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Procter & Gamble
Fabric and Home Care Division
Ivorydale Technical Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: FH/F/2004/VBVV-5YAP6R Issue Date: 5/18/04
Supersedes: FH/F/2004/VBVV-5WCSJZ Issue Date: 4/13/04
SECTION I - CHEMICAL PRODUCT
Identity: Aerosol Air Refresher
Brands: FEBREZE
Hazard Rating: Health: 1 4=EXTREME
Flammability: 2 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: 24 hour P&G Operator: 1-800-308-EASY (1-800-308-3279) or call Local Poison
Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients include: water alcohol, odor eliminator derived from corn, fragrance, non-flammable natural propellant,
quality control ingredients
CONTENTS UNDER PRESSURE WITH NITROGEN AT 120 PSI
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS No. Recommended Composition Range LD50/LC50
Chemical
Name Limits
Name
Ethyl alcohol Ethanol 64-17-5 ACGIH TLV: 3-7% 7.06 g/kg Rat, oral
1000 mg/m3
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: None
Eye Contact: Mild eye irritant.
Inhalation: None
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Do not spray directly toward face. If eye contact occurs, rinse well with water.
Skin: Prolonged skin contact or instillation into the eye may result in transient, superficial effects similar to
those produced by mild toilet soap.
Inhalation: Intentional misuse by deliberately concentrating and inhailing pressurized product may be harmful
or fatal. Inhalation of high concentrations of ethanol vapor may cause irritation of the eyes and
respiratory tract, drowsiness, and fatigue.
FEBREEZE AEROSOL AIR REFRESHER MSDS PAGE 2 OF 4
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Inhalation: Remove to fresh air.
Ingestion: Dilute with fluids and treat symptomatically.
Eye Contact: Rinse well with water for at least 15 minutes.
Skin: Rinse with water.
Other:
US Product Package:
Consumer product packages have a caution statement: FRONT PANEL: CAUTION: CONTENTS UNDER
PRESSURE. Read back panel carefully. BACK PANEL: CAUTION: Intentional misuse by deliberately
concentrating and inhailing pressurized product may be harmful or fatal KEEP OUT OF REACH OF
CHILDREN . Do not spray towards face. If eye contact occurs, rinse well with water. If irritation persits, get
medical attention. Do not expose to heat or open flame or store at temperatures above 120 F. Dispose
properly. Do not puncture or incinerate container.
Canadian Product Package:
FRONT PANEL: CAUTION: CONTENTS UNDER PRESSURE. BACK PANEL: CAUTION:
CONTAINER MAY EXPLODE IF HEATED. Do not puncture. Do not burn. Store away from heat. KEEP
OUT OF REACH OF CHILDREN. Do not spray towards face. If eye contact occurs, rinse well with water.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): >> 55 o 鈥? 58oC / Explosive Limits: LEL: N/A UEL: N/A
131-137掳 F (cc)
Extinguishing Media: Use CO2, water, or dry chemical.
Special Fire Fighting Procedures:. N/A
Unusual Fire Hazards: N/A
Conditions to Avoid: None
Stability Unstable:
Stable: X
Incompatibility (Materials to Avoid): None known
Hazardous Decomposition/By Products: None known
Conditions to Avoid: None
Hazardous Polymerization: May Occur:
Will Not Occur: X
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL
REGULATIONS. Collect liquid and incinerate. Puncture container and landfill.
Steps To Be Taken in Case Material is Released or Spilled: Use water spray to dilute and/or wash away spills to
avoid exposure and to protect persons working to stop/repair leak. Any spills are to be prevented from entering
waterways. Sorbents may be used.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store at room temperature. Avoid temperatures above 43 oC
/ 110F
Other Precautions: None
FEBREEZE AEROSOL AIR REFRESHER MSDS PAGE 3 OF 4
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): No special requirements with casual exposure.
Ventilation Local Exhaust: Not necessary. Special: None
Mechanical (General): Acceptable Other: None
Eye Protection: None required with normal consumer use.
Industrial Setting: If a splash of solution is likely, chemical goggles may be needed.
Protective Gloves: None required with normal consumer use.
Industrial Setting: Minimize skin contact with protective gloves (rubber, neoprene).
Other Protective Equipment: None required with normal use.
Industrial Setting: Use ventilation to minimize exposure to vapor or mist (ethanol).
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 掳F: ~ 100 oC / 212潞F Specific Gravity (H2O=1): ca. 1
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): ca. 95
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/K
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (1% solution): 4.0-5.0
Scooped Density: N/A Solubility in Water: Soluble
Appearance and Odor: Clear liquid. Product is Reserve Alkalinity: N/A
perfumed.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None known
Materials to Avoid: None
Hazardous Decomposition Products: None known
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): >5000 mg/kg
SECTION XII - ECOLOGICAL INFORMATION
There are no concerns at relevant environmental concentrations. Based on ecotoxicity and fate data for the
individual ingredients in this formulation and for similar consumer product formulations, this product is anticipated
to be non-hazardous to the environment following consumer usage.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Prodcut is a RCRA hazardous waste (D001 ignitable compressed gas). Expell liquid,
collect and incinerate. Puncture container and landfill. For consumer use, dispose of empty containers in the
landfill. Disposal is to be performed in compliance with all Federal, Provincial and local regulations.
FEBREEZE AEROSOL AIR REFRESHER MSDS PAGE 4 OF 4
SECTION XIV - TRANSPORT INFORMATION
Proper shipping name for the product is: Aerosols, 2.1 UN1950
For finished packaged product shipped by ground in the US: ORM-D Consumer Commodity Finished product
container capacity may not exceed 1L for Consumer commodity classification.
For finished packaged product by air: Consumer commodity, 9 , ID8000 Product container capacity may not
exceed 500mL due to flammability.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA 搂5.
No components of Febreze are subject to California Proposition 65.
Chemical Name CERCLA RQ
Ethanol 100 lbs
Hydrochloric Acid 5000 lbs
EPCRA (SARA Title III) Section 313 Toxic Chemical: Hydrochloric Acid 1.0% De Minimis Concentration
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information
required by the Canadian Products Regulation.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to
any property resulting from misuse of the controlled product.
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