Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
Revision Date: 04/19/2006
INSECTICIDE
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE INSECTICIDE
Product Name
102000012928
MSDS Number
264-992
EPA Registration No.
Bayer CropScience
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA
For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-866-99BAYER (1-866-992-2937)
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component Name CAS-No. Average % by Weight
Chlorpyrifos-methyl 5598-13-0 21.60
Deltamethrin 52918-63-5 3.70
1,2,4-Trimethylbenzene 95-63-6 18.70
Xylene 1330-20-7 13.85
Ethylbenzene 100-41-4 2.77
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information.
Danger! Corrosive - causes irreversible eye damage. Causes eye irritation.
Emergency Overview
Causes skin irritation. Prolonged or frequently repeated skin contact may cause
allergic reactions in some individuals. Harmful if inhaled. Do not breathe vapours
or spray mist. Do not get in eyes, on skin, or on clothing. Extremely toxic to fish.
Highly toxic to bees.
liquid
Physical State
of mercaptans
Odor
amber
Appearance
Inhalation, Ingestion, Eye contact, Skin contact, Skin Absorption
Routes of Exposure
Immediate Effects
Corrosive - causes irreversible eye damage. May produce severe eye irritation.
Eye
Vapors and mists can cause irritation. Do not get in eyes.
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
Moderate skin irritation. May cause a transient, localized paresthesia,
Skin
characterized by tingling, burning or numbness sensation in some individuals.
Prolonged or frequently repeated skin contact may cause allergic reactions in
some individuals. Do not get in eyes, on skin, or on clothing.
Do not take internally. Harmful if swallowed.
Ingestion
Inhalation of high concentrations of solvent vapors can cause nausea, vomiting,
Inhalation
dizziness, drowsiness and incoordination. May cause respiratory tract irritation.
Harmful if inhaled. Do not breathe vapours or spray mist.
This product contains ingredients that are considered to be probable or
Chronic or Delayed
suspected human carcinogens (see Section 11 - Chronic). This product or its
Long-Term
components may have target organ effects.
SECTION 4. FIRST AID MEASURES
When possible, have the product container or label with you when calling a
General
poison control center or doctor or going for treatment.
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Eye
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing
eye. Call a physician or poison control center immediately.
Wash off immediately with plenty of water for at least 15 minutes. Take off
Skin
contaminated clothing and shoes immediately. Call a physician or poison control
center immediately.
Call a physician or poison control center immediately. Rinse out mouth and give
Ingestion
water in small gulps to drink. DO NOT induce vomiting unless directed to do so
by a physician or poison control center. Never give anything by mouth to an
unconscious person. Do not leave victim unattended.
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or
poison control center immediately.
Notes to Physician
May pose an aspiration pneumonia hazard. Cholinesterase inhibitor.
Hazards
There is no specific antidote. Appropriate supportive and symptomatic treatment
Treatment
as indicated by the patient's condition is recommended.
SECTION 5. FIRE FIGHTING MEASURES
48.9 掳C / 120.0 掳F
Flash Point
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
Under fire conditions, toxic, corrosive fumes are emitted.
Fire and Explosion
Keep away from open flames, hot surfaces and sources of ignition.
Hazards
foam, carbon dioxide (CO2), dry chemical, water spray
Suitable Extinguishing
Media
Keep out of smoke. Fight fire from upwind position. Cool closed containers
Fire Fighting
exposed to fire with water spray. Dike area to prevent runoff and contamination
Instructions
of water sources. Equipment or materials involved in pesticide fires may become
contaminated.
Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled
Personal Precautions
product or contaminated surfaces.
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary
Methods for Cleaning Up
absorbent material). Keep in suitable, closed containers for disposal. Clean
contaminated floors and objects thoroughly, observing environmental
regulations.
Use personal protective equipment. Do not allow product to enter streams,
Additional Advice
sewers or other waterways.
SECTION 7. HANDLING AND STORAGE
Handle and open container in a manner as to prevent spillage.
