Procter & Gamble
CPG TN 6
2 Procter & Gamble Plaza
Cincinnati, OH 45202
MATERIAL SAFETY DATA SHEET
MSDS #: FH/C/2005/MHMT-6CJJLL and RQ0700974 Issue Date: 9/07
Supersedes: N/A Issue Date: N/A
SECTION I - CHEMICAL PRODUCT
Identity: Granular Stain Removal Treatment
Brands: TIDE STAIN REMOVAL TREATMENT
Hazard Rating: Health: 1 4=EXTREME
Flammability: 1 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
P&G Telephone Number: 1-800-879-8433 or call Local Poison Control Center or your physician.
SECTION II - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation
Eye Contact: May cause moderate, transient irritation.
Skin Contact: None
Inhalation: Heavy exposure to dust may cause transient respiratory tract irritation. Prolonged heavy
Exposure to dust may cause respiratory sensitization.
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Eye contact with the product or its aqueous solution may produce transient superficial irritation.
Skin: None.
Inhalation: Heavy exposure to dust may cause transient respiratory tract irritation.
Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS
Ingredients listed on the product label are: biodegradable surfactants and enzymes.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
This product is hazardous under U.S. OSHA Hazard Communication (eye irritant). With increased exposure
compared with consumer use, this mixture, when tested as a whole, is considered an inhalation hazard (enzymes).
Common Name CAS No. Composition LD50/LC50
Chemical Name
Range
Soda Ash 497-19-8 15-40% 1.9 g/kg (rats, oral)
Sodium Carbonate
LD50=0.65-1.26 g/kg
Sodium Alkyl 68081-81-2 0-5%
Linear Alkyl Benzene
LC50=N/A
Sulfonic Acid, Soduim Salt Benzene
Sulfonate
1.3 鈥? 2.1 g/kg
Alkyl Sulfate 68081-98-1 5-10%
Alkyl Sulfate, Sodium Salt
(Rats, oral)
&
Proprietary
Proteolytic 9014-01-1 <0.1% g/kg (Rats, oral)
Subtilisin
Enzyme
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SECTION IV - FIRST AID INFORMATION
First Aid Procedures:
Ingestion: Give milk or water.
Eye Contact: Flush eyes with water for 15 minutes.
Skin Contact: Rinse exposed area with water.
Inhalation: Leave dusty area. In rare cases a respiratory reaction can occur which may include tightness of
chest
and difficulty breathing. If this occurs, seek medical attention immediately.
Note to Physician: (if applicable): Treat symptomatically.
Other: Product package has a caution statement: CAUTION: May cause eye irritation. Eye irritant. Avoid eye
contact. Eye contact may result in mild to moderate transient irritation unless rinsed immediately and thoroughly
with water. If eye contact occurs, flush with water for 15 minutes. If irritation persists, seek medical attention.
KEEP OUT OF REACH OF CHILDREN.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): N/A
Flammable Properties:
Upper Flammable Limit: N/A
Lower Flammable Limit: N/A
Explosive Limits: UEL: N/A LEL: N/A
Auto-ignition Temperature: N/A
Hazardous Combustion Products: None Known
Explosion Data (Sensitivity to Mechanical Impact): None Known
Explosion Data (Sensitivity to Static Discharge): None Known
Extinguishing Media:
Suitable: CO2, water, or dry chemical may be used.
Unsuitable: None.
Protection of Firefighters:
Specific Hazards Arising from the Material: None.
Protective Equipment and Precautions for Firefighters: Firefighters should be equipped with self-contained
breathing apparatus to protect against potentially irritating or sensitizing fumes.
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SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: Minimize dust levels while collecting product (see "Inhalation" health effects). Prevent
exposure to dust with NIOSH approved respirators with HEPA filters. Minimize prolonged skin contact by using
gloves.
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Small (household) solutions may be disposed of in sewer.
Dry product may be landfilled if permitted by local regulations. Discard empty container in trash. Waste water
containing product may be sewered in compliance with all federal and state/provincial regulations, and local
ordinances.
Steps To Be Taken in Case Material is Released or Spilled: Review Personal Precautions, FIRE FIGHTING
MEASURES, HANDLING AND STORAGE, and EXPOSURE CONTROL, PERSONAL PROTECTION sections
before proceeding with clean-up. Use appropriate personal protective equipment during clean-up. Spilled material
may be a slip hazard.
