION
Identity: Liquid Hand Dishwashing Detergents Finished Product
Brands: P&G PROFESSIONAL DAWN
P&G Telephone Number: 1-800-332-7787 or call Local Poison Control Center or your physician.
SECTION II - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestions: Ingestion may cause transient gastrointestinal irritation.
Eye Contact: May cause mild, transient irritation.
Skin Contact: Transient irritation with prolonged exposure to concentrated material.
Inhalation: N/A
Signs and Symptoms of Exposure:
Ingestion: May result in nausea, vomiting, and/or diarrhea.
Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness.
Skin Contact: Prolonged contact with concentrated material may be drying or transiently irritating to
skin.
Inhalation: N/A
Medical Conditions Generally Known to be Aggravated by Exposure: None
Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS
Ingredients: Water (CAS# 7732-18-5), sodium alkyl sulfate (CAS# 68585-47-7), sodium alkyl
ethoxylate sulfate (CAS# 68585-34-2), alkyl dimethyl amine oxide (CAS# 70592-80-2), undeceth-9
(CAS# 34398-01-1), SD alcohol (CAS# 64-17-5)
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
Common Name CAS No. Composition LD50/LC50
Chemical Name
Range
Ethyl alcohol Ethanol 64-17-5 1-5% 7.06 g/kg (oral, rat)
P&G PROFESSIONAL DAWN Page 1 of 5
SECTION IV 鈥? FIRST AID INFORMATION
First Aid Procedures:
Ingestion: Drink 1 or 2 glasses of water.
Eye Contact: Flush thoroughly with water for 15 minutes.
Skin Contact: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change
clothes. If symptoms persist or recur, seek medical attention.
Inhalation: N/A
Note to Physician: (if applicable)
Other: Product packages have the following cautionary information on the font panel: KEEP OUT OF
REACH OF CHILDREN. CAUTION: MAY CAUSE EYE IRRITATION. SEE SIDE/BACK PANEL.
Product packages have the following cautionary information on the side/back panel: EYE IRRITANT:
Avoid eye contact. Eye contact may cause mild to moderate transient eye irritation. If eye irritation
occurs, flush with water for 15 minutes. If irritation persists seek medical attention. KEEP OUT OF
REACH OF CHILDREN.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): 115-135掳F (46.1-57.2掳C) Pensky-Martens (Closed cup). This is an
aqueous solution (>50% water) that contains less than 24% by volume of alcohol and does not sustain
combustion.
Flammable Properties:
Upper Flammable Limit:
Lower Flammable Limit:
Explosive Limits: UEL: N/A LEL: N/A
Auto-ignition Temperature: N/A
Hazardous Combustion Products: N/A
Explosion Data (Sensitivity to Mechanical Impact): N/A
Explosion Data (Sensitivity to Static Discharge): N/A
Extinguishing Media:
Suitable: CO2, water or dry chemical.
Unsuitable: N/K
Protection of Firefighters:
Specific Hazards Arising from the Material: None
Protective Equipment and Precautions for Firefighters: No unusual precautions necessary.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL
FEDERAL, STATE /PROVINCIAL AND LOCAL REGULATIONS. Solutions of the detergents may be
allowed to be flushed down sewer -- First check with your local water treatment plant. Recycling is
recommended for undiluted scrap product. Do not landfill.
Methods for Containment: Sorbents may be used. Read 鈥淲aste Disposal Method鈥? below for further
information.
Methods for Cleanup: Prevent spills from reaching a waterway.
Other Information: (if applicable)
P&G PROFESSIONAL DAWN Page 2 of 5
SECTION VII 鈥? HANDLING AND STORAGE
Precautions To Be Taken in Handling: No unusual precautions necessary.
Precautions To Be Taken in Storage: No unusual precautions necessary.
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm
OSHA Z-1 PEL 1000 ppm
Engineering Controls:
Personal Protective Equipment (PPE):
Eye/Face Protection: None required with normal consumer use.
Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable.
Skin Protection: None required with normal use.
Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact.
Respiratory Protection: None required with normal use.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Flash Point (Method Used): 115-135掳F (46.1-
Appearance (color, physical form, shape):
Blue or Yellow perfumed liquids. 57.2掳C) Pensky-Martens (Closed cup). This is an
aqueous solution (>50% water) that contains less than
24% by volume of alcohol and does not sustain
combustion.
Odor: Perfumed Reserve Alkalinity: N/A
Odor Threshold: N/A Solubility in Water: Complete
Physical State: Liquid Decomposition Temperature: N/K
Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): N/K
Vapor Density (Air=1): N/A Specific Gravity/Density: ca. 1
Boiling Point: N/K Melting/Freezing Point: ~ 30 掳F (-1.1掳C)
Partition Coefficient (n-octanol/water): N/A pH (10% solution): 8-9.2
Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State
or Federal level.
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: None Known
Incompatible Materials: None Known
Hazardous Decomposition Products: None
Possibility of Hazardous Reactions: None
P&G PROFESSIONAL DAWN Page 3 of 5
SECTION XI - TOXICOLOGICAL INFORMATION
Liquid hand dishwashing detergents have a relatively low order of toxicity. They may be
irritating, but they are not expected to be corrosive. They are expected to be emetic.
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: This finished product is not carcinogenic.
NTP: No
IARC: No
SECTION XII - ECOLOGICAL INFORMATION
Based on ecotoxicity and fate data for the individual ingredients in this specific formulation, and for
related consumer household cleaning products formulations, this product is not considered harmful to
aquatic organisms or to cause long-term adverse effects in the environment at relevant environmental
concentrations. The surfactant(s) used in the formulation biodegrade rapidly and do not accumulate in
the environment. This product is intended for dispersive use and should not be disposed of directly into
the environment.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL,
STATE /PROVINCIAL AND LOCAL REGULATIONS. The product waste is not considered RCRA
hazardous since it is an aqueous solution (>50% water) that contains less than 24% by volume of alcohol.
Non-Household Setting (US Federal): Solutions of diluted detergent in the course of use, may be
allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is
recommended for undiluted scrap product. Do not landfill.
Non-Household Setting (California): No
SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Finished product package not regulated.
Air Transport (IATA): Finished product package not regulated.
Marine/Water Transport (IMDG): Finished product package not regulated.
P&G PROFESSIONAL DAWN Page 4 of 5
SECTION XV - REGULATORY INFORMATION
United States
All intentionally-added components of this product are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable
SARA 313/302/304/311/312 chemicals: None
California: This product has been evaluated and does not require warning labeling under California
Proposition 65.
California Registration Number: Not Applicable
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state
worker exposure lists
Ingredient CAS # Level State CERCLA
RQ
Ethanol 64-17-5 1-5% CT IL IN KY LA MA 100 lbs
MN NJ NC PA RI
Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been
classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR)
and this MSDS contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.
P&G Hazard Rating: Health: 1 4=EXTREME
Flammability: 1 3=HIGH
Reactivity: 0 2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/A. - Not Applicable *N/K. - Not Known
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance
regarding the use of this material. The information contained here has been compiled from sources
considered by Procter & Gamble to be dependable and is accurate to the best of the Company鈥檚
knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication
regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of
use and design the appropriate protective mechanisms to prevent employee exposures, property damage
or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or
third persons, or for any damage to any property resulting from misuse of the product.
P&G PROFESSIONAL DAWN Page 5 of 5
|