Handling Procedures
Store in a cool, dry place and in such a manner as to prevent cross
Storing Procedures
contamination with other pesticides, fertilizers, food, and feed. Store in original
container and out of the reach of children, preferably in a locked storage area.
Wash hands thoroughly with soap and water after handling and before eating,
Work/Hygienic
drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.
Procedures
Take off contaminated clothing and shoes immediately. Then wash thoroughly
and put on clean clothing.
Remove Personal Protective Equipment (PPE) immediately after handling this
product. Before removing gloves clean them with soap and water. As soon as
practical, wash thoroughly and change into clean clothing.
Do not transport or store below -7 掳C / 19 掳F
Min/Max Storage
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
Do not transport or store above 49 掳C / 120 掳F
Temperatures
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Follow all label instructions. Train employees in safe use of the product.
General Protection
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such
instructions for washables, use detergent and warm/tepid water. Keep and wash
PPE separately from other laundry.
Maintain exposure levels below the exposure limit through the use of general
Engineering Controls
and local exhaust ventilation.
tightly fitting safety goggles
Eye/Face Protection
Chemical resistant nitrile rubber gloves
Hand Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Body Protection
When respirators are required, select NIOSH approved equipment based on
Respiratory Protection
actual or potential airborne concentrations and in accordance with the
appropriate regulatory standards and/or Industry recommendations.
Exposure Limits
1,2,4-Trimethylbenzene 95-63-6 NIOSH REL 25 ppm 125 mg/m3
ACGIH TWA 25 ppm
OSHA Z1A TWA 25 ppm 125 mg/m3
US CA OEL TWA PEL 25 ppm 125 mg/m3
Xylene 1330-20-7 ACGIH TWA 100 ppm
ACGIH STEL 150 ppm
OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
OSHA Z1A STEL 150 ppm 655 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL Ceiling 300 ppm
US CA OEL STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 150 ppm 655 mg/m3
Ethylbenzene 100-41-4 ACGIH TWA 100 ppm
ACGIH STEL 125 ppm
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 125 ppm 545 mg/m3
OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
OSHA Z1A STEL 125 ppm 545 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL STEL 125 ppm 545 mg/m3
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
amber
Appearance
liquid
Physical State
of mercaptans
Odor
3.0 - 4.0 (1 %)
pH
0.99 at 20 掳C
Specific Gravity
miscible
Water Solubility
SECTION 10. STABILITY AND REACTIVITY
Stable
Chemical Stability
Exposure to extreme heat.
Conditions to Avoid
strong bases
Incompatibility
oxidizing agents
Thermal decomposition can lead to release of:
Hazardous
sulphides
Decomposition Products
nitrogen oxides (NOx)
SECTION 11. TOXICOLOGICAL INFORMATION
rat: LD50: 150 mg/kg
Acute Oral Toxicity
rat: LD50: > 5,000 mg/kg
Acute Dermal Toxicity
rat: LC50: 0.53 - 2.58 mg/l
Acute Inhalation Toxicity
Exposure time: 4 h
Moderate skin irritation.
Skin Irritation
Severe eye irritation.
Eye Irritation
guinea pig: Causes sensitization.
Sensitization
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
Assessment Carcinogenicity
ACGIH
Xylene 1330-20-7 Group A4
Ethylbenzene 100-41-4 Group A3
NTP
None.
IARC
Deltamethrin 52918-63-5 Overall evaluation: 3
Xylene 1330-20-7 Overall evaluation: 3
Ethylbenzene 100-41-4 Overall evaluation: 2B
OSHA
None.
SECTION 12. ECOLOGICAL INFORMATION
Highly toxic to fish. Toxic to birds. Toxic to wildlife. Do not apply directly to water,
Environmental
to areas where surface water is present or to intertidal areas below the mean
Precautions
high water mark. Do not discharge into the drains/surface water/groundwater. Do
not contaminate surface or ground water by cleaning equipment or disposal of
wastes, including equipment wash water. Exposed treated seed may be
hazardous to birds. Apply this product only as specified on the label.
Highly toxic to bees. Do not apply this product or allow it to drift to blooming
crops or weeds if bees are visiting the treatment area.
