The Procter & Gamble Company
P & G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
Issue Date: August, 2007
MSDS: RQ0701623
SECTION I - PRODUCT IDENTIFICATION
Identity: Liquid Laundry Detergent Finished Product
Brands: P&G PROLINE TIDE
P&G Telephone Number: 1-888-4PG-PROLINE (1-888-474-7765)
or call Local Poison Control Center or your physician.
SECTION II - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation.
Eye Contact: May cause mild, transient irritation.
Inhalation: Transient irritation with prolonged exposure to concentrated material.
Signs and Symptoms of Exposure:
Ingestion: May result in nausea, vomiting, and/or diarrhea.
Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness.
Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin.
SECTION III 鈥? COMPOSITION AND INGREDIENTS
Ingredients include: Water (7732-18-5), sodium alkyl ethoxylate sulfate (68585-34-2), alcohols C10-16 ethoxylate
(68002-97-1), benzene sulfonic acid (68584-22-5), C12-14 Real Soap (629-29-4 & 822-12-8)
These products contain < 0.2% detergent enzyme protein.
Hazardous ingredients as defined by OSHA 29 CFR 1910.1200 (HCS):
Common Name CAS No. Composition Range
Chemical Name
Ethyl alcohol Ethanol 64-17-5 1-5%
(Mono)Ethanolamine 141-43-5
2-Aminoethanol 1-5%
Surfactants varied
Ethoxylated Alcohol Surfactants 20 鈥? 30%
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Drink a glassful of water.
Eye Contact: Flush with water for 10 to 15 minutes.
Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change
clothes.
If symptoms persist or reoccur, seek medical attention.
Other: Product package has a caution statement: "CAUTION: Eye irritant. Harmful if swallowed. KEEP OUT
OF REACH OF CHILDREN. Avoid eye contact, which may cause mild to moderate transient irritation. If eye
contact occurs, flush with water for 15 minutes. If swallowed, give a glassful of water. If irritation persists,
seek medical attention."
P&G PROLINE TIDE Page 1 of 4
SECTION V - FIRE FIGHTING INFORMATION
Flammable Properties: These products have a Flash Explosive Limits: LEL: N/A UEL: N/A
Point > 2000 F., and they do not sustain combustion. Autoignition Temperature: N/A
Suitable Extinguishing Media: CO2, water, foam, dry chemical.
Unsuitable Extinguishing Media: Not known.
Protection of Fire Fighters:
- Specific Hazards arising from the chemical mixture: Not known.
- Protective Equipment and Precautions for Firefighters: Standard self-contained breathing apparatus (SCBA)
and full fire fighting turn-out gear (Bunker gear).
SECTION VI - ACCIDENTAL RELEASE MEASURES
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Incinerate product. Do not landfill.
Methods for Containment: Prevent spills from reaching waterways. Sorbents may be used if needed.
Methods for Cleanup: Do not landfill. Dispose of in accordance with all federal, state/provincial and local
regulations.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: No unusual precautions necessary.
Other Precautions: None
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm
OSHA Z-1 PEL 1000 ppm
Respiratory Protection (Specify Type): None required with normal use.
Ventilation Local Exhaust: None required with normal consumer use. Special: None
Mechanical (General): Normal/general dilution ventilation is acceptable. Other: None
Eye Protection: Industrial Setting: If a splash is likely, chemical goggles may be needed.
Protective Gloves: Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct
contact.
Other Protective Equipment: None required with normal use.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Flash Point: Range: > 200 0F. (CC), and these products
Appearance: Product is blue in color and perfumed.
do not sustain combustion.
Odor: Product contains perfume/fragrance. Evaporation Rate (nBuOAc=1): Not known
Odor Threshold: Not known. Explosive Limits: LEL: N/A UEL: N/A
Physical State: Liquid. Percent Volatile by Volume (%): 30 鈥? 40
o
Vapor Pressure Range (mm Hg): 18 - 21 @ 68 F. Specific Gravity (H2O=1): 1.04 to 1.09
(200 C) (mostly water)
Vapor Density (Air=1): Not known Melting/Freezing Point: N/A
Boiling Point Range 掳F: 210 - 216潞 F (98.9 鈥? 102.2 C)
0 0
pH (10% solution): 8.1 to 8.6
Coefficient of Water/Oil Distribution: N/A Reserve Alkalinity: N/A
Solubility in Water: Completely soluble.
Volatile Organic Compound (VOC): Not applicable
P&G PROLINE TIDE Page 2 of 4
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable.
Conditions to Avoid: None known.
Materials to Avoid: None known.
Hazardous Decomposition Products: None known.
Possibility of Hazardous Reactions: None known.
SECTION XI - TOXICOLOGICAL INFORMATION
Liquid Cheer formulas have a low order of toxicity. If ingested, it may be mildly irritating. It is expected to be
moderately emetic.
LD50 (oral, estimated): > 2g/kg
ED50 (emesis, estimated): ~ 0.5 g/kg
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No
IARC: No
OSHA: No
SECTION XII - ECOLOGICAL INFORMATION
Based on ecotoxicity and fate data for the individual ingredients in these mixtures, and for related consumer
household cleaning product formulations, it is expected that these mixtures would exhibit a non-hazardous order of
toxicity at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS.
Industrial Setting: For non household use/larger quantities, incineration is preferred. Do not landfill.
SECTION XIV - TRANSPORT INFORMATION
U.S. D.O.T.: These products are not regulated when transported by ground.
IATA: These products are not regulated when transported by air.
IMDG: These products are not regulated when transported by vessel.
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SECTION XV - ADDITIONAL REGULATORY INFORMATION
UNITED STATES - FEDERAL
All intentionally-added components of this product are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable
SARA chemicals: This product contains the following SARA 313/302/304/311/312 chemicals: NONE
STATES:
This product is not subject to warning labeling under California Proposition 65.
California Registration Number: Not Applicable.
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state worker
exposure lists:
Ingredient CAS# Level CERCLA
State
RQ
1-5%
Ethanol 64-17-5 CA CT IL IN KY LA 100 lbs.
MA MN NJ NC PA RI
1-5%
MEA 141-43-5 CA CT IL IN KY LA MA N/A
MN NC NJ OR PA RI
1-5%
Propylene 57-55-6 MN PA RI N/A
Glycol
1-5%
Diethylene 111-46-6 CA MN PA RI N/A
Glycol
Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in
accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS
contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION
Perfumes contained within these products covered by this MSDS comply with appropriate IFRA guidance.
*N/A. - Not Applicable *N/K. - Not Known
P&G Hazard Rating: Health: 2 4=EXTREME
Flammability: 1 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the
use of this material. The information contained here has been compiled from sources considered by Procter &
Gamble to be dependable and is accurate to the best of the Company鈥檚 knowledge. It is not meant to be an all-
inclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and
design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the
environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any
damage to any property resulting from misuse of the product.
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