Methods for Containment: For dry product spills, collect material in an approved container while minimizing
dust generation. Vacuum, as appropriate, remaining dust on floor.
Methods for Cleanup: Recycle or dispose of product, as necessary, in accordance with regulations and other
requirements in this section. Flush small (household) quantities down acceptable sanitary/process sewer. Wipe up
small spills with a damp cloth. Dispose of according to local regulations.
Other Information: (if applicable): N/A
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store in a cool, dry place. Keep product dry to maintain
free-flowing granules.
Other Precautions: None
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
This section only applies to the product when used in the workplace setting.
Exposure Guidelines: Minimize dust.
Engineering Controls: N/A
Personal Protective Equipment (PPE):
Eye/Face Protection: If a splash of product in solution is likely, chemical goggles may be needed.
Skin Protection: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Respiratory Protection: Dusty conditions may require a NIOSH approved respirator with HEPA filters.
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SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance (color, physical form, shape): Flash Point (Method Used): N/A
White powder with or without colored speckles
Odor: Scented or unscented. Reserve Alkalinity: ~ 5-8.75 g NaOH/100 mL (at
pH=9.5)
Solubility in Water: Mostly soluble at 68oF (20oC)
Odor Threshold: N/A
Physical State: Solid granules at 68oF (20oC) Decomposition Temperature: N/A
Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): N/A
Vapor Density (Air=1): N/A Specific Gravity/Density: Density 420鈥?650 g/L
Boiling Point: N/A Melting/Freezing Point: N/A
Partition Coefficient (n-octanol/water): N/A pH (of a 1% solution): 10鈥?11.5
Volatile Organic Compound (VOC): Not Applicable - Product not regulated for VOC Content at State or
Federal level.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: None known
Hazardous Decomposition Products: None
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
Granular detergent has a relative low order of toxicity. If ingested, it may result in mild gastrointestinal irritation,
diarrhea, and/or vomiting. Eye contact with the product or its aqueous solution my produce transient superficial
irritation.
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: This finished consumer product is not carcinogenic.
NTP: No
IARC: Ingredients checked and no carcinogens are present.
SECTION XII - ECOLOGICAL INFORMATION
Based on ecotoxicity and chemical fate data the ingredients in this product are not expected to harm the
environment when disposed of through normal routes of use. The surfactants in this detergent are readily
biodegradable and well removed during sewage treatment processing.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Small quantities may be disposed of in sewer. For larger
quantities, incineration is preferred. Do not landfill. Discard empty container in trash.
Non-Household Setting (federal): Products covered by this MSDS, in their original form, when disposed as waste, are
considered non-hazardous waste according to Federal RCRA regulations (40 CFR 261).
Non-Household Setting (California): Not hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24
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SECTION XIV - TRANSPORT INFORMATION
Products covered by this MSDS, in their original form, are not regulated for transportation.
Ground Transport (US DOT): Not regulated
Air Transport (IATA): Not regulated
Marine/Water Transport (IMDG): Not regulated
SECTION XV - ADDITIONAL REGULATORY INFORMATION
UNITED STATES - FEDERAL
All intentionally added components of this product are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable.
This product contains the following SARA 313/302/304/311/312 chemicals present at 1% or greater in the product
formula 90.1% for carcinogens): None
UNITED STATES - STATES
California: This product is not subject to warning labeling under California Proposition 65.
California Registration Number: Not Applicable.
The following ingredients are present in the finished product and are listed on the following state right-to-know
lists state worker exposure lists:
Ingredient CAS# Level State CERCLA
Sodium Carbonate 497-19-8 15-40% TX N/A
Polyethylene Glycol 25322-68-3 1-5% MN TX N/A
Zeolite 1318-02-1 1-5% NJ N/A
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Controlled Products Regulation (CPR) and this MSDS contains all
information required by the Controlled Products Regulation.
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SECTION XVI - OTHER INFORMATION
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.
*N/A. - Not Applicable *N/K. - Not Known
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the
use of this material. The information contained here has been compiled from sources considered by Procter &
Gamble to be dependable and is accurate to the best of the Company鈥檚 knowledge. It is not meant to be an all-
inclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of the material needs to evaluate the conditions of use and
design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the
environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any
damage to any property resulting from misuse of the product.
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