SECTION 13. DISPOSAL CONSIDERATIONS
Open dumping is prohibited. Pesticide wastes are acutely hazardous. Improper
General Disposal
disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal
Guidance
Law. If these wastes cannot be disposed of by use according to label
instructions, contact your State Pesticide or Environmental Control Agency, or
the Hazardous Waste representative at the nearest EPA Regional Office for
guidance.
Do not re-use empty containers. Triple rinse containers. Then offer for recycling
Container Disposal
or reconditioning or puncture and dispose of in a sanitary landfill or incineration,
or if allowed by State and Local authorities, by burning. If burned, stay out of
smoke.
The RCRA Classifications may be on the individual component(s) and not
RCRA Classification:
necessarily on the product as a whole.
1330-20-7 Xylene
US. EPA Resource Conservation and Recovery Act (RCRA) U List of Hazardous Wastes (40
CFR 261.33(f) and 40 CFR 302 [CERCLA]): U239
100-41-4 Ethylbenzene
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
US. EPA Resource Conservation and Recovery Act: (RCRA) D List of Characteristic
Hazardous Wastes (40 CFR 261.21-24): D001
SECTION 14. TRANSPORT INFORMATION
TRANSPORTATION CLASSIFICATION:
RQ, Pesticides, Liquid, Toxic, Flammable, N.O.S. (chlorpyrifos-methyl, xylene range solvents), 6.1,(3),
UN2903, PG III
FREIGHT CLASSIFICATION:
Insecticides or Fungicides, N.O.I.; poison, other than gases that are poisonous by inhalation
SECTION 15. REGULATORY INFORMATION
264-992
EPA Registration No.
US Federal Regulations
TSCA list
1,2,4-Trimethylbenzene 95-63-6
Xylene 1330-20-7
Ethylbenzene 100-41-4
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
Xylene 1330-20-7
SARA Title III - Section 302 - Notification and Information
None.
SARA Title III - Section 313 - Toxic Chemical Release Reporting
Chlorpyrifos-methyl 5598-13-0 1.0%
1,2,4-Trimethylbenzene 95-63-6 1.0%
Xylene 1330-20-7 1.0%
Ethylbenzene 100-41-4 0.1%
US States Regulatory Reporting
CA Prop65
This product contains a chemical known to the State of California to cause cancer.
Ethylbenzene 100-41-4
This product does not contain any substances known to the State of California to cause reproductive
harm.
US State Right-To-Know Ingredients
Chlorpyrifos-methyl 5598-13-0 NJ
1,2,4-Trimethylbenzene 95-63-6 CA, IL, MN, NJ, PA, RI
Xylene 1330-20-7 CA, CT, IL, MI, MN, NJ, PA, RI
Ethylbenzene 100-41-4 CA, CT, IL, MN, NJ, PA, RI
Canadian Regulations
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Bayer CropScience
Material Safety Data Sheet MSDS Number: 102000012928
STORCIDE鈩? II GRAIN, BIN AND WAREHOUSE MSDS Version 2.0
INSECTICIDE
Canadian Domestic Substance List
1,2,4-Trimethylbenzene 95-63-6
Xylene 1330-20-7
Ethylbenzene 100-41-4
Environmental
CERCLA
Xylene 1330-20-7 100 lbs
Ethylbenzene 100-41-4 1,000 lbs
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.
International Regulations
European Inventory of Existing Commercial Substances (EINECS)
Chlorpyrifos-methyl 5598-13-0
Deltamethrin 52918-63-5
1,2,4-Trimethylbenzene 95-63-6
Xylene 1330-20-7
Ethylbenzene 100-41-4
SECTION 16. OTHER INFORMATION
NFPA 704 (National Fire Protection Association):
Health - 3 Flammability - 2 Reactivity - 1 Others - none
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard
Reason to Revise: Update format to new system.
Revision Date: 04/19/2006
This information is provided in good faith but without express or implied warranty. The customer assumes all
responsibility for safety and use not in accordance with label instructions. The product names are registered
trademarks of Bayer